Journal
BATTERIES & SUPERCAPS
Volume -, Issue -, Pages -Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/batt.202200421
Keywords
co-intercalation; electrochemistry; graphite; sodium-ion battery; solid-state NMR spectroscopy
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The possibility of co-intercalating sodium ions and glymes in graphite for use in sodium-ion batteries as negative electrode material needs further clarification regarding the storage mechanism and local interactions. Experiments using solid-state NMR provide insights into the storage mechanism depending on the state of charge and electrolyte solvent used, as well as information on sodium ion transport in the graphitic lattice. The inferior cycling performance of triglyme compared to diglyme and pentaglyme is reflected in the ss-NMR spectra, showing reduced mobility and stronger interactions between sodium ions, triglyme, and graphite.
The possibility to co-intercalate sodium ions together with various glymes in graphite enables its use as a negative electrode material in sodium-ion batteries (SIBs). However, the storage mechanism and local interactions appearing during this reaction still needs further clarification. H-1, C-13 and Na-23 ex situ solid-state NMR (ss-NMR) experiments are performed to obtain insights into the storage mechanism depending on the state of charge (SOC) and the electrolyte solvent used. Distinct differences could be seen depending on the SOC, indicating a possible change of the solvation shell, differences in the mobility as well as a phase transition at the voltage plateau. Furthermore, exchange experiments reveal information on the sodium ion transport process in the graphitic lattice. The inferior cycling performance of triglyme (3G) (compared to diglyme (2G) and pentaglyme (5G)) is also reflected in the ss-NMR spectra, showing a reduced mobility and stronger interactions between sodium ions, 3G and graphite already at room temperature (RT).
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