4.6 Article

Phases in HfO2-Based Ferroelectric Thin Films and Their Integration in Low-Power Devices

Journal

ACS APPLIED ELECTRONIC MATERIALS
Volume 5, Issue 1, Pages 11-20

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acsaelm.2c01513

Keywords

HfO2; ferroelectrics; negative capacitance; memories; field-effect transistors

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HfO2-based ferroelectrics are widely used in electronic devices, including ultralow-power logic circuits and nonvolatile memory. These ferroelectrics offer compatibility with complementary metal oxide semiconductor and demonstrate large coercive fields and ferroelectricity at sub-10 nm thicknesses. This article focuses on their application to surpass the physical limit of the subthreshold swing of field-effect transistors (FETs) by stabilizing negative capacitance. It also discusses HfO2-ferroelectric-based memories, such as two-terminal random-access devices, tunnel junctions, three-terminal ferroelectric FETs, and their respective 3D stacked architectures.
HfO2-based ferroelectrics are applied in a large spectrum of electronic devices ranging from ultralow-power logic to nonvolatile memory. The efficacy of these ferroelectrics is that these offer complementary metal oxide semiconductor compatibility in conjunction with large coercive fields and ferroelectricity at sub-10 nm thicknesses. Because of these advantages compared with conventional lead-based thick perovskite films (>50 nm), the present spotlight article focuses on their use to surpass the physical limit of the subthreshold swing (60 mV/dec at room temperature) of field-effect transistors (FETs) via the stabilization of the negative capacitance. In addition, the discussion on HfO2-ferroelectric-based memories is focused on two-terminal random-access devices, tunnel junctions, three-terminal ferroelectric FETs and their respective 3D stacked architectures.

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