Crystal structure engineering of metal halide perovskites for photocatalytic organic synthesis

Engineering crystal structure of Cs3BiBr6 and Cs3Bi2Br9 is theoretically and experimentally demonstrated to modulate their photocatalytic performance. This work offers insights into the structure-photoactivity relationships of metal halide perovskites (MHPs) and provides a guideline for exploiting MHPs toward efficient photocatalytic organic synthesis.

Automated summary

By theoretically and experimentally engineering the crystal structure of Cs3BiBr6 and Cs3Bi2Br9, their photocatalytic performance can be modulated. This study provides insights into the structure-photoactivity relationships of metal halide perovskites (MHPs) and offers a guideline for exploiting MHPs for efficient photocatalytic organic synthesis.