High-resolution molecular fingerprinting in the 11.6-15 μm range by a quasi-CW difference-frequency-generation laser source

We report an approach for high-resolution spectroscopy using a widely tunable laser emitting in the molecular fingerprint region. The laser is based on difference-frequency generation (DFG) in a nonlinear orientation-patterned GaAs crystal. The signal laser, a CO2 gas laser, is operated in a kHz-pulsed mode while the pump laser, an external-cavity quantum cascade laser, is finely mode-hop-free tuned. The idler radiation covers a spectral range of similar to 11.6-15 mu m with a laser linewidth of similar to 2.3 MHz. We showcase the versatility and the potential for molecular fingerprinting of the developed DFG laser source by resolving the absorption features of a mixture of several species in the long-wavelength mid-infrared. Furthermore, exploiting the wide tunability and resolution of the spectrometer, we resolve the broadband absorption spectrum of ethylene (C2H4) over similar to 13-14.2 mu m and quantify the self-broadening coefficients of some selected spectral lines.(c) 2023 Optica Publishing Group under the terms of the Optica Open Access Publishing Agreement

Automated summary

We present a method for high-resolution spectroscopy in the molecular fingerprint region using a widely tunable laser based on difference-frequency generation (DFG) in a nonlinear orientation-patterned GaAs crystal. The developed DFG laser source demonstrates versatility and potential for molecular fingerprinting by resolving absorption features and quantifying self-broadening coefficients. The spectrometer offers wide tunability and resolution, enabling the resolution of broadband absorption spectra.