Assessing human exposure to phthalate esters in drinking water migrated from various pipe materials and water filter elements during water treatments and storage

Plastic water-supply pipes and filter element are frequently used in municipal water supply systems. Leaching of phthalate esters (PAEs) from these pipes and filter elements to drinking water has become a common concern among the public. In this study, the migrations of 16 phthalate esters (PAEs) in seven different kinds of water-supply product materials were investigated. Di-n-butyl phthalate (DBP) had the highest detection frequency of 54.4% in the water leaching samples of various water supply pipes and water filter elements samples, followed by Diisobutyl phthalate (DIBP, 46/90, 51.1%). The maximum detected concentration level for di(2-ethylhexyl) phthalate (DEHP), diethyl phthalate (DEP), and DBP in the leaching experiment was below the regulatory limit values of 8 mu g/L, 300 mu g/L, and 3 mu g/L for each compound in China standards for drinking water quality. The increasing of the water temperature, the lower pH of the water, and the increasing of the leaching time will increase the migration of PAEs from plastic pipes into water. The chronic daily intake of children aged < 1-12 years to PAEs through drinking water was higher than the rest of the population groups. Carcinogenic risks (CR) of DEHP via drinking water were neglectable for most groups of people, while for young children with age of 1-2 years old, the CR is an acceptable risk.

Automated summary

The migration of 16 phthalate esters (PAEs) in seven different types of water pipes and filter materials was investigated. It was found that the migration of PAEs from plastic pipes into water increases with higher water temperature, lower pH, and longer leaching time. The chronic daily intake of PAEs through drinking water was higher for children aged < 1-12 years than other population groups. The carcinogenic risk of DEHP through drinking water was negligible for most groups, but acceptable for young children aged 1-2 years.