Probing single-chain conformation and its impact on the optoelectronic properties of donor-accepter conjugated polymers

The chain conformation of donor-acceptor conjugated polymers (D-A CPs) is critical to their optical and electronic properties. However, probing the conformation of D-A CPs (e.g., persistence length and contour length) at a single-chain level is challenging due to the formation of aggregates in dilute solution, even in a good solvent. In this work, we studied the chain conformation and corresponding optical spectra for high-performance D-A CPs in the single-chain state by multimodal variable-temperature scattering and spectroscopy techniques, as well as by molecular dynamics simulations. We found a critical role of the side-chain length and branch point in the persistence length and optical absorption due to steric effects. Hence, it is important to consider both the chain rigidity and coplanarity of the polymer backbone to achieve desirable optoelectronic properties. Our findings bridge the fundamental knowledge gaps to design new CPs with desired optoelectronic properties via molecular engineering for next-generation electronic devices.

Automated summary

We studied the chain conformation and optical properties of high-performance donor-acceptor conjugated polymers at the single-chain level. The length of side chains and the presence of branch points play a critical role in the chain conformation and optical absorption. Considering the rigidity and coplanarity of the polymer backbone is important for achieving desired optoelectronic properties.