Journal
NEW JOURNAL OF CHEMISTRY
Volume 47, Issue 15, Pages 7356-7368Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d2nj06252f
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The synthesis and characterization of symmetric liquid crystal dimers containing different terminal chains are reported. The nematogenic behavior is observed in the dimers with short alkylthio or alkyloxy terminal chains, while the higher homologues show the smectic A phase. The dimers with alkylthio chains have lower clearing temperatures compared to those with alkyloxy chains, except for the dimers with the shortest terminal chains. The steric and electronic interactions are discussed to explain the observed behavior.
The synthesis and characterisation of four series of symmetric liquid crystal dimers containing either alkylthio or alkyloxy terminal chains are reported. The (E,E)-[pentane-1,5-diylbis(oxy-4,1-phenylene)]bis{N-[4-(alkyloxy)phenyl]methanimine}s, mO.O5O.Om and (E,E)-[hexane-1,6-diylbis(oxy-4,1-phenylene)]bis{N-[4-(alkyloxy)phenyl]methanimine}s, mO.O6O.Om series are nematogenic when the terminal chains are short whereas the higher homologues show the smectic A phase. The mO.O6O.Om series shows higher clearing temperatures regardless of the terminal chain length. The (E,E)-[pentane-1,5-diylbis(oxy-4,1-phenylene)]bis{N-[(alkylthio)phenyl]methanimine}s, mS.O5O.Sm series is solely nematogenic, and does not show liquid crystallinity when m >= 5. The (E,E)-[hexane-1,6-diylbis(oxy-4,1-phenylene)]bis{N-[(alkylthio)phenyl]methanimine}s, mS.O6O.Sm series, however, shows mesogenic behavior over the entire series, with the smectic C phase only emerging when the terminal chain is long, m >= 8. In general, for a given spacer length, the dimers containing alkyloxy chains show the highest clearing temperatures and the alkylthio chains the lowest. For the shortest terminal chains, however, the nematic-isotropic transition temperatures of the alkylthio materials are higher than those containing the alkyl chain. This behaviour is rather general and discussed in terms of steric and electronic interactions.
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