Journal
JOURNAL OF PHYSICAL CHEMISTRY C
Volume 127, Issue 4, Pages 1955-1964Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.jpcc.2c070321955J
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The development of Li-metal batteries has led to research on the chemical modification of solid polymer electrolytes, involving the tuning of polymer or Li salt properties to improve overall cell performance. This study focuses on the simultaneous chemical modification of both the polymer matrix and lithium salt, exploring ion coordination environments, ion transport mechanisms, and molecular speciation. By substituting F atoms with H atoms in the Li salt and exchanging PEO with PCL, the lithium transference number and charge carrier speciation can be enhanced. Molecular dynamics simulations and experimental techniques help analyze the solvation structure and synergistic effects on macroscopic properties such as Li+ conductivity and transference number.
The advent of Li-metal batteries has seen progress toward studies focused on the chemical modification of solid polymer electrolytes, involving tuning either polymer or Li salt properties to enhance the overall cell performance. This study encompasses chemically modifying simultaneously both polymer matrix and lithium salt by assessing ion coordination environments, ion transport mechanisms, and molecular speciation. First, commercially used lithium bis(trifluoromethanesulfonyl)imide (LiTFSI) salt is taken as a reference, where F atoms become partially substituted by one or two H atoms in the -CF3 moieties of LiTFSI. These substitutions lead to the formation of lithium-(difluoromethanesulfonyl) (trifluoromethanesulfonyl)imide (LiDFTFSI) and lithium bis(difluoromethanesulfonyl)imide (LiDF-SI) salts. Both lithium salts promote anion immobilization and increase the lithium transference number. Second, we show that exchanging archetypal poly(ethylene oxide) (PEO) with poly(epsilon-caprolactone) (PCL) significantly changes charge carrier speciation. Studying the ionic structures of these polymer/Li salt combinations (LiTFSI, LiDFTFSI or LiDFSI with PEO or PCL) by combining molecular dynamics simulations and a range of experimental techniques, we provide atomistic insights to understand the solvation structure and synergistic effects that impact macroscopic properties, such as Li+ conductivity and transference number.
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