Journal
CHEMICAL COMMUNICATIONS
Volume 59, Issue 35, Pages 5265-5268Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d3cc01037f
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This article presents a dinuclear metallacycle that is assembled from a bispyridyl dithienylethene linker and a highly anisotropic dysprosium based Single Molecule Magnet (SMM). It exhibits magnetic hysteresis at 1.8 K and photoisomerization in single crystals (SC). The impact of photoswitching on the SMM behavior is evidenced and correlated with the specific organization of the magnetic units.
A dinuclear metallacycle assembled from a bispyridyl dithienylethene linker and a highly anisotropic dysprosium based Single Molecule Magnet (SMM) shows magnetic hysteresis at 1.8 K together with photoisomerization in single crystals (SC). The impact of photoswitching on the SMM behavior is evidenced and related to the specific organization of the magnetic units.
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