☆ 4.8 Review

Engineering strategies and active site identification of MXene-based catalysts for electrochemical conversion reactions

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Nickel-decorated MoS2/MXene nanosheets composites for electrocatalytic oxidation of methanol

Mijun Chandran et al.

Summary: NiMoS2/MXene catalysts prepared by wet impregnation method exhibit excellent electrocatalytic activity, good tolerance to CO poisoning, and high mechanical stability, making them a promising anode material for fuel cell applications, such as Direct Methanol Fuel Cell (DMFC).

CERAMICS INTERNATIONAL (2021)

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Article Chemistry, Physical

Efficient tuning the electronic structure of N-doped Ti-based MXene to enhance hydrogen evolution reaction

Meina Han et al.

Summary: A low-cost electrocatalyst with controlled N-doping, synthesized by ultrasonication to produce Ti3C2Tx MXene, exhibits enhanced HER activity at an optimized ultrasonic temperature of 35 degrees C due to the formation of Ti-N chemical bonds. This N-doped MXene (N-MXene-35) shows exceptional performance with a significantly lower overpotential compared to pristine MXene, making it the best HER electrocatalyst among reported MXene or N-doped MXene electrodes.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2021)

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Article Energy & Fuels

Cobalt Nanoparticles Encapsulated in N-Doped Carbon on the Surface of MXene (Ti3C2) Play a Key Role for Electroreduction of Oxygen

Haridas B. Parse et al.

Summary: MXenes have been widely used in electrochemical devices due to their unique two-dimensional structure; this study focused on the preparation and electrocatalytic ability of a composite material Co-NC/Ti3C2-800 derived from MXene and metal organic framework; the optimized composite showed enhanced oxygen reduction reaction activity and superior cycling performance, making it a potential substitute for current catalysts, especially in alkaline conditions.

ENERGY & FUELS (2021)

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Article Energy & Fuels

Facile synthesis of polyaniline/titanium carbide (MXene) nanosheets/palladium nanocomposite for efficient electrocatalytic oxidation of methanol for fuel cell application

Mari Elancheziyan et al.

Summary: A highly efficient electrocatalyst composed of PANI/Pd/MXene nanocomposite was developed for methanol electrooxidation, showing improved electrochemical response and stability up to 100 cycles. This design demonstrates the potential for MXene-supported noble metal electrocatalysts to enhance methanol electrooxidation in DMFCs.

FUEL (2021)

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Article Chemistry, Multidisciplinary

Electrocatalytic Synthesis of Ammonia Using a 2D Ti3C2 MXene Loaded with Copper Nanoparticles

Anmin Liu et al.

Summary: In this study, a Cu/Ti3C2 composite catalyst was prepared for efficient electrochemical conversion of N2 into NH3. This catalyst exhibited high Faradaic efficiency and NH3 production rate in 0.1 M KOH solution. Moreover, it showed superior electrochemical stability and durability, with Cu playing a vital role in enhancing the catalytic activity and conductivity of Ti3C2-based materials.

CHEMPLUSCHEM (2021)

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Article Chemistry, Multidisciplinary

Selective Etching Quaternary MAX Phase toward Single Atom Copper Immobilized MXene (Ti3C2Clx) for Efficient CO2 Electroreduction to Methanol

Qi Zhao et al.

Summary: An efficient method for producing single atom copper immobilized MXene for catalyzing CO2 reduction to methanol through selective etching of hybrid A layers in quaternary MAX phases was demonstrated. The single atom Cu catalyst exhibited high Faradaic efficiency and good electrocatalytic stability, attributed to its unique electronic structure and surface functional groups.

ACS NANO (2021)

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Review Chemistry, Multidisciplinary

Status and Prospects of MXene-Based Lithium-Sulfur Batteries

Qian Zhao et al.

Summary: MXenes, with their metallic conductivity, strong chemical adsorption ability to polysulfides, and effective catalytic effect, show promising potential for high-performance Li-S batteries. Their use in sulfur cathode, interlayer between cathode and separator, and Li anode can enhance electrochemical performance and address challenges in Li-S battery application.

ADVANCED FUNCTIONAL MATERIALS (2021)

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Article Chemistry, Physical

Interface Catalysis of Nickel Molybdenum (NiMo) Alloys on Two-Dimensional (2D) MXene for Enhanced Hydrogen Electrochemistry

Tong Zhang et al.

Summary: Efficient bifunctional nonprecious metallic electrocatalysts have been developed by immobilizing transition-metal-based NiMo nanoparticles on 2D Ti3C2Tx surfaces, showing superior hydrogen evolution reaction (HER) and hydrogen oxidation reaction (HOR) activities in alkaline media. The Ti3C2Tx support facilitates charge transfer and tailors the electronic structure of catalytic sites, resulting in optimized adsorption free energies for hydrogen electrochemistry.

JOURNAL OF PHYSICAL CHEMISTRY LETTERS (2021)

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Article Chemistry, Inorganic & Nuclear

Facile fabrication of N-doped graphene/Ti3C2Tx (Mxene) aerogel with excellent electrocatalytic activity toward oxygen reduction reaction in fuel cells and metal-air batteries

Monireh Faraji et al.

Summary: The study successfully designed and prepared efficient, cost-effective, and durable non-platinum based electrocatalysts through the fabrication of a 3D porous N-doped graphene hybrid structure. These materials exhibited comparable catalytic activity to commercial platinum-based materials in the ORR, along with superior long-term stability.

JOURNAL OF SOLID STATE CHEMISTRY (2021)

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Article Energy & Fuels

Heterostructured MoSe2/Oxygen-Terminated Ti3C2 MXene Architectures for Efficient Electrocatalytic Hydrogen Evolution

Weiping Xiao et al.

Summary: The study successfully fabricated a 2D MoSe2/2D Ti3C2 MXene heterostructured architecture, leading to improved HER performance in terms of electrochemically active surface areas, oxygen-substituted surfaces, and the synergy effect between MoSe2 and MXene.

ENERGY & FUELS (2021)

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Article Chemistry, Physical

Single transition metal atom catalysts on Ti2CN2 for efficient CO2 reduction reaction

Feifei Li et al.

Summary: This study investigated the catalytic activity of single transition-metal atoms anchored on 2D Ti2CN2 for CO2RR, finding that Sc, Ti, and V show high catalytic activity for CO production, while Mn and Fe are active for HCOOH production. Additional electrons injection can tune the catalytic activity and selectivity.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2021)

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Article Chemistry, Physical

Two-Dimensional Carbonitride MXenes as an Efficient Electrocatalyst for Hydrogen Evolution

Bo Wei et al.

Summary: Carbonitride MXenes are highly desirable as potential electrocatalysts for the HER due to their excellent properties. This study explored the stable configurations of Mo-based carbonitride MXenes under various electrochemical environments, finding that O*/OH*-terminated Mo-based carbonitride MXenes exhibit the most stable state at ambient conditions with good catalytic activity for HER. The results provide a strategy to synthesize carbonitride MXenes with various surface functionalizations and design them through chemical doping and strain engineering.

JOURNAL OF PHYSICAL CHEMISTRY C (2021)

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Article Materials Science, Multidisciplinary

Ultrafine Pt stabilized on Ti3C2Tx/reduced graphene oxide nanocomposites for alcohol oxidation reaction (AOR)

Yunmeng Zhao et al.

Summary: Three-dimensional platinum/Ti3C2Tx-reduced graphene oxide catalyst prepared by solvothermal method exhibits superior electrocatalytic activity and stability for alcohol oxidation reaction, demonstrating its potential as an effective anode catalyst for direct alcohol fuel cells.

MATERIALS LETTERS (2021)

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Article Chemistry, Physical

Mechanisms of Hydrogen Evolution Reaction in Two-Dimensional Nitride MXenes Using In Situ X-Ray Absorption Spectroelectrochemistry

Abdoulaye Djire et al.

Summary: MXenes, based on early transition-metal carbides and nitrides, exhibit highly tunable electrochemical properties suitable for various catalytic reactions. Research has shown that modifying these MXenes can enhance their catalytic activity, such as in the hydrogen evolution reaction. Mechanistic studies using in situ X-ray absorption spectroscopy indicate that the creation of oxygen vacancies on the basal planes is crucial for the catalytic activity, providing insight for future electrocatalysis and photocatalysis schemes.

ACS CATALYSIS (2021)

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Article Multidisciplinary Sciences

A Mo5N6 electrocatalyst for efficient Na2S electrodeposition in room-temperature sodium-sulfur batteries

Chao Ye et al.

Summary: The Mo5N6 cathode material enables efficient Na2S electrodeposition, improving cycling performance in room-temperature sodium-sulfur batteries.

NATURE COMMUNICATIONS (2021)

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Article Chemistry, Physical

Late Transition Metal Doped MXenes Showing Superb Bifunctional Electrocatalytic Activities for Water Splitting via Distinctive Mechanistic Pathways

Rohit Anand et al.

Summary: In this study, it is demonstrated that late transition metal doping can significantly enhance the HER/OER activities of MXenes. By embedding a single Ni or Co atom into MXenes, it provides a suitable amount of electrons for optimal adsorbate evolving mechanism, resulting in activated lattice oxygen mechanism. The stability and bifunctional catalytic capability of MXene combinations towards both HER and OER are shown.

ADVANCED ENERGY MATERIALS (2021)

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Article Multidisciplinary Sciences

Vertically-interlaced NiFeP/MXene electrocatalyst with tunable electronic structure for high-efficiency oxygen evolution reaction

Jiexin Chen et al.

Summary: NiFeP/MXene materials with excellent oxygen evolution reaction (OER) performance have been successfully synthesized in this study, showing promise for efficient water splitting. By tuning the electronic structure and density, the material enhances the energy level of the catalyst surface, leading to superior OER performance.

SCIENCE BULLETIN (2021)

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Article Chemistry, Multidisciplinary

Lamellar MXene Composite Aerogels with Sandwiched Carbon Nanotubes Enable Stable Lithium-Sulfur Batteries with a High Sulfur Loading

Bin Zhang et al.

Summary: In this study, a lamellar aerogel composed of Ti3C2Tx MXene/carbon nanotube sandwiches was prepared to improve the cycling stability of high sulfur loading batteries. The unique parallel-aligned structure of the material effectively suppresses lithium polysulfide shuttling and enhances the confinement ability of LiPS, resulting in high capacity and superior cycling stability.

ADVANCED FUNCTIONAL MATERIALS (2021)

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Article Chemistry, Multidisciplinary

The Electrostatic Attraction and Catalytic Effect Enabled by Ionic-Covalent Organic Nanosheets on MXene for Separator Modification of Lithium-Sulfur Batteries

Pengyue Li et al.

Summary: This study proposes a new strategy to regulate the redox kinetics and shuttle effect of polysulfides by modifying a polypropylene separator with a coating layer of guanidinium-based ionic-covalent organic nanosheets (iCON) on the surface of Ti3C2. The synergistic effects of Ti3C2 and iCON effectively suppress the shuttle effect of polysulfides and accelerate the redox reactions of sulfur species, resulting in high-performance lithium-sulfur batteries.

ADVANCED MATERIALS (2021)

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Article Chemistry, Physical

Edge-oriented, high-percentage 1T′-phase MoS2 nanosheets stabilize Ti3C2 MXene for efficient electrocatalytic hydrogen evolution

Xitao Li et al.

Summary: This study successfully synthesized an efficient and stable MoS2-Ti3C2 MXene electrocatalyst using a one-step hydrothermal method, which has abundant active sites and high electrical conductivity, showing excellent electrocatalytic performance in acidic medium.

APPLIED CATALYSIS B-ENVIRONMENTAL (2021)

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Review Chemistry, Multidisciplinary

Recent Advances on MXene-Based Electrocatalysts toward Oxygen Reduction Reaction: A Focused Review

Shaik Gouse Peera et al.

Summary: MXenes are promising catalyst supports with potential for efficient oxygen reduction reaction (ORR) processes, showing good reactivity and stability when used with both Pt and non-Pt metals. However, there are limitations and challenges that need to be addressed for further development of MXene-based ORR catalysts.

ADVANCED MATERIALS INTERFACES (2021)

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Article Chemistry, Multidisciplinary

Facile Atomic-Level Tuning of Reactive Metal-Support Interactions in the Pt QDs@ HF-Free MXene Heterostructure for Accelerating pH-Universal Hydrogen Evolution Reaction

Sin-Yi Pang et al.

Summary: This study introduces a novel strategy to grow Pt quantum dots on MXene under atomic-level modulation reaction, forming efficient Pt (111) QDs 0D/1D heterostructure catalyst.

ADVANCED SCIENCE (2021)

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Article Chemistry, Multidisciplinary

Single-Atom-Substituted Mo2CTx:Fe-Layered Carbide for Selective Oxygen Reduction to Hydrogen Peroxide: Tracking the Evolution of the MXene Phase

Denis A. Kuznetsov et al.

Summary: This study critically assesses the electrocatalytic activity, stability, and nature of the active phase of a two-dimensional molybdenum carbide with single-atomic iron sites in the catalysis of the oxygen reduction reaction. The research revealed that the iron single sites transformed into active iron oxyhydroxide species, challenging previous studies on the activity of native MXene phases in oxygen electrocatalysis.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

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Article Chemistry, Physical

Engineering the Cu/Mo2CTx (MXene) interface to drive CO2 hydrogenation to methanol

Hui Zhou et al.

Summary: In this study, an optimized Cu/Mo2CTx interface was achieved through engineering methods, leading to higher efficiency in the catalytic conversion of CO2 to methanol. Density functional theory calculations confirmed the critical role of the interface between Cu and Mo2CTx in stabilizing reaction intermediates.

NATURE CATALYSIS (2021)

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Article Chemistry, Physical

Concurrent realization of dendrite-free anode and high-loading cathode via 3D printed N-Ti3C2 MXene framework toward advanced Li-S full batteries

Chaohui Wei et al.

Summary: A multifunctional 3D printed framework comprising nitrogen-doped porous Ti3C2MXene is proposed to regulate both electrodes of Li-S batteries. The framework possesses high conductivity and ample nitrogen sites for synergizing lithiophilic-sulfiphilic feature.

ENERGY STORAGE MATERIALS (2021)

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Review Chemistry, Physical

Electrochemical reduction of nitrogen to ammonia: Progress, challenges and future outlook

Carmen Lee et al.

Summary: The article provides a brief overview of the current progress and challenges of the electrochemical nitrogen reduction reaction (NRR) to synthesize ammonia. Different types of electrocatalysts and their design principles are discussed, but most show unsatisfactory catalytic performance for NRR due to various factors. Future outlook includes exploring alternative external energy inputs such as cold plasma and surface plasmon resonance to improve NRR performance.

CURRENT OPINION IN ELECTROCHEMISTRY (2021)

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Article Chemistry, Multidisciplinary

Intralayered Ostwald Ripening-Induced Self-Catalyzed Growth of CNTs on MXene for Robust Lithium-Sulfur Batteries

Mengyao Xu et al.

Summary: The synthesis of Ti3C2Tx-CNTs hybrids without the addition of catalyst precursors allows for the uniform precipitation of catalysts and the formation of CNTs with high integrity on the surface of Ti3C2Tx, making them ideal 3D scaffolds for accommodating sulfur and regulating the polysulfides conversion in lithium-sulfur batteries.

SMALL (2021)

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Article Nanoscience & Nanotechnology

Promoting N2 electroreduction to ammonia by fluorine-terminating Ti3C2Tx MXene

Yu Ding et al.

Summary: In this study, a Ti3C2Tx MXene with a medium density of surface functionalized fluorine terminal groups was reported as an excellent catalyst for N-2 reduction reaction, showing enhanced adsorption and activation of N-2. The Ti3C2Tx MXene catalyst exhibited a high production rate of ammonia, partial current density, and Faradic efficiency, surpassing similar MXene catalysts with higher or lower densities of surface fluorine terminal groups. This work highlights the potential of developing surface functionalization toolkit to enhance the electrochemical catalytic activities of two-dimensional MXene-based materials.

NANO CONVERGENCE (2021)

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Article Nanoscience & Nanotechnology

Theoretical Approach toward Optimum Anion-Doping on MXene Catalysts for Hydrogen Evolution Reaction: an Ab Initio Thermodynamics Study

Hyunjun Nam et al.

Summary: Developing highly active catalysts for hydrogen evolution reaction using earth-abundant materials is challenging. Recent studies have shown that nitrogen doping can improve the catalytic properties of titanium carbide MXene, but systematic doping engineering has not been well controlled, which hinders the reliable production of high-activity MXene catalysts. This study investigates the optimal nitrogen doping concentration and process conditions on O-functionalized Ti2C MXene for the hydrogen evolution reaction using density functional theory and thermodynamics. It was found that 8.8 at % nitrogen-doped Ti2CO2 demonstrated the best catalytic properties under standard conditions, with a deterioration in catalytic properties observed at higher doping concentrations.

ACS APPLIED MATERIALS & INTERFACES (2021)

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Article Chemistry, Multidisciplinary

Rational Design of Highly Stable and Active MXene-Based Bifunctional ORR/OER Double-Atom Catalysts

Bo Wei et al.

Summary: Designing highly active and bifunctional oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) catalysts with non-noble metals such as Fe/Co/Ni on MXene surfaces has shown superior performance compared to traditional unifunctional catalysts, providing a novel pathway for tunable catalytic behavior in MXenes. The electronic structure analyses revealed that the excellent catalytic activities in MXene-based DACs are attributed to the electron-capturing capability and synergistic interactions between Fe/Co/Ni adsorbents and MXene substrate. These findings not only suggest promising candidates for MXene-based bifunctional ORR/OER catalysts but also offer new theoretical insights into rationally designing noble-metal-free bifunctional DACs.

ADVANCED MATERIALS (2021)

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Review Chemistry, Multidisciplinary

Comprehensive Understanding of the Thriving Ambient Electrochemical Nitrogen Reduction Reaction

Xue Zhao et al.

Summary: The electrochemical nitrogen reduction reaction, which produces ammonia, is environmentally friendly and suitable for rural economy, but faces challenges in catalysts and quantitative determination.

ADVANCED MATERIALS (2021)

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Article Engineering, Environmental

Tunable nitrogen-doped delaminated 2D MXene obtained by NH3/Ar plasma treatment as highly efficient hydrogen and oxygen evolution reaction electrocatalyst

Xunxin Chen et al.

Summary: The structural properties and nitrogen content of MXene can be adjusted by controlling the volume ratio of NH3 and Ar in plasma gas, leading to improved electrocatalytic performance.

CHEMICAL ENGINEERING JOURNAL (2021)

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Review Chemistry, Physical

Recent advances in two-dimensional Pt based electrocatalysts for methanol oxidation reaction

Hao Tian et al.

Summary: Direct methanol fuel cells (DMFCs) have attracted attention for their high energy density, but the slow kinetics of methanol oxidation reaction affects commercialization. Pt based catalysts are effective but expensive, while 2D Pt based nanostructures are considered promising for MOR.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2021)

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Article Chemistry, Physical

Modulating oxygen electronic orbital occupancy of Cr-based MXenes via transition metal adsorbing for optimal HER activity

Xilin Zhang et al.

Summary: Modulating surface electronic properties of 2D MXenes using transition metal adatoms can enhance hydrogen evolution reaction activity, with optimal performance achieved by depositing Cr atom on Cr2TiC2O2 MXene. Charge transfer from transition metals to surface oxygen atoms plays a critical role in tuning hydrogen adsorption strength and HER activity.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2021)

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Article Chemistry, Analytical

Fabrication of 3D interconnected porous MXene-based PtNPs as highly efficient electrocatalysts for methanol oxidation

Qiang Zhang et al.

Summary: In this study, Pt nanoparticles attached on 3D porous embossed MXene were prepared to enhance the catalytic performance and stability towards methanol oxidation reaction. A 3D interconnected porous structure was fabricated using sacrificial templates to prevent restacking of MXene nanosheets, enabling rapid electrical/ionic transport. The synthesized Pt/e-MXene composites exhibited significantly improved electrocatalytic activity and durability compared to other catalysts, providing a new guide for designing aggregation-resistant 3D porous MXene with high performance in catalysis.

JOURNAL OF ELECTROANALYTICAL CHEMISTRY (2021)

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Article Chemistry, Physical

Tuning the Activity of Molybdenum Carbide MXenes for CO2 Electroreduction by Embedding the Single Transition-Metal Atom

Yue Zhang et al.

Summary: M@Mo2C MXenes, such as Fe@Mo2C and Co@Mo2C, show higher activity and selectivity towards CO2 reduction to CH4, highlighting potential as promising electrocatalysts for CO2 reduction to methane or methanol at low overpotentials. Additionally, Fe@Mo2C may also reduce CO2 to C2H4 and CH3CH2OH, demonstrating its potential as a 2D electrocatalytic material for CO2 reduction to C1 and C2 products.

JOURNAL OF PHYSICAL CHEMISTRY C (2021)

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Article Chemistry, Physical

Integrated Co4MnFe3/Ti3C2: Componential and Structural Engineering toward Boosting Electrocatalytic Oxygen Evolution

Chengqiang Gan et al.

Summary: MXene, as an ideal substrate material with metal-like conductivity and hydrophilicity, shows promising application prospects in the field of electrocatalytic water decomposition. This study successfully synthesized Co4MnFe3/Ti3C2 using ultrathin two-dimensional layered Ti3C2 as substrate material, exhibiting excellent electrochemical performance in alkaline media.

JOURNAL OF PHYSICAL CHEMISTRY C (2021)

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Article Electrochemistry

Construction of Ti3C2T x MXene Supported Low-Platinum Electrocatalyst for Hydrogen Evolution Reaction by Direct Electrochemical Strategy

Xuan Jian et al.

Summary: A high-performance catalyst with ultralow-Pt nanoclusters on a two-dimensional titanium carbide MXene support was synthesized using electrophoretic deposition and cyclic voltammetry. The catalyst showed lower overpotential and Tafel slope compared to commercial Pt/C catalyst, with significantly higher turnover frequency and mass activity. Additionally, it exhibited stable performance in a long-term cycling test.

JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2021)

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Article Chemistry, Physical

FeNi nanoparticles on Mo2TiC2Tx MXene@nickel foam as robust electrocatalysts for overall water splitting

Jiayang Wang et al.

Summary: Synthesis of composite FeNi@Mo2TiC2Tx@NF with high HER and OER activity through introducing Fe2+ ions and combining with surface nickel atoms, provides a new strategy for overall water splitting.

NANO RESEARCH (2021)

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Review Chemistry, Multidisciplinary

MXenes as Superexcellent Support for Confining Single Atom: Properties, Synthesis, and Electrocatalytic Applications

Mingming Zhang et al.

Summary: MXenes serve as excellent supports for SACs due to their large specific surface area and superior electronic conductivity. The structure and property of MXenes can be manipulated by changing transition metal elements and surface termination.

SMALL (2021)

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Article Chemistry, Multidisciplinary

Tuning the Chemical Properties of Co-Ti3C2Tx MXene Materials for Catalytic CO2 Reduction

Jun Ma et al.

Summary: This study demonstrates that the surface reducibility of Ti3C2Tx MXene can be tuned by N doping, leading to a change in the catalytic properties of supported Co nanoparticles. Pristine Co-Ti3C2Tx MXene favors CO production during CO2 hydrogenation, whereas CH4 production is favored when the MXene is subjected to N doping.

SMALL (2021)

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Article Chemistry, Multidisciplinary

Highly Dispersed Ru Nanoparticles on Boron-Doped Ti3C2Tx (MXene) Nanosheets for Synergistic Enhancement of Electrocatalytic Hydrogen Evolution

Munkhjargal Bat-Erdene et al.

Summary: Doped MXene nanosheets with boron were developed as a solid support for hosting ruthenium nanoparticles for electrocatalytic hydrogen evolution. Theoretical calculations and experimental tests showed that boron doping can enhance reactivity and electrode kinetics of active sites, leading to improved catalytic activity.

SMALL (2021)

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Article Chemistry, Multidisciplinary

Synergistic Enhancement of Electrocatalytic Nitrogen Reduction Over Boron Nitride Quantum Dots Decorated Nb2CTx-MXene

Ke Chu et al.

Summary: A novel hexagonal BN quantum dots (BNQDs) decorated Nb2CTx-MXene (BNQDs@Nb2CTx) has been explored as an efficient NRR catalyst, which shows optimum NRR activity, high Faradaic efficiency, and excellent stability, outperforming most of the state-of-the-art NRR catalysts. The synergistic interplay of BNQDs and Nb2CTx creates unique interfacial B sites serving as NRR catalytic centers, enhancing N-2 activation and impeding H-2 evolution.

SMALL (2021)

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Article Chemistry, Physical

Hierarchically structured Ti3C2Tx MXene paper for Li-S batteries with high volumetric capacity

Wenli Zhao et al.

Summary: This study explores the use of MXene as a new host material to improve the electrochemical performance of Li-S batteries, successfully increasing the volumetric energy density of the batteries. Experimental results show that Ti-OH bonds in the MXene membrane effectively trigger the transformation of LiPS, and the stable charge product alpha-S-8 plays a potential important role in reducing active mass loss and enhancing cycling capability in the battery.

NANO ENERGY (2021)

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Article Chemistry, Physical

A simple approach to synthesis Cr2CTx MXene for efficient hydrogen evolution reaction

Xinshu Zou et al.

Summary: This study proposes a simple strategy for synthesizing ultra-thin Cr2CTx MXenes with superior performance in hydrogen evolution reaction and high stability. The fabricated material exceeds even Pt catalyst in terms of performance, showcasing potential for practical applications.

MATERIALS TODAY ENERGY (2021)

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Article Materials Science, Multidisciplinary

Synthesis of new two-dimensional titanium carbonitride Ti2C0.5N0.5Tx MXene and its performance as an electrode material for sodium-ion battery

Kun Liang et al.

Summary: A new 2D carbonitride MXene material, Ti2C0.5N0.5Tx, was reported in this study, showing higher specific capacities and larger electroactive surface area compared to traditional Ti2CTx powders. The multilayer Ti2C0.5N0.5Tx powders exhibited a specific capacity of 182 mAh g-1 at 20 mA g-1, the highest among reported MXene electrodes for SIBs, with excellent cycling stability.

INFOMAT (2021)

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Article Chemistry, Physical

Rose-like, ruthenium-modified cobalt nitride nanoflowers grown in situ on an MXene matrix for efficient and stable water electrolysis

Liang Yan et al.

Summary: A novel bifunctional electrocatalyst, Ru-CoN/Ti3C2Tx MXene, has been synthesized with good conductivity and optimized electronic structure, displaying remarkable and stable performance in water electrolysis for both hydrogen and oxygen evolution reactions. This work provides a new strategy for the design and fabrication of efficient and nonprecious catalysts for electrochemical energy systems.

JOURNAL OF MATERIALS CHEMISTRY A (2021)

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Article Chemistry, Physical

Constructing an electron-rich interface over an Sb/Nb2CTx-MXene heterojunction for enhanced electrocatalytic nitrogen reduction

Xingchuan Li et al.

Summary: In this study, a highly efficient NRR catalyst Sb/Nb2CTx was reported, achieving high NH3 yield and selectivity. Density functional theory calculations revealed the mechanism behind the excellent performance of this catalyst.

JOURNAL OF MATERIALS CHEMISTRY A (2021)

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Article Chemistry, Physical

Pt-on-Pd bimetallic nanodendrites stereoassembled on MXene nanosheets for use as high-efficiency electrocatalysts toward the methanol oxidation reaction

Cuizhen Yang et al.

Summary: The stereoassembly of 3D porous Pt-on-Pd bimetallic nanodendrites on a 2D ultrathin Ti3C2Tx MXene matrix results in a Pt-on-Pd/Ti3C2Tx catalyst with superior electrocatalytic properties towards methanol oxidation, attributed to numerous accessible electrocatalytically active sites and optimized electronic structures. Density functional theory calculations reveal significant down shift of d-band centers and weaker CO adsorption ability for the Pt-on-Pd/Ti3C2Tx model, leading to stronger poisoning tolerance and enhanced methanol oxidation activity.

JOURNAL OF MATERIALS CHEMISTRY A (2021)

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Article Chemistry, Applied

Catalytic activity of V2CO2 MXene supported transition metal single atoms for oxygen reduction and hydrogen oxidation reactions: A density functional theory calculation study

Zhongjing Deng et al.

Summary: The research investigates the potential of TM single atoms supported by V2CO2 in two-dimensional materials for ORR and HOR catalysis, finding that Mn- and Sc-V2CO2 exhibit high catalytic activity and stability, serving as excellent bifunctional catalysts for fuel cells.

CHINESE JOURNAL OF CATALYSIS (2021)

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Review Chemistry, Multidisciplinary

Pyrolyzed M-Nx catalysts for oxygen reduction reaction: progress and prospects

Ergui Luo et al.

Summary: Recent research efforts on cost-effective catalysts in fuel cells, especially on the cathode, have shown promising advancements in the development of M-N-x/C materials. The focus has been on clarifying the nature of catalytic sites and utilizing advanced characterization tools to optimize synthesis methodologies. Future directions aim to achieve rational and controllable synthesis of catalysts with sufficient active sites and strategies to mitigate catalyst degradation.

ENERGY & ENVIRONMENTAL SCIENCE (2021)

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Article Chemistry, Multidisciplinary

Ni nanoparticles/V4C3Tx MXene heterostructures for electrocatalytic nitrogen fixation

Cheng-Feng Du et al.

Summary: This study reports a highly efficient NRR electrocatalyst by loading Ni nanoparticles on V4C3Tx MXene, which exhibits significantly improved NRR activity compared to other MXene derivatives and even comparable to noble-metal-based electrocatalysts. The enhanced NRR performance is attributed to a synergistic NRR route by Ni sites in the nanoparticles and the surface O vacancy of V4C3Tx MXene, demonstrating the critical role of MXene and its derivatives with surface modification as electrocatalysts.

MATERIALS CHEMISTRY FRONTIERS (2021)

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Article Chemistry, Multidisciplinary

Heteroatom coordination induces electric field polarization of single Pt sites to promote hydrogen evolution activity†

Xianyun Peng et al.

Summary: Pt-SA/MXene catalyst shows efficient hydrogen evolution reaction (HER) activity in alkaline electrolytes with low overpotential and long-term stability. It has competitive mass activity and improved catalytic performance due to its unique structure and polarized electric field effect.

NANOSCALE (2021)

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Article Chemistry, Multidisciplinary

Electrocatalytic CO2 reduction on earth abundant 2D Mo2C and Ti3C2 MXenes

Nuwan H. Attanayake et al.

Summary: Mo2C and Ti3C2 MXenes show high efficiency as electrocatalysts for the CO2 reduction reaction, with Mo2C exhibiting a faradaic efficiency of 90% and Ti3C2 exhibiting a faradaic efficiency of 65%. The use of an ionic liquid electrolyte suppresses the competing hydrogen evolution reaction, allowing for improved CO2 reduction efficiency.

CHEMICAL COMMUNICATIONS (2021)

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Article Chemistry, Multidisciplinary

A two-dimensional MXene-supported metal-organic framework for highly selective ambient electrocatalytic nitrogen reduction

Xingyou Liang et al.

Summary: The study successfully prepared a ZIF-67@Ti3C2 catalyst for efficient electrochemical synthesis of ammonia, demonstrating excellent NH3 yield and good Faraday efficiency. The successful preparation of this catalyst expands the application of the MXene family in the electrochemical nitrogen reduction reaction.

NANOSCALE (2021)

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Article Chemistry, Multidisciplinary

A hybrid plasma electrocatalytic process for sustainable ammonia production

Jing Sun et al.

Summary: The research team successfully developed a non-thermal plasma bubble column reactor to convert NOx intermediaries into ammonia at ambient conditions. Their innovative approach combines plasma-driven nitrogen oxides generation with electrocatalytic reduction for scalable green ammonia production.

ENERGY & ENVIRONMENTAL SCIENCE (2021)

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Article Chemistry, Physical

Uncovering the electrochemical mechanisms for hydrogen evolution reaction of heteroatom doped M2C MXene (M = Ti, Mo)

Bo Ding et al.

APPLIED SURFACE SCIENCE (2020)

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Article Chemistry, Physical

In situ fabrication of 1D CdS nanorod/2D Ti3C2 MXene nanosheet Schottky heterojunction toward enhanced photocatalytic hydrogen evolution

Rong Xiao et al.

APPLIED CATALYSIS B-ENVIRONMENTAL (2020)

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Review Chemistry, Physical

3D Carbon Materials for Efficient Oxygen and Hydrogen Electrocatalysis

Ana Belen Jorge et al.

ADVANCED ENERGY MATERIALS (2020)

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Article Chemistry, Multidisciplinary

MXene-Supported FeCo-LDHs as Highly Efficient Catalysts for Enhanced Electrocatalytic Oxygen Evolution Reaction

Ming Tian et al.

CHEMNANOMAT (2020)

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CO2 Reduction: From Homogeneous to Heterogeneous Electrocatalysis

Sheng Zhang et al.

ACCOUNTS OF CHEMICAL RESEARCH (2020)

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MXene Surface Terminations Enable Strong Metal-Support Interactions for Efficient Methanol Oxidation on Palladium

Zhiquan Lang et al.

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Synthesis of Mo4VAlC4 MAX Phase and Two-Dimensional Mo4VC4 MXene with Five Atomic Layers of Transition Metals

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Iron-Cluster-Directed Synthesis of 2D/2D Fe-N-C/MXene Superlattice-like Heterostructure with Enhanced Oxygen Reduction Electrocatalysis

Lili Jiang et al.

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A Novel Approach for Achieving High-Efficiency Photoelectrochemical Water Oxidation in InGaN Nanorods Grown on Si System: MXene Nanosheets as Multifunctional Interfacial Modifier

Jing Lin et al.

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Facile CO Oxidation on Oxygen-functionalized MXenes via the Mars-van Krevelen Mechanism

Hassan A. Tahini et al.

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Current Challenges and Routes Forward for Nonaqueous Lithium-Air Batteries

Tao Liu et al.

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Platinum Nanoparticle-Deposited Ti3C2Tx MXene for Hydrogen Evolution Reaction

Xiaobao Zhang et al.

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Pd/MXene(Ti3C2Tx)/reduced graphene oxide hybrid catalyst for methanol electrooxidation

Peng Zhang et al.

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Molecular enhancement of heterogeneous CO2 reduction

Dae-Hyun Nam et al.

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MXene Materials for the Electrochemical Nitrogen Reduction-Functionalized or Not?

Luke R. Johnson et al.

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Ambient Growth of Hierarchical FeOOH/MXene as Enhanced Electrocatalyst for Oxygen Evolution Reaction

Kaixin Zhao et al.

CHEMISTRYSELECT (2020)

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Realization of 2D crystalline metal nitrides via selective atomic substitution

Jun Cao et al.

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MXene (Ti3C2Tx) and Carbon Nanotube Hybrid-Supported Platinum Catalysts for the High-Performance Oxygen Reduction Reaction in PEMFC

Chenxi Xu et al.

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Polyelectrolyte-Induced Stereoassembly of Grain Boundary-Enriched Platinum Nanoworms on Ti3C2Tx MXene Nanosheets for Efficient Methanol Oxidation

Cuizhen Yang et al.

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Basal Plane Hydrogen Evolution Activity from Mixed Metal Nitride MXenes Measured by Scanning Electrochemical Microscopy

Abdoulaye Djire et al.

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Ultrastable MXene@Pt/SWCNTs' Nanocatalysts for Hydrogen Evolution Reaction

Cong Cui et al.

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MXene Printing and Patterned Coating for Device Applications

Yi-Zhou Zhang et al.

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Transition metal atoms implanted into MXenes (M2CO2) for enhanced electrocatalytic hydrogen evolution reaction

Zhenhua Chen et al.

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Cu Anchored Ti2NO2as High Performance Electrocatalyst for Oxygen Evolution Reaction: A Density Functional Theory Study

Zhiguo Chen et al.

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Modulating interfacial electronic structure of CoNi LDH nanosheets with Ti3C2Tx MXene for enhancing water oxidation catalysis

Liuyong Hu et al.

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Pt nanowire/Ti3C2Tx-CNT hybrids catalysts for the high performance oxygen reduction reaction for high temperature PEMFC

Ranran Wang et al.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2020)

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3d transitional-metal single atom catalysis toward hydrogen evolution reaction on MXenes supports

Zihan Shen et al.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2020)

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Anchoring Co3O4 nanoparticles on MXene for efficient electrocatalytic oxygen evolution

Yi Lu et al.

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Spontaneous Atomic Ruthenium Doping in Mo2CTX MXene Defects Enhances Electrocatalytic Activity for the Nitrogen Reduction Reaction

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Rational Design of Hydroxyl-Rich Ti3C2Tx MXene Quantum Dots for High-Performance Electrochemical N2 Reduction

Zhaoyong Jin et al.

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Rational design of porous nitrogen-doped Ti3C2 MXene as a multifunctional electrocatalyst for Li-S chemistry

Yingze Song et al.

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The High-Performance Bifunctional Catalyst Pd/Ti3C2Tx-Carbon Nanotube for Oxygen Reduction Reaction and Hydrogen Evolution Reaction in Alkaline Medium

Peng Zhang et al.

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Efficient Energy Conversion and Storage Based on Robust Fluoride-Free Self-Assembled 1D Niobium Carbide in 3D Nanowire Network

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A general Lewis acidic etching route for preparing MXenes with enhanced electrochemical performance in non-aqueous electrolyte

Youbing Li et al.

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Lattice-confined Ru clusters with high CO tolerance and activity for the hydrogen oxidation reaction

Yuanyuan Zhou et al.

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Iontronics Using V2CTx MXene-Derived Metal-Organic Framework Solid Electrolytes

Xiangming Xu et al.

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Highly Efficient Electrochemical Reduction of Nitrogen to Ammonia on Surface Termination Modified Ti3C2Tx MXene Nanosheets

Ying Guo et al.

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Rational Design of Two-Dimensional Transition Metal Carbide/Nitride (MXene) Hybrids and Nanocomposites for Catalytic Energy Storage and Conversion

Kang Rui Garrick Lim et al.

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Recent Progress in MXene-Based Materials: Potential High-Performance Electrocatalysts

Anmin Liu et al.

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Catalytic Conversion of Polysulfides on Single Atom Zinc Implanted MXene toward High-Rate Lithium-Sulfur Batteries

Di Zhang et al.

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Heterogeneous Single-Atom Catalysts for Electrochemical CO2Reduction Reaction

Minhan Li et al.

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Boosting electrosynthesis of ammonia on surface-engineered MXene Ti3C2

Jiexiang Xia et al.

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Two-Dimensional Titanium and Molybdenum Carbide MXenes as Electrocatalysts for CO2 Reduction

Albertus D. Handoko et al.

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Strongly Coupled NiCo2O4 Nanocrystal/MXene Hybrid through In Situ Ni/Co-F Bonds for Efficient Wearable Zn-Air Batteries

Hang Lei et al.

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Interface Chemistry on MXene-Based Materials for Enhanced Energy Storage and Conversion Performance

Xiaobin Hui et al.

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Defect-Enhanced CO2Reduction Catalytic Performance in O-Terminated MXenes

Hetian Chen et al.

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Theoretical Study of Transition-Metal-Modified Mo2CO2MXene as a Catalyst for the Hydrogen Evolution Reaction

Jinyu Gan et al.

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Covalent surface modifications and superconductivity of two-dimensional metal carbide MXenes

Vladislav Kamysbayev et al.

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Trifunctional Single-Atomic Ru Sites Enable Efficient Overall Water Splitting and Oxygen Reduction in Acidic Media

Xianyun Peng et al.

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Direct insights into the role of epoxy groups on cobalt sites for acidic H2O2 production

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Electrocatalytic Hydrogen Evolution of Ultrathin Co-Mo5N6Heterojunction with Interfacial Electron Redistribution

Fei Lin et al.

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One-Step Synthesis of Modified Ti3C2 MXene-Supported Amorphous Molybdenum Sulfide Electrocatalysts by a Facile Gamma Radiation Strategy for Efficient Hydrogen Evolution Reaction

Shuangxiao Li et al.

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2H-MoS2 on Mo2CTx MXene Nanohybrid for Efficient and Durable Electrocatalytic Hydrogen Evolution

Kang Rui Garrick Lim et al.

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Two dimensional electrocatalyst engineering via heteroatom doping for electrocatalytic nitrogen reduction

Yuanyuan Yang et al.

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Defect engineering for electrochemical nitrogen reduction reaction to ammonia

Chenhuai Yang et al.

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Construction of Ti3C2 supported hybrid Co3O4/NCNTs composite as an efficient oxygen reduction electrocatalyst

Jing Liu et al.

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Highly efficient N2 fixation catalysts: transition-metal carbides M2C (MXenes)

Shuo Wang et al.

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A general approach to the synthesis of transition metal phosphide nanoarrays on MXene nanosheets for pH-universal hydrogen evolution and alkaline overall water splitting

Liang Yan et al.

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Confined growth of pyridinic N-Mo2C sites on MXenes for hydrogen evolution

Hao Wang et al.

JOURNAL OF MATERIALS CHEMISTRY A (2020)

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A two-dimensional Ru@MXene catalyst for highly selective ambient electrocatalytic nitrogen reduction

Anmin Liu et al.

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Rational design of bifunctional ORR/OER catalysts based on Pt/Pd-doped Nb2CT2 MXene by first-principles calculations

Dongxiao Kan et al.

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The effect of in situ nitrogen doping on the oxygen evolution reaction of MXenes

Yi Tang et al.

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MXene and MXene-based composites: synthesis, properties and environment-related applications

Xiaoxue Zhan et al.

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Hierarchical nanoroll like MoS2/Ti3C2Tx hybrid with high electrocatalytic hydrogen evolution activity

Jiapeng Liu et al.

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Pt decorated Ti3C2 MXene for enhanced methanol oxidation reaction

Yajing Wang et al.

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Titanium oxide-Ti3C2 hybrids as sulfur hosts in lithium-sulfur battery: Fast oxidation treatment and enhanced polysulfide adsorption ability

Hong Pan et al.

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Oxygen-Functionalized Ultrathin Ti3C2Tx MXene for Enhanced Electrocatalytic Hydrogen Evolution

Yanan Jiang et al.

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Unifying the Hydrogen Evolution and Oxidation Reactions Kinetics in Base by Identifying the Catalytic Roles of Hydroxyl-Water-Cation Adducts

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MXene (Ti3C2) Vacancy-Confined Single-Atom Catalyst for Efficient Functionalization of CO2

Di Zhao et al.

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Decorating g-C3N4 Nanosheets with Ti3C2 MXene Nanoparticles for Efficient Oxygen Reduction Reaction

Xuelian Yu et al.

LANGMUIR (2019)

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Facile synthesis of hierarchical NaTi2(PO4)3/Ti3C2 nanocomposites with superior sodium storage performance

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Ruthenium atomically dispersed in carbon outperforms platinum toward hydrogen evolution in alkaline media

Bingzhang Lu et al.

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High-Performance Electrocatalytic Conversion of N2 to NH3 Using Oxygen-Vacancy-Rich TiO2 In Situ Grown on Ti3C2Tx MXene

Yanfeng Fang et al.

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Boosting redox activity on MXene-induced multifunctional collaborative interface in high Li2S loading cathode for high-energy Li-S and metallic Li-free rechargeable batteries

Zhiyu Wang et al.

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A Robust, Freestanding MXene-Sulfur Conductive Paper for Long-Lifetime Li-S Batteries

Huan Tang et al.

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Hydrogen Evolution and Oxidation: Mechanistic Studies and Material Advances

Xiaoyu Tian et al.

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In Situ Hydrothermal Growth of TiO2 Nanoparticles on a Conductive Ti3C2Tx MXene Nanosheet: A Synergistically Active Ti-Based Nanohybrid Electrocatalyst for Enhanced N2 Reduction to NH3 at Ambient Conditions

Jie Zhang et al.

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Universal Strategy for HF-Free Facile and Rapid Synthesis of Two-dimensional MXenes as Multifunctional Energy Materials

Sin-Yi Pang et al.

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Optimal bulk-heterojunction morphology enabled by fibril network strategy for high-performance organic solar cells

Tian Xia et al.

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Surface Modified MXene-Based Nanocomposites for Electrochemical Energy Conversion and Storage

Hong Yu et al.

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Ultrathin Ti3C2Tx (MXene) Nanosheet-Wrapped NiSe2 Octahedral Crystal for Enhanced Supercapacitor Performance and Synergetic Electrocatalytic Water Splitting

Hanmei Jiang et al.

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MXene Boosted CoNi-ZIF-67 as Highly Efficient Electrocatalysts for Oxygen Evolution

Yangyang Wen et al.

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Synergy of Nb Doping and Surface Alloy Enhanced on Water-Alkali Electrocatalytic Hydrogen Generation Performance in Ti-Based MXene

Cheng-Feng Du et al.

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Synergistic Electrocatalytic Nitrogen Reduction Enabled by Confinement of Nanosized Au Particles onto a Two-Dimensional Ti3C2 Substrate

Dan Liu et al.

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Precious-Metal-Free Electrocatalysts for Activation of Hydrogen Evolution with Nonmetallic Electron Donor: Chemical Composition Controllable Phosphorous Doped Vanadium Carbide MXene

Yeoheung Yoon et al.

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Nitrogen Vacancies on 2D Layered W2N3: A Stable and Efficient Active Site for Nitrogen Reduction Reaction

Huanyu Jin et al.

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Single Pt atoms stabilized on Mo2TiC2O2 for hydrogen evolution: A first-principles investigation

Tao Jing et al.

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Theoretical Prediction of Catalytic Activity of Ti2C MXene as Cathode for Li-O2 Batteries

Yingying Yang et al.

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In Situ Formed Pt3Ti Nanoparticles on a Two-Dimensional Transition Metal Carbide (MXene) Used as Efficient Catalysts for Hydrogen Evolution Reactions

Zhe Li et al.

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Engineering Multifunctional Collaborative Catalytic Interface Enabling Efficient Hydrogen Evolution in All pH Range and Seawater

Xianhong Wu et al.

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MXene-Based Co, N-Codoped Porous Carbon Nanosheets Regulating Polysulfides for High-Performance Lithium-Sulfur Batteries

Jingtao Wang et al.

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Catalytic Effect on CO2 Electroreduction by Hydroxyl-Terminated Two-Dimensional MXenes

Hetian Chen et al.

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A General Atomic Surface Modification Strategy for Improving Anchoring and Electrocatalysis Behavior of Ti3C2T2 MXene in Lithium-Sulfur Batteries

Dashuai Wang et al.

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Boosting Performance of Na-S Batteries Using Sulfur-Doped Ti3C2Tx MXene Nanosheets with a Strong Affinity to Sodium Polysulfides

Weizhai Bao et al.

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N-Butyllithium-Treated Ti3C2Tx MXene with Excellent Pseudocapacitor Performance

Xifan Chen et al.

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Preparation of Pt/(Ti3C2Tx)y-(MWCNTs)1-y electrocatalysts via a facile and scalable solvothermal strategy for high-efficiency methanol oxidation

Xin Zhang et al.

APPLIED CATALYSIS A-GENERAL (2019)

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Porous Mo2C nanorods as an efficient catalyst for the hydrogen evolution reaction

Yufei Zhao et al.

JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS (2019)

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Single Site Cobalt Substitution in 2D Molybdenum Carbide (MXene) Enhances Catalytic Activity in the Hydrogen Evolution Reaction

Denis A. Kuznetsov et al.

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Synergistic Effects of Nitrogen Doping on MXene for Enhancement of Hydrogen Evolution Reaction

Thi Anh Le et al.

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A hierarchically porous and hydrophilic 3D nickel-iron/MXene electrode for accelerating oxygen and hydrogen evolution at high current densities

Mengzhou Yu et al.

NANO ENERGY (2019)

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VO2(p)-V2C(MXene) Grid Structure as a Lithium Polysulfide Catalytic Host for High-Performance Li-S Battery

Zhenguo Wang et al.

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Heteroatom-Mediated Interactions between Ruthenium Single Atoms and an MXene Support for Efficient Hydrogen Evolution

Vinoth Ramalingam et al.

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Rational Design of Flexible Two-Dimensional MXenes with Multiple Functionalities

Zhongheng Fu et al.

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Ultrafine Pt Nanoparticle-Decorated 3D Hybrid Architectures Built from Reduced Graphene Oxide and MXene Nanosheets for Methanol Oxidation

Cuizhen Yang et al.

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Electrochemical Nitrogen Reduction Reaction Performance of Single-Boron Catalysts Tuned by MXene Substrates

Shisheng Zheng et al.

JOURNAL OF PHYSICAL CHEMISTRY LETTERS (2019)

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Surface and Heterointerface Engineering of 2D MXenes and Their Nanocomposites: Insights into Electro- and Photocatalysis

Jiahe Peng et al.

CHEM (2019)

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Termination Effects of Pt/v-Tin+1CnT2 MXene Surfaces for Oxygen Reduction Reaction Catalysis

Chi-You Liu et al.

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Boosting the Photocatalytic Ability of Cu2O Nanowires for CO2 Conversion by MXene Quantum Dots

Zhiping Zeng et al.

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MXene Supported Cobalt Layered Double Hydroxide Nanocrystals: Facile Synthesis Route for a Synergistic Oxygen Evolution Reaction Electrocatalyst

Mohamed Benchakar et al.

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Multiwall carbon nanotubes loaded with MoS2 quantum dots and MXene quantum dots: Non-Pt bifunctional catalyst for the methanol oxidation and oxygen reduction reactions in alkaline solution

Xinli Yang et al.

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1T/2H MoSe2-on-MXene heterostructure as bifunctional electrocatalyst for efficient overall water splitting

Nan Li et al.

ELECTROCHIMICA ACTA (2019)

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MXene Derived Metal-Organic Frameworks

Hao Wu et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2019)

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Tuning the Coordination Environment in Single-Atom Catalysts to Achieve Highly Efficient Oxygen Reduction Reactions

Jinqiang Zhang et al.

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Impact of strain on the excitonic linewidth in transition metal dichalcogenides

Zahra Khatibi et al.

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Synchronous Gains of Areal and Volumetric Capacities in Lithium-Sulfur Batteries Promised by Flower-like Porous Ti3C2Tx Matrix

Zhubing Xiao et al.

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Fluorine-free Ti3C2Tx (T = O, OH) nanosheets (∼50-100 nm) for nitrogen fixation under ambient conditions

Tengfei Li et al.

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Self-Assembled 3D MnO2 Nanosheets@Delaminated-Ti3C2 Aerogel as Sulfur Host for Lithium-Sulfur Battery Cathodes

Heng Zhang et al.

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Theoretical Screening of Single Transition Metal Atoms Embedded in MXene Defects as Superior Electrocatalyst of Nitrogen Reduction Reaction

Lei Li et al.

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The hydrogen evolution reaction: from material to interfacial descriptors

Nicolas Dubouis et al.

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Efficient Electrocatalytic N2 Fixation with MXene under Ambient Conditions

Yaru Luo et al.

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An N-doped porous carbon/MXene composite as a sulfur host for lithium-sulfur batteries

Youquan Zhang et al.

INORGANIC CHEMISTRY FRONTIERS (2019)

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Tailoring Electrocatalytic Properties of Pt Nanoparticles Grown on Ti3C2TX MXene Surface

Jaroslav Filip et al.

JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2019)

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MXene-supported Co3O4 quantum dots for superior lithium storage and oxygen evolution activities

Chuang Wang et al.

CHEMICAL COMMUNICATIONS (2019)

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Integrating MXene nanosheets with cobalt-tipped carbon nanotubes for an efficient oxygen reduction reaction

Jianian Chen et al.

JOURNAL OF MATERIALS CHEMISTRY A (2019)

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Exploring the Composition-Activity Relation of Ni-Cu Binary Alloy Electrocatalysts for Hydrogen Oxidation Reaction in Alkaline Media

Gongwei Wang et al.

ACS APPLIED ENERGY MATERIALS (2019)

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Self-Supported Nonprecious MXene/Ni3S2 Electrocatalysts for Efficient Hydrogen Generation in Alkaline Media

Luna Tie et al.

ACS APPLIED ENERGY MATERIALS (2019)

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Nanostructure of Cr2CO2 MXene Supported Single Metal Atom as an Efficient Bifunctional Electrocatalyst for Overall Water Splitting

Yuwen Cheng et al.

ACS APPLIED ENERGY MATERIALS (2019)

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Applications of 2D MXenes in energy conversion and storage systems

Jinbo Pang et al.

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Defect Engineering Strategies for Nitrogen Reduction Reactions under Ambient Conditions

Dafeng Yan et al.

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FeNC/MXene hybrid nanosheet as an efficient electrocatalyst for oxygen reduction reaction

Yangyang Wen et al.

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Bifunctional N-CoSe2/3D-MXene as Highly Efficient and Durable Cathode for Rechargeable Zn-Air Battery

Zhiping Zeng et al.

ACS MATERIALS LETTERS (2019)

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Single molybdenum atom anchored on 2D Ti2NO2 MXene as a promising electrocatalyst for N2 fixation

Yuwen Cheng et al.

NANOSCALE (2019)

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Cu single atoms on Ti2CO2 as a highly efficient oxygen reduction catalyst in a proton exchange membrane fuel cell

Qiong Peng et al.

JOURNAL OF MATERIALS CHEMISTRY A (2019)

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2D MXene nanosheets enable small-sulfur electrodes to be flexible for lithium-sulfur batteries

Qian Zhao et al.

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Lattice constant-dependent anchoring effect of MXenes for lithium-sulfur (Li-S) batteries: a DFT study

Na Li et al.

NANOSCALE (2019)

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Approaches for measuring the surface areas of metal oxide electrocatalysts for determining their intrinsic electrocatalytic activity

Chao Wei et al.

CHEMICAL SOCIETY REVIEWS (2019)

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An MnO2-Ti3C2Tx MXene nanohybrid: an efficient and durable electrocatalyst toward artificial N2 fixation to NH3 under ambient conditions

Wenhan Kong et al.

JOURNAL OF MATERIALS CHEMISTRY A (2019)

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Rational design of free-standing 3D porous MXene/rGO hybrid aerogels as polysulfide reservoirs for high-energy lithium-sulfur batteries

Jianjun Song et al.

JOURNAL OF MATERIALS CHEMISTRY A (2019)

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Single atom-supported MXene: how single-atomic-site catalysts tune the high activity and selectivity of electrochemical nitrogen fixation

Bin Huang et al.

JOURNAL OF MATERIALS CHEMISTRY A (2019)

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MXene supported CoxAy (A = OH, P, Se) electrocatalysts for overall water splitting: unveiling the role of anions in intrinsic activity and stability

N. Clament Sagaya Selvam et al.

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Truncated octahedral bipyramidal TiO2/ MXene Ti3C2 hybrids with enhanced photocatalytic H2 production activity

Yang Li et al.

NANOSCALE ADVANCES (2019)

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Interface-coupling of CoFe-LDH on MXene as high-performance oxygen evolution catalyst

Chongyan Hao et al.

MATERIALS TODAY ENERGY (2019)

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Metal-Organic Framework-Derived Nickel-Cobalt Sulfide on Ultrathin Mxene Nanosheets for Electrocatalytic Oxygen Evolution

Haiyuan Zou et al.

ACS APPLIED MATERIALS & INTERFACES (2018)

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Solution-Plasma-Assisted Bimetallic Oxide Alloy Nanoparticles of Pt and Pd Embedded within Two-Dimensional Ti3C2TX Nanosheets as Highly Active Electrocatalysts for Overall Water Splitting

Bingbing Cui et al.

ACS APPLIED MATERIALS & INTERFACES (2018)

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Rational Design of MXene/1T-2H MoS2-C Nanohybrids for High-Performance Lithium-Sulfur Batteries

Yelong Zhang et al.

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2D/2D Heterojunction of Ultrathin MXene/Bi2WO6 Nanosheets for Improved Photocatalytic CO2 Reduction

Shaowen Cao et al.

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W-Based Atomic Laminates and Their 2D Derivative W1.33C MXene with Vacancy Ordering

Rahele Meshkian et al.

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Identifying the Key Role of Pyridinic-N-Co Bonding in Synergistic Electrocatalysis for Reversible ORR/OER

Xue-Rui Wang et al.

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Fe Isolated Single Atoms on S, N Codoped Carbon by Copolymer Pyrolysis Strategy for Highly Efficient Oxygen Reduction Reaction

Qiheng Li et al.

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Fluorine-Free Synthesis of High-Purity Ti3C2Tx (T=OH, O) via Alkali Treatment

Tengfei Li et al.

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MoS2-on-MXene Heterostructures as Highly Reversible Anode Materials for Lithium-Ion Batteries

Chi Chen et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2018)

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Anchoring effects of S-terminated Ti2C MXene for lithium-sulfur batteries: A first-principles study

Xiaobiao Liu et al.

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In-situ construction of hierarchical accordion-like TiO2/Ti3C2 nanohybrid as anode material for lithium and sodium ion batteries

Chao Yang et al.

ELECTROCHIMICA ACTA (2018)

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TiO2/MXene Ti3C2 composite with excellent photocatalytic CO2 reduction activity

Jingxiang Low et al.

JOURNAL OF CATALYSIS (2018)

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Heterostructures of MXenes and N-doped graphene as highly active bifunctional electrocatalysts

Si Zhou et al.

NANOSCALE (2018)

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Single Pd atomic catalyst on Mo2CO2 monolayer (MXene): unusual activity for CO oxidation by trimolecular Eley-Rideal mechanism

Cheng Cheng et al.

PHYSICAL CHEMISTRY CHEMICAL PHYSICS (2018)

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Facile Synthesis of Crumpled Nitrogen-Doped MXene Nanosheets as a New Sulfur Host for Lithium-Sulfur Batteries

Weizhai Bao et al.

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In situ hybridization of an MXene/TiO2/NiFeCo-layered double hydroxide composite for electrochemical and photoelectrochemical oxygen evolution

Ningxian Hao et al.

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Hydrogen oxidation reaction in alkaline media: From mechanism to recent electrocatalysts

Yuanyuan Cong et al.

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In-situ grown nanocrystal TiO2 on 2D Ti3C2 nanosheets for artificial photosynthesis of chemical fuels

Yanjie Xu et al.

NANO ENERGY (2018)

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Ultrathin MXene nanosheets with rich fluorine termination groups realizing efficient electrocatalytic hydrogen evolution

Shuang Li et al.

NANO ENERGY (2018)

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Boosting electrocatalytic oxygen evolution by synergistically coupling layered double hydroxide with MXene

Mengzhou Yu et al.

NANO ENERGY (2018)

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In Situ Growth of Cobalt Nanoparticles Encapsulated Nitrogen-Doped Carbon Nanotubes among Ti3C2Tx (MXene) Matrix for Oxygen Reduction and Evolution

Youkui Zhang et al.

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Metallic Transition-Metal Dichalcogenide Nanocatalysts for Energy Conversion

Haoyi Li et al.

CHEM (2018)

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Dynamic traction of lattice-confined platinum atoms into mesoporous carbon matrix for hydrogen evolution reaction

Huabin Zhang et al.

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Cu-3-Cluster-Doped Monolayer Mo2CO2 (MXene) as an Electron Reservoir for Catalyzing a CO Oxidation Reaction

Cheng Cheng et al.

ACS APPLIED MATERIALS & INTERFACES (2018)

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Ultralight MXene-Coated, Interconnected SiCnws Three-Dimensional Lamellar Foams for Efficient Microwave Absorption in the X-Band

Xinliang Li et al.

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Aggregation-Resistant 3D MXene-Based Architecture as Efficient Bifunctional Electrocatalyst for Overall Water Splitting

Luyang Xiu et al.

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The Marriage of the FeN4 Moiety and MXene Boosts Oxygen Reduction Catalysis: Fe 3d Electron Delocalization Matters

Zilan Li et al.

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Hierarchical Cobalt Borate/MXenes Hybrid with Extraordinary Electrocatalytic Performance in Oxygen Evolution Reaction

Jiapeng Liu et al.

CHEMSUSCHEM (2018)

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A room-temperature sodium-sulfur battery with high capacity and stable cycling performance

Xiaofu Xu et al.

NATURE COMMUNICATIONS (2018)

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Self-Assemble and In Situ Formation of Ni1-xFexPS3 Nanomosaic-Decorated MXene Hybrids for Overall Water Splitting

Cheng-Feng Du et al.

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Flexible Nitrogen-Doped 2D Titanium Carbides (MXene) Films Constructed by an Ex Situ Solvothermal Method with Extraordinary Volumetric Capacitance

Chenhui Yang et al.

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In situ formation of NaTi2(PO4)(3) cubes on Ti3C2 MXene for dual-mode sodium storage

Qi Yang et al.

JOURNAL OF MATERIALS CHEMISTRY A (2018)

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Establishing new scaling relations on two-dimensional MXenes for CO2 electroreduction

Albertus D. Handoko et al.

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Enhanced electrocatalytic activity by chemical nitridation of two-dimensional titanium carbide MXene for hydrogen evolution

Yeoheung Yoon et al.

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Constructing tunable dual active sites on two-dimensional C3N4@MoN hybrid for electrocatalytic hydrogen evolution

Huanyu Jin et al.

NANO ENERGY (2018)

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Hybridization of Binary Non-Precious-Metal Nanoparticles with d-Ti3C2 MXene for Catalyzing the Oxygen Reduction Reaction

Liangguang Chen et al.

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Single-Crystal Nitrogen-Rich Two-Dimensional Mo5N6 Nanosheets for Efficient and Stable Seawater Splitting

Huanyu Jin et al.

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Atmospheric-Pressure Synthesis of 2D Nitrogen-Rich Tungsten Nitride

Huimin Yu et al.

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Fluoride-Free Synthesis of Two-Dimensional Titanium Carbide (MXene) Using A Binary Aqueous System

Sheng Yang et al.

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2D MoN-VN Heterostructure To Regulate Polysulfides for Highly Efficient Lithium-Sulfur Batteries

Chao Ye et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2018)

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Hybrid Architectures based on 2D MXenes and Low-Dimensional Inorganic Nanostructures: Methods, Synergies, and Energy-Related Applications

Yi-Tao Liu et al.

SMALL (2018)

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Interfacing nickel nitride and nickel boosts both electrocatalytic hydrogen evolution and oxidation reactions

Fuzhan Song et al.

NATURE COMMUNICATIONS (2018)

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Single platinum atoms immobilized on an MXene as an efficient catalyst for the hydrogen evolution reaction

Jinqiang Zhang et al.

NATURE CATALYSIS (2018)

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Adding a New Member to the MXene Family: Synthesis, Structure, and Electrocatalytic Activity for the Hydrogen Evolution Reaction of V4C3Tx

Minh H. Tran et al.

ACS APPLIED ENERGY MATERIALS (2018)

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Phosphorized MXene-Phase Molybdenum Carbide as an Earth-Abundant Hydrogen Evolution Electrocatalyst

Guoxing Qu et al.

ACS APPLIED ENERGY MATERIALS (2018)

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Tuning the Basal Plane Functionalization of Two-Dimensional Metal Carbides (MXenes) To Control Hydrogen Evolution Activity

Albertus D. Handoko et al.

ACS APPLIED ENERGY MATERIALS (2018)

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Exploring the synergy of 2D MXene-supported black phosphorus quantum dots in hydrogen and oxygen evolution reactions

Xiao-Dong Zhu et al.

JOURNAL OF MATERIALS CHEMISTRY A (2018)

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Ti3C2Tx ( T 1/4 F, OH) MXene nanosheets: conductive 2D catalysts for ambient electrohydrogenation of N2 to NH3+

Jinxiu Zhao et al.

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Porous Cryo-Dried MXene for Efficient Capacitive Deionization

Weizhai Bao et al.

JOULE (2018)

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2D MXenes: A New Family of Promising Catalysts for the Hydrogen Evolution Reaction

Guoping Gao et al.

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Mechanism on the Improved Performance of Lithium Sulfur Batteries with MXene-Based Additives

Dewei Rao et al.

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(111) TiO2-x/Ti3C2: Synergy of active facets, interfacial charge transfer and Ti3+ doping for enhance photocatalytic activity

Chao Peng et al.

MATERIALS RESEARCH BULLETIN (2017)

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2D molybdenum and vanadium nitrides synthesized by ammoniation of 2D transition metal carbides (MXenes)

Patrick Urbankowski et al.

NANOSCALE (2017)

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Two-dimensional Mo1.33C MXene with divacancy ordering prepared from parent 3D laminate with in-plane chemical ordering

Quanzheng Tao et al.

NATURE COMMUNICATIONS (2017)

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Mn3O4 nanoparticles on layer-structured Ti3C2 MXene towards the oxygen reduction reaction and zinc-air batteries

Qi Xue et al.

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Electrochemical etching of Ti2AlC to Ti2CTx (MXene) in low-concentration hydrochloric acid solution

W. Sun et al.

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Salt-templated synthesis of defect-rich MoN nanosheets for boosted hydrogen evolution reaction

Jie Xiong et al.

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Ti2CO2 MXene: a highly active and selective photocatalyst for CO2 reduction

Xu Zhang et al.

JOURNAL OF MATERIALS CHEMISTRY A (2017)

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2D-Layered Carbon/TiO2 Hybrids Derived from Ti3C2 MXenes for Photocatalytic Hydrogen Evolution under Visible Light Irradiation

Wenyu Yuan et al.

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Constructing a Triple-Phase Interface in Micropores to Boost Performance of Fe/N/C Catalysts for Direct Methanol Fuel Cells

Yu-Cheng Wang et al.

ACS ENERGY LETTERS (2017)

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Ultra-high-rate pseudocapacitive energy storage in two-dimensional transition metal carbides

Maria R. Lukatskaya et al.

NATURE ENERGY (2017)

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2D metal carbides and nitrides (MXenes) for energy storage

Babak Anasori et al.

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A selective electrocatalyst-based direct methanol fuel cell operated at high concentrations of methanol

Yan Feng et al.

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Understanding of Electrochemical Mechanisms for CO2 Capture and Conversion into Hydrocarbon Fuels in Transition-Metal Carbides (MXenes)

Neng Li et al.

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Direct Synthesis of Large-Area 2D Mo2C on In Situ Grown Graphene

Dechao Geng et al.

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Confined Sulfur in 3D MXene/Reduced Graphene Oxide Hybrid Nanosheets for Lithium-Sulfur Battery

Weizhai Bao et al.

CHEMISTRY-A EUROPEAN JOURNAL (2017)

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A review of flexible lithium-sulfur and analogous alkali metal-chalcogen rechargeable batteries

Hong-Jie Peng et al.

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Two-dimensional MXenes for energy storage and conversion applications

Yijing Sun et al.

MATERIALS TODAY ENERGY (2017)

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Two-Dimensional Titanium Nitride (Ti2N) MXene: Synthesis, Characterization, and Potential Application as Surface-Enhanced Raman Scattering Substrate

Bhuvaneswari Soundiraraju et al.

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Stabilizing the MXenes by Carbon Nanoplating for Developing Hierarchical Nanohybrids with Efficient Lithium Storage and Hydrogen Evolution Capability

Xianhong Wu et al.

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Interdiffusion Reaction-Assisted Hybridization of Two-Dimensional Metal-Organic Frameworks and Ti3C2Tx Nanosheets for Electrocatalytic Oxygen Evolution

Li Zhao et al.

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Salt-Templated Synthesis of 2D Metallic MoN and Other Nitrides

Xu Xiao et al.

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Electrocatalysis for the oxygen evolution reaction: recent development and future perspectives

Nian-Tzu Suen et al.

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Interacting Carbon Nitride and Titanium Carbide Nanosheets for High-Performance Oxygen Evolution

Tian Yi Ma et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2016)

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Synthesis of MXene/Ag Composites for Extraordinary Long Cycle Lifetime Lithium Storage at High Rates

Guodong Zou et al.

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Atomic Defects in Monolayer Titanium Carbide (Ti3C2Tx) MXene

Xiahan Sang et al.

ACS NANO (2016)

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3D Metal Carbide@Mesoporous Carbon Hybrid Architecture as a New Polysulfide Reservoir for Lithium-Sulfur Batteries

Weizhai Bao et al.

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Layered Orthorhombic Nb2O5@Nb4C3Tx and TiO2@Ti3C2Tx Hierarchical Composites for High Performance Li-ion Batteries

Chuanfang (John) Zhang et al.

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Organic-Base-Driven Intercalation and Delamination for the Production of Functionalized Titanium Carbide Nanosheets with Superior Photothermal Therapeutic Performance

Jinnan Xuan et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2016)

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Graphitic Carbon Nitride (g-C3N4)-Based Photocatalysts for Artificial Photosynthesis and Environmental Remediation: Are We a Step Closer To Achieving Sustainability?

Wee-Jun Ong et al.

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Designing high-energy lithium-sulfur batteries

Zhi Wei Seh et al.

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Recent advances in transition metal phosphide nanomaterials: synthesis and applications in hydrogen evolution reaction

Yanmei Shi et al.

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Searching for Highly Active Catalysts for Hydrogen Evolution Reaction Based on O-Terminated MXenes through a Simple Descriptor

Chongyi Ling et al.

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Promising prospects for 2D d(2)-d(4) M3C2 transition metal carbides (MXenes) in N-2 capture and conversion into ammonia

Luis Miguel Azofra et al.

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Synthesis of two-dimensional titanium nitride Ti4N3 (MXene)

Patrick Urbankowski et al.

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A stable room-temperature sodium-sulfur battery

Shuya Wei et al.

NATURE COMMUNICATIONS (2016)

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Self-Reduction Synthesis of New MXene/Ag Composites with Unexpected Electrocatalytic Activity

Zhiwei Zhang et al.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2016)

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A Ti-anchored Ti2CO2 monolayer (MXene) as a single-atom catalyst for CO oxidation

Xu Zhang et al.

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Transition Metal-Promoted V2CO2 (MXenes): A New and Highly Active Catalyst for Hydrogen Evolution Reaction

Chongyi Ling et al.

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Two-Dimensional Molybdenum Carbide (MXene) as an Efficient Electrocatalyst for Hydrogen Evolution

Zhi Wei Seh et al.

ACS ENERGY LETTERS (2016)

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Two-Dimensional Nb-Based M4C3 Solid Solutions (MXenes)

Jian Yang et al.

JOURNAL OF THE AMERICAN CERAMIC SOCIETY (2016)

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Two-Dimensional, Ordered, Double Transition Metals Carbides (MXenes)

Babak Anasori et al.

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Lithium-Sulfur Batteries: Progress and Prospects

Arumugam Manthiram et al.

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Coupling Mo2C with Nitrogen-Rich Nanocarbon Leads to Efficient Hydrogen-Evolution Electrocatalytic Sites

Yipu Liu et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2015)

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Sulfur Cathodes Based on Conductive MXene Nanosheets for High-Performance Lithium-Sulfur Batteries

Xiao Liang et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2015)

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Design of electrocatalysts for oxygen- and hydrogen-involving energy conversion reactions

Yan Jiao et al.

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Effect of Postetch Annealing Gas Composition on the Structural and Electrochemical Properties of Ti2CTx MXene Electrodes for Supercapacitor Applications

R. B. Rakhi et al.

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Role of the surface effect on the structural, electronic and mechanical properties of the carbide MXenes

Xian-Hu Zha et al.

EPL (2015)

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Effects of Fe Electrolyte Impurities on Ni(OH)2/NiOOH Structure and Oxygen Evolution Activity

Shannon Klaus et al.

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Atomically Resolved Structural and Chemical Investigation of Single MXene Sheets

Linda H. Karlsson et al.

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Large-area high-quality 2D ultrathin Mo2C superconducting crystals

Chuan Xu et al.

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Exploring the potential of exfoliated ternary ultrathin Ti4AlN3 nanosheets for fabricating hybrid patterned polymer brushes

Qun Ye et al.

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Flexible MXene/Carbon Nanotube Composite Paper with High Volumetric Capacitance

Meng-Qiang Zhao et al.

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A High-Energy Room-Temperature Sodium-Sulfur Battery

Sen Xin et al.

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Transparent Conductive Two-Dimensional Titanium Carbide Epitaxial Thin Films

Joseph Halim et al.

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Phenylenediamine-Based FeNx/C Catalyst with High Activity for Oxygen Reduction in Acid Medium and Its Active-Site Probing

Qiang Wang et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2014)

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Conductive two-dimensional titanium carbide 'clay' with high volumetric capacitance

Michael Ghidiu et al.

NATURE (2014)

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In situ environmental transmission electron microscopy study of oxidation of two-dimensional Ti3C2 and formation of carbon-supported TiO2

H. Ghassemi et al.

JOURNAL OF MATERIALS CHEMISTRY A (2014)

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Challenges and Prospects of Lithium-Sulfur Batteries

Arumugam Manthiram et al.

ACCOUNTS OF CHEMICAL RESEARCH (2013)

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An extraordinarily stable catalyst: Pt NPs supported on two-dimensional Ti3C2X2 (X = OH, F) nanosheets for oxygen reduction reaction

Xiaohong Xie et al.

CHEMICAL COMMUNICATIONS (2013)

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Improving the hydrogen oxidation reaction rate by promotion of hydroxyl adsorption

Dusan Strmcnik et al.

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Two-Dimensional Transition Metal Carbides

Michael Naguib et al.

ACS NANO (2012)

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Graphene-like titanium carbides and nitrides Tin+1Cn, Tin+1Nn (n=1, 2, and 3) from de-intercalated MAX phases: First-principles probing of their structural, electronic properties and relative stability

I. R. Shein et al.

COMPUTATIONAL MATERIALS SCIENCE (2012)

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Two-Dimensional Nanocrystals Produced by Exfoliation of Ti3AlC2

Michael Naguib et al.

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Poisoning the Oxygen Reduction Reaction on Carbon-Supported Fe and Cu Electrocatalysts: Evidence for Metal-Centered Activity

Matthew S. Thorum et al.

JOURNAL OF PHYSICAL CHEMISTRY LETTERS (2011)

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Identification of active edge sites for electrochemical H2 evolution from MoS2 nanocatalysts

Thomas F. Jaramillo et al.

SCIENCE (2007)

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Carbon-carbon coupling reactions catalyzed by heterogeneous palladium catalysts

Lunxiang Yin et al.

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Two-dimensional gas of massless Dirac fermions in graphene

KS Novoselov et al.

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