Journal
DALTON TRANSACTIONS
Volume 52, Issue 16, Pages 5044-5046Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d3dt00567d
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The synthesis and solid-state characterization of a heterobimetallic rhodium(III)/silver(I) complex [Rh(2,2'-biphenyl)(CxP(2))Cl]superset of Ag+ is reported, in which CxP(2) is a trans-spanning calix[4]arene-based diphosphine ligand and the silver cation is dative bond to the chloride ligand within the cavity of the macrocycle.
The synthesis and solid-state characterisation of the heterobimetallic rhodium(III)/silver(I) complex [Rh(2,2'-biphenyl)(CxP(2))Cl]superset of Ag+ is described, where CxP(2) is a trans-spanning calix[4]arene-based diphosphine and the silver cation is datively bound to the chloride ligand within the cavity of the macrocycle.
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