4.6 Article

A highly explicit electrochemical biosensor for catechol detection in real samples based on copper-polypyrrole

Journal

RSC ADVANCES
Volume 13, Issue 20, Pages 13443-13455

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/d2ra07847c

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A highly specific, selective, and sensitive electrochemical biosensor based on a copper-polypyrrole composite and a glassy carbon electrode has been developed for catechol detection. The novelty of this biosensor was tested using electrochemical techniques, and its characteristics of sensitivity, LOD, LOQ, linear range, specificity, interference, and real sample detection were investigated. The morphological, structural, and bonding characteristics of the biosensor were examined using XRD, Raman, FTIR, and SEM.
Catechol is a pollutant that can lead to serious health issues. Identification in aquatic environments is difficult. A highly specific, selective, and sensitive electrochemical biosensor based on a copper-polypyrrole composite and a glassy carbon electrode has been created for catechol detection. The novelty of this newly developed biosensor was tested using electrochemical techniques. The charge and mass transfer functions and partially reversible oxidation kinetics of catechol on the redesigned electrode surface were examined using electrochemical impedance spectroscopy and cyclic voltammetry scan rates. Using cyclic voltammetry, chronoamperometry, and differential pulse voltammetry, the characteristics of sensitivity (8.5699 mu A cm(-2)), LOD (1.52 x 10(-7) mu M), LOQ (3.52 x 10(-5) mu M), linear range (0.02-2500 mu M), specificity, interference, and real sample detection were investigated. The morphological, structural, and bonding characteristics were investigated using XRD, Raman, FTIR, and SEM. Using an oxidation-reduction technique, a suitable biosensor material was produced. In the presence of interfering compounds, it was shown that it was selective for catechol, like an enzyme.

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