4.6 Article

Surface plasmon resonance in metal nanospheres explained with LCR circuits

Journal

PHYSICAL CHEMISTRY CHEMICAL PHYSICS
Volume 25, Issue 19, Pages 13708-13715

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/d3cp00589e

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This manuscript presents various simple LCR circuits that explain the surface plasmon resonance (SPR) behavior of spherical metal nanoparticles. The simulation results using QUCS demonstrate similarity with the SPR results in the literature, effectively explaining the size-effect, the influence of the surrounding dielectric medium, and the proximity effect of densely packed metal nanoparticles. Additionally, the study explores the circuital parameters to explain these material-dependent observations, providing insights into the role of material parameters on the influence of the surrounding dielectric medium and the proximity effect.
The manuscript details various simple LCR circuits to explain the experimentally observed surface plasmon resonance behavior of spherical metal nanoparticles. The results of the circuit's performance simulated using standard software like QUCS show similarity with SPR results in the literature, thus successfully explaining the size-effect, the influence of the surrounding dielectric medium and the proximity effect of densely packed metal nanoparticles. The study also explains these material dependent observations in terms of circuital parameters. This opens an avenue to detail the exact role of the material parameters in the influence of the surrounding dielectric medium and the proximity effect.

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