Journal
CHEMICAL COMMUNICATIONS
Volume 59, Issue 44, Pages 6698-6701Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d3cc00891f
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The reduction of 2-H-substituted pyrrolinium cations results in dimerisation or H-abstracted products, depending on the N-substituents. The dimerised 2,2'-bipyrrolidine derivatives with a central carbon-carbon single bond are stable and can be oxidised chemically or electrochemically. These dimers, which are air and moisture-stable, can serve as a source of two electrons in various chemical transformations.
Reduction of 2-H-substituted pyrrolinium cations via initially formed secondary radicals results in either dimerisation or H-abstracted products, while the outcome depends on the N-substituents. The resultant central carbon-carbon single bond in the dimerised 2,2 '-bipyrrolidine derivatives can be oxidised chemically and electrochemically. The notably air and moisture-stable dimers were subsequently utilised as a source of two electrons in various chemical transformations.
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