Journal
CHEMICAL COMMUNICATIONS
Volume 59, Issue 47, Pages 7243-7246Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d3cc00964e
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The strategic inclusion of nucleic bases adenine, cytosine, and thymine, in the form of outer coordination sphere, positively impacts the electro- and photocatalytic H-2 production by cobaloxime cores. These cobaloxime derivatives showcased their optimal H-2 production in acidic media due to specific protonation of adenine and cytosine below pH 5.0.
The strategic inclusion of nucleic bases adenine, cytosine, and thymine, in the form of outer coordination sphere, positively impacts the electro- and photocatalytic H-2 production by cobaloxime cores. These cobaloxime derivatives showcased their optimal H-2 production in acidic media due to specific protonation of adenine and cytosine below pH 5.0.
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