☆ 4.7 Article

The future of organic electrochemistry current transfer

CHINESE JOURNAL OF CATALYSIS (2023)

Related references

Note: Only part of the references are listed.

Article Chemistry, Multidisciplinary

Electrochemical Rhodium-Catalyzed Enantioselective C-H Annulation with Alkynes

Yuan-Qiong Huang et al.

Summary: The synergistic use of transition metal catalysis and electrochemistry is an attractive strategy for oxidative site-selective C-H functionalization. This study presents an electrochemically tuned rhodium-catalyzed enantioselective C-H annulation, which provides a practical and environmentally benign tool for the synthesis of chiral spiropyrazolones.

CCS CHEMISTRY (2022)

Add to Collection

Review Chemistry, Multidisciplinary

Recent Applications of Homogeneous Catalysis in Electrochemical Organic Synthesis

Xu Cheng et al.

Summary: This review presents recent advances in electrochemical homogeneous catalysis, with a focus on electrochemical noble-transition-metal catalysis, photoelectrochemical catalysis, and electrochemical enantioselective catalysis. The topics discussed include the mechanism of noble metal catalysts in the presence of cathodic hydrogen evolution, the enhancement of redox properties in photocatalysis, and the regulation of enantioselectivity in catalytic electrochemical reactions.

CCS CHEMISTRY (2022)

Add to Collection

Article Chemistry, Multidisciplinary

Cathodic Radical Cyclisation of Aryl Halides Using a Strongly-Reducing Catalytic Mediator in Flow

Ana A. Folgueiras-Amador et al.

Summary: The electro-reductive radical cyclisation of aryl halides using an organic mediator in an undivided flow reactor is a practical and efficient method to synthesize hetero- and carbo-cycles. The use of a sub-stoichiometric amount of mediator increases its practical utility. This methodology is versatile and can be applied to different tethering groups, resulting in the formation of diverse cyclic compounds.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2022)

Add to Collection

Article Chemistry, Multidisciplinary

Cu-Electrocatalytic Diazidation of Alkenes at ppm Catalyst Loading

Chen-Yan Cai et al.

Summary: A scalable Cu-electrocatalytic alkene diazidation reaction with 0.02 mol % of copper(II) acetylacetonate as a precatalyst without exogenous ligands has been reported. This electrocatalytic method is characterized by low catalyst loading, scalability, compatibility with a wide range of functional groups, and applicability to various types of alkene diazidation.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2022)

Add to Collection

Article Chemistry, Multidisciplinary

Transition-Metal-Free, Site-Selective C-F Arylation of Polyfluoroarenes via Electrophotocatalysis

Ya-Jing Chen et al.

Summary: An unprecedented transition-metal-free strategy for site-selective C-Ar-F arylation of polyfluoroarenes with simple (het)arenes is reported. This strategy features high regioselectivity and comparable yields to transition-metal catalysis, with a broad substrate scope and good functional-group compatibility.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2022)

Add to Collection

Article Chemistry, Physical

Photoelectrochemical asymmetric catalysis enables site- and enantioselective cyanation of benzylic C-H bonds

Chen-Yan Cai et al.

Summary: The combination of molecular photoelectrochemistry and asymmetric catalysis enables highly site- and enantioselective cyanation of benzylic C(sp(3))-H bonds. This photoelectrochemical asymmetric catalysis does not require a chemical oxidant and exhibits exceptional site selectivity and functional group tolerance, allowing efficient conversion of feedstock chemicals and late-stage functionalization of complex bioactive molecules and natural products, including those with multiple benzylic sites.

NATURE CATALYSIS (2022)

Add to Collection

Review Chemistry, Multidisciplinary

Electrochemical Oxidation Induced Selective C-C Bond Cleavage

Shi-Hui Shi et al.

Summary: Selective C-C bond cleavage using electrochemical methods has been identified as a sustainable and scalable strategy that shows potential in replacing chemical reagents with electricity. Progress in this area has been made, with more examples of C-C bond cleavage via different maneuvers being developed recently, showcasing the exciting potential of electrochemical synthesis.

CHEMICAL REVIEWS (2021)

Add to Collection

Article Chemistry, Multidisciplinary

Time-Resolved EPR Revealed the Formation, Structure, and Reactivity of N-Centered Radicals in an Electrochemical C(sp3)-H Arylation Reaction

Yichang Liu et al.

Summary: Electrochemical synthesis has rapidly developed in recent years, with the majority of reactions proceeding through a radical pathway. Understanding the properties of radical intermediates is crucial for mechanistic studies and developing new reactions. This study directly researched the formation and structure of sulfonamide N-centered radicals using the time-resolved EPR technique under electrochemical conditions, and successfully applied the results in the discovery of an unactivated C(sp(3))-H arylation reaction.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

Add to Collection

Article Chemistry, Multidisciplinary

Mediator-Enabled Electrocatalysis with Ligandless Copper for Anaerobic Chan-Lam Coupling Reactions

Benjamin R. Walker et al.

Summary: This study reports the use of substoichiometric quantities of redox mediators to address limitations to Cu-catalyzed electrosynthesis. By applying this strategy to Chan-Lam coupling of aryl-, heteroaryl-, and alkylamines with arylboronic acids without the need for chemical oxidants, couplings under these electrochemical conditions occur with higher yields and shorter reaction times compared to conventional reactions. The redox mediators serve multiple roles in rapidly oxidizing low-valent Cu intermediates, regenerating the catalyst, revealing the active Pt surface for proton reduction, and providing anodic overcharge protection to prevent substrate oxidation.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

Add to Collection

Article Chemistry, Multidisciplinary

C-H Amination via Electrophotocatalytic Ritter-type Reaction

Tao Shen et al.

Summary: A method for C-H bond amination via electrophotocatalytic Ritter-type reaction has been developed, catalyzed by a trisaminocyclopropenium (TAC) ion in an electrochemical cell under irradiation, converting benzylic C-H bonds to acetamides without stoichiometric chemical oxidant. The method demonstrates compatibility with a wide range of functionalities and shows successful transformation of several complex substrates.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

Add to Collection

Review Chemistry, Multidisciplinary

Recent advances in electrochemical oxidative cross-coupling with hydrogen evolution involving radicals

Yong Yuan et al.

Summary: Oxidative cross-coupling is a robust method for forming C-C, C-X, and X-Y bonds. Organic electrosynthesis is recognized as an environmentally friendly and powerful synthetic platform. Recent advancements have shown that radical-involved electrochemical oxidative cross-coupling reactions can be achieved under exogenous-oxidant-free conditions.

CHEMICAL SOCIETY REVIEWS (2021)

Add to Collection

Review Chemistry, Multidisciplinary

Electrocatalysis as an enabling technology for organic synthesis

Luiz F. T. Novaes et al.

Summary: Electrochemistry has recently become a versatile strategy in achieving challenging transformations in synthetic organic chemistry. The use of redox-active electrocatalysts has increased in recent developments in electrosynthesis to enhance control over reactive intermediates. Electrocatalytic mediators allow for synthetic transformations to proceed in a manner different from purely chemical methods.

CHEMICAL SOCIETY REVIEWS (2021)

Add to Collection

Review Chemistry, Multidisciplinary

Electrochemical Oxidation of Organic Molecules at Lower Overpotential: Accessing Broader Functional Group Compatibility with Electron-Proton Transfer Mediators

Fei Wang et al.

ACCOUNTS OF CHEMICAL RESEARCH (2020)

Add to Collection

Review Chemistry, Multidisciplinary

Synthetic Photoelectrochemistry

Joshua P. Barham et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

Add to Collection

Review Chemistry, Multidisciplinary

Asymmetric Electrochemical Transformations

Xihao Chang et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

Add to Collection

Article Chemistry, Physical

Electrochemical oxidative aminocarbonylation of terminal alkynes

Li Zeng et al.

NATURE CATALYSIS (2020)

Add to Collection

Article Chemistry, Multidisciplinary

Catalytic Asymmetric Electrochemical α-Arylation of Cyclic β-Ketocarbonyls with Anodic Benzyne Intermediates

Longji Li et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

Add to Collection

Review Chemistry, Multidisciplinary

Fundamentals, Applications, and Future Directions of Bioelectrocatalysis

Hui Chen et al.

CHEMICAL REVIEWS (2020)

Add to Collection

Review Chemistry, Multidisciplinary

Powering the Future: How Can Electrochemistry Make a Difference in Organic Synthesis?

Tjark H. Meyer et al.

CHEM (2020)

Add to Collection

Article Chemistry, Multidisciplinary

Nickel catalysis enables convergent paired electrolysis for direct arylation of benzylic C-H bonds

Lei Zhang et al.

CHEMICAL SCIENCE (2020)

Add to Collection

Article Chemistry, Multidisciplinary

Upgraded Bioelectrocatalytic N2 Fixation: From N2 to Chiral Amine Intermediates

Hui Chen et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2019)

Add to Collection

Article Chemistry, Multidisciplinary

Electrochemically Driven, Ni-Catalyzed Aryl Amination: Scope, Mechanism, and Applications

Yu Kawamata et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2019)

Add to Collection

Article Multidisciplinary Sciences

Scalable and safe synthetic organic electroreduction inspired by Li-ion battery chemistry

Byron K. Peters et al.

SCIENCE (2019)

Add to Collection

Review Chemistry, Multidisciplinary

Electrochemical Oxidative Cross-Coupling with Hydrogen Evolution Reactions

Yong Yuan et al.

ACCOUNTS OF CHEMICAL RESEARCH (2019)

Add to Collection

Review Chemistry, Multidisciplinary

Chemistry with Electrochemically Generated N-Centered Radicals

Peng Xiong et al.

ACCOUNTS OF CHEMICAL RESEARCH (2019)

Add to Collection

Review Electrochemistry

Use of Boron-Doped Diamond Electrodes in Electro-Organic Synthesis

Sebastian Lips et al.

CHEMELECTROCHEM (2019)

Add to Collection

Article Chemistry, Multidisciplinary

Uniting laboratory automation, DoE data, and modeling techniques to accelerate chemical process development

Victor Rosso et al.

REACTION CHEMISTRY & ENGINEERING (2019)

Add to Collection

Review Chemistry, Multidisciplinary

Recent Advances in Electrocatalysts for Oxygen Reduction Reaction

Minhua Shao et al.

CHEMICAL REVIEWS (2016)

Add to Collection

Review Chemistry, Multidisciplinary

Artificial Photosynthesis: Molecular Systems for Catalytic Water Oxidation

Markus D. Karkas et al.

CHEMICAL REVIEWS (2014)

Add to Collection

© Peeref 2019-2024. All rights reserved.