Journal
CHEMPLUSCHEM
Volume 81, Issue 8, Pages 708-713Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cplu.201600046
Keywords
cyclic carbonates; epoxidation; liquid-phase epitaxy; metal-organic frameworks; tandem catalysis
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Funding
- Army Research Office [W911NF-13-1-0229]
- Deanship of Scientific Research (DSR), King Abdulaziz University, Jeddah [23-130-36-HiCi]
- Bill and Melinda Gates Foundation
- DFG
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A functional metal-organic framework (MOF) composed of robust porphyrinic material (RPM) based on the pillared-paddlewheel topology is prepared with large 3D channels, and is used to perform a tandem epoxidation/CO2 insertion reaction. The designated system benefits from two metalloporphyrins: 1) a Mn-porphyrin, which catalyzes the epoxidation of an olefin substrate, and 2) a Zn-porphyrin, which catalyzes the epoxide opening. By using an automated liquid-phase epitaxial growth system, the RPM-MOF is also prepared in layer-by-layer fashion as an ultrathin film on a self-assembled-monolayer-coated silicon platform. Deployed as a tandem catalyst, the film version yields a substantially higher catalytic turnover number for tandem methoxy-styrene epoxidation followed by CO2 insertion than the bulk crystalline MOF samples.
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