Journal
CHEMPLUSCHEM
Volume 82, Issue 7, Pages 1034-1038Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cplu.201600465
Keywords
arenes; N-heterocycles; organic semiconductors; polycycles
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Funding
- Research Grants Council of Hong Kong [GRF402613]
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Herein, two novel N-phenylated N-heteroacenes (1 and 2) are reported, along with details of their synthesis, structures, and properties. Compound 1 is a N-hetero analogue of rubrene, but differs from rubrene by having a bent backbone and behaving as an insulator in the solid state owing to the lack of p-p interactions. Compound 2 is a N-hetero analogue of 6,13-diphenylpentacene (DPP) with essentially the same molecular geometry and crystal packing as DPP, but exhibiting a field effect mobility higher than that of DPP by two orders of magnitude.
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