4.6 Article

Enhanced electrochemical performance of iron-doped (NH4)2V12O27•xH2O as a cathode material for aqueous zinc-ion batteries

Journal

REACTION CHEMISTRY & ENGINEERING
Volume 8, Issue 7, Pages 1545-1552

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/d3re00184a

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In this study, Fe-doped (NH4)2V12O27·xH2O was synthesized using solvothermal method which greatly enhanced material's electrochemical performance. The resulting product showed remarkably high capacity of 165 mA h g-1 at 50 mA g-1 and ultrahigh stability with 74.2% retention over 1000 cycles at 1 A g-1. This improvement is attributed to increased intrinsic conductivity from Fe doping which promotes absorption and release kinetics of Zn2+ and prevents gradual dissolution of V-O layer.
Aqueous zinc ion batteries (ZIBs) have attracted significant attention due to their high energy density, non-toxicity, robust security, and low cost. The cathode material is a crucial factor affecting the cost and performance of ZIBs. However, vanadate-based materials suffer from low conductivity and sluggish reaction kinetics, which impede the transfer of Zn2+ and electrons, leading to rapid capacity loss. In this study, we report the solvothermal synthesis of Fe-doped (NH4)(2)V12O27 center dot xH(2)O, which greatly enhances the electrochemical performance of the material. The resulting product exhibits a remarkably high capacity of 165 mA h g(-1) at 50 mA g(-1), and an ultrahigh stability with 74.2% retention over 1000 cycles at 1 A g(-1). This improvement in performance is attributed to the increased intrinsic conductivity from Fe doping, which promotes the absorption and release kinetics of Zn2+ and prevents the gradual dissolution of the V-O layer.

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