Journal
JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING
Volume 11, Issue 2, Pages -Publisher
ELSEVIER SCI LTD
DOI: 10.1016/j.jece.2023.109363
Keywords
Epoxy resin; Alcoholysis; Recovery; Self -separation; Polyurethane foam
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High-efficiency and energy-saving conversion of epoxy thermosets into high value, high quality, and high-performance products is desired for environmental protection and resource utilization. A new strategy for mild degradation of epoxy thermosets and in situ preparation of polyurethane foam from degradation solutions is demonstrated. The degradation solution contains unreacted solvent polyethylene glycol and polyol degradation products, which can react with isocyanate to produce polyurethane. The use of an insoluble catalyst enables in-situ foaming of the degradation solution, allowing for direct and full utilization of degradation products. The rigid epoxy skeleton of the degradation products contributes to the high mechanical properties, thermal insulation performance, low water absorption, regular pore structure, and thermal stability of the obtained polyurethane foam, making it a promising candidate for building insulation materials.
High-efficiency and energy-saving conversion of epoxy thermosets into three-high (high value, high quality and high performance) products is highly desired from the viewpoints of both environmental protection and resource utilization. Here, we demonstrate a new strategy for mild degradation of epoxy thermosets and in situ preparation of polyurethane foam from degradation solutions. The degradation solution contains the unreacted solvent polyethylene glycol and polyol degradation products after alcoholysis, both of which can react with isocyanate to produce polyurethane. The use of an insoluble catalyst makes it possible to achieve in-situ foaming of the degradation solution, which realizes the direct and full utilization of degradation products. Owing to the rigid epoxy skeleton of the degradation products, the obtained rigid polyurethane foam exhibited high mechanical properties (similar to 170kPa), good thermal insulation performance (33-35 mW center dot m(-1)center dot K-1), low water absorption (3-5%), regular pore structure and good thermal stability, thus can be a good candidate for building insulation materials.
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