Journal
CHEMICAL COMMUNICATIONS
Volume 59, Issue 48, Pages 7447-7450Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d3cc01461d
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In this study, 0D chiral zinc halides with high efficiency second-order nonlinear optical responses were successfully fabricated. The incorporation of Sb3+ into the chiral zinc halide matrix effectively triggers circularly polarized luminescence with a balance between quantum yield and luminescence dissymmetry factor.
Chiral hybrid metal halides have grabbed extensive attention in linear and nonlinear chiroptics. Herein, 0D chiral zinc halides, (R-/S-2-MP)ZnCl4, have been fabricated, which demonstrate high efficiency second-order nonlinear optical responses. Incorporating Sb3+ into the chiral zinc halide matrix triggers the circularly polarized luminescence effectively with a balance between quantum yield and luminescence dissymmetry factor.
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