Algal sorbents and prospects for their application in the sustainable recovery of rare earth elements from E-waste

Efficient and sustainable secondary sourcing of Rare-Earth Elements (REE) is essential to counter supply bottlenecks and the impacts associated with primary mining. Recycled electronic waste (E-waste) is considered a promising REE source and hydrometallurgical methods followed by chemical separation techniques (usually solvent extraction) have been successfully applied to these wastes with high REE yields. However, the generation of acidic and organic waste streams is considered unsustainable and has led to the search for greener approaches. Sorption-based technologies using biomass such as bacteria, fungi and algae have been developed to sustainably recover REE from e-waste. Algae sorbents in particular have experienced growing research interest in recent years. Despite its high potential, sorption efficiency is strongly influenced by sorbent-specific parameters such as biomass type and state (fresh/dried, pre-treatment, functionalization) as well as solution parameters such as pH, REE concentration, and matrix complexity (ionic strength and competing ions). This review highlights differences in experimental conditions among published algal-based REE sorption studies and their impact on sorption efficiency. Since research into algal sorbents for REE recovery from real wastes is still in its infancy, aspects such as the economic viability of a realistic application are still unexplored. However, it has been proposed to integrate REE recovery into an algal biorefinery concept to increase the economics of the process (by providing a range of additional products), but also in the prospect of achieving carbon neutrality (as large-scale algae cultivation can act as a CO2 sink).

Automated summary

Efficient and sustainable secondary sourcing of Rare-Earth Elements (REE) is important to address supply bottlenecks and the negative impacts of primary mining. Recycling electronic waste (E-waste) is a promising source of REE, and hydrometallurgical methods followed by chemical separation techniques have successfully been used to recover REE from these wastes. However, the generation of unsustainable acidic and organic waste streams has led to the exploration of greener approaches, such as sorption-based technologies using biomass. Algae sorbents have gained attention, but the efficiency of sorption is influenced by various factors, including biomass type, solution parameters, and matrix complexity.