Enhancing decomposition of rhodamine (RhB) and methylene blue (MB) using CdS decorated with Ag or Ru driven by visible radiation

The development of photocatalysts has an influential role in solving the environmental pollution crisis. Herein, the two different noble metals of silver (Ag)/ruthenium (Ru) were separately decorated on cadmium sulfide (CdS) photocatalysts by novel chemical methods. Characterization tests confirmed the formation of Ag/Ru-decorated CdS with spherical morphologies. According to the DRS and PL experiments, Ru-decorated CdS accounted for the highest light absorbance and the most accelerated transfer and detachment of photoelectrons/holes, followed by Ag-decorated CdS compared to pure CdS, which brought proper optical properties of Ag/Ru-decorated CdS. The photodecomposition of methylene blue (MB)/rhodamine B (RhB) as dyes and phenol as a colorless pollutant in the presence of Ag-decorated CdS (96%, 95%, and 69%) and Ru-decorated CdS (100%, 100%, and 80%) exposed to visible light radiation climbed compared to pure CdS (80%, 67%, and 61%) respectively. The influence of various parameters on the MB/RhB photocatalytic activity was investigated. The quenching experiment determined the functions of active species. Finally, experimental results proved that the MB/RhB photodecomposition by Ag/Ru-decorated CdS followed the pseudo-first-order kinetic model.

Automated summary

The development of Ag/Ru-decorated CdS photocatalysts has shown promise in addressing the environmental pollution crisis. The addition of Ag and Ru noble metals onto CdS photocatalysts resulted in improved optical properties and enhanced photodecomposition of dyes and pollutants under visible light radiation. Furthermore, the experiments demonstrated that the photodecomposition followed a pseudo-first-order kinetic model.