4.6 Article

Anion-exchange facilitated selective extraction of sulfate and phosphate by overcoming the Hofmeister bias

Journal

RSC ADVANCES
Volume 13, Issue 24, Pages 16185-16195

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/d3ra01771k

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In this paper, a method for the selective recognition and removal of sulfate and phosphates from aqueous media using nitrophenyl-functionalized tris-urea receptors and tris-thiourea receptors is presented. The selectivity of the receptors for sulfate and phosphates was evaluated through competitive extraction experiments. The results showed that the nitrophenyl-functionalized tris-urea receptors had higher extraction efficiency for sulfate, while the tris-thiourea receptors had higher extraction efficiency for phosphates.
Selective recognition and removal of sulfate and phosphates from aqueous media in the presence of highly competing anions is very demanding because of their biological and environmental implications. In this paper, we present the anion recognition approach for the selective and efficient extraction of sulfate by nitrophenyl-functionalized tris-urea receptors (L-1-L-2) from highly competitive aqueous media with an equivalent concentration of nitrate and other anions. Tetrabutylammonium hydroxide has been used for the first time as a phase transfer anionic extractant for sulfate-exchange from the aqueous phase to the organic phase (dichloromethane) containing a tris-urea receptor (L-1-L-3). The sulfate extraction efficacy of L-2 (approximate to 84-90%) was observed to be higher than those of L-1 (approximate to 76-82%) and L-3 (approximate to 68-75%) in competitive extraction experiments. In contrast, an analogous nitrophenyl-functionalized tris-thiourea receptor (L-4) has been recognized for the selective and efficient extraction of phosphates from aqueous media in the presence of several competing anions including sulfate and nitrate, with approximate to 85-92% extraction efficiency. In this case, tetrabutylammonium acetate has been used as a phase transfer anionic extractant for phosphate exchange between the two immiscible phases. Due to the higher acidity of tris-thiourea -NH groups in comparison to the analogous tris-urea, tetrabutylammonium hydroxide could deprotonate a hydrogen bond donating -NH group of the thiourea receptor and phosphate extraction was observed to be inefficient in such a case. Several liquid-liquid extraction (LLE) experiments have been carried out to establish the selective removal of sulfate and phosphates by the tripodal receptors from competitive aqueous media having different combinations of two or more anions. The LLE products obtained from organic phases were characterized by NMR (H-1, C-13, P-31, and F-19) spectroscopy to affirm the oxoanion selectivity of the receptors and purity of the complexes. The tripodal receptors can easily be recycled for successive extraction cycles by simply washing the LLE products (oxoanion complexes) with a methanol-water (1 : 1, v/v) solvent system followed by filtration.

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