Dynamics of reduced graphene oxide: synthesis and structural models

Technological advancements are leading to an upsurge in demand for functional materials that satisfy several of humankind's needs. In addition to this, the current global drive is to develop materials with high efficacy in intended applications whilst practising green chemistry principles to ensure sustainability. Carbon-based materials, such as reduced graphene oxide (RGO), in particular, can possibly meet this criterion because they can be derived from waste biomass (a renewable material), possibly synthesised at low temperatures without the use of hazardous chemicals, and are biodegradable (owing to their organic nature), among other characteristics. Additionally, RGO as a carbon-based material is gaining momentum in several applications due to its lightweight, nontoxicity, excellent flexibility, tuneable band gap (from reduction), higher electrical conductivity (relative to graphene oxide, GO), low cost (owing to the natural abundance of carbon), and potentially facile and scalable synthesis protocols. Despite these attributes, the possible structures of RGO are still numerous with notable critical variations and the synthesis procedures have been dynamic. Herein, we summarize the highlights from the historical breakthroughs in understanding the structure of RGO (from the perspective of GO) and the recent state-of-the-art synthesis protocols, covering the period from 2020 to 2023. These are key aspects in the realisation of the full potential of RGO materials through the tailoring of physicochemical properties and reproducibility. The reviewed work highlights the merits and prospects of the physicochemical properties of RGO toward achieving sustainable, environmentally friendly, low-cost, and high-performing materials at a large scale for use in functional devices/processes to pave the way for commercialisation. This can drive the sustainability and commercial viability aspects of RGO as a material.

Automated summary

Technological advancements have resulted in a higher demand for functional materials that meet various needs. Carbon-based materials, specifically reduced graphene oxide (RGO), have the potential to fulfill this requirement due to their renewable nature, low-temperature synthesis, and biodegradability. Furthermore, RGO has several advantageous properties, including lightweight, nontoxicity, flexibility, tunable band gap, high electrical conductivity, low cost, and scalable synthesis protocols. However, the numerous possible structures of RGO and evolving synthesis procedures pose challenges. This article provides a summary of the historical breakthroughs in understanding RGO's structure and recent state-of-the-art synthesis protocols from 2020 to 2023, highlighting the importance of tailoring physicochemical properties and reproducibility for realizing RGO's full potential in sustainable, environmentally friendly, low-cost, and high-performing materials.