Homochiral Cu6Dy3 single-molecule magnets displaying proton conduction and a strong magneto-optical Faraday effect

Using the new Schiff base ligands condensed from 2-hydroxy-1-naphthalenecarboxaldehyde and (1R,2R)/ (1S,2S)-2-aminocyclohexanol (R-H3L/S-H3L), a pair of homochiral Cu6Dy3 heterometallic cluster complexes [Cu6Dy3(R-L) (6)(OH)(6)(H2O)(6)](ClO4)(NO3) (2)center dot 4.75H(2)O center dot 8.5MeOH (R-1) and [Cu6Dy3(S-L)(6)(OH)(6)(H2O)(6)] (ClO4)(NO3) 2 center dot 5.5H(2)O center dot 8MeOH (S-1) were synthesized at room temperature, which exhibit an interesting topology of triangular corner-sharing cubanes. Magnetic measurements revealed that they are zero-field single-molecule magnets (SMMs), with different U-eff/k values of 19.5(0.6) K for R-1 and 21.4(0.4) K for S-1, owing to solvent magnetic effects. Meanwhile, the chiral enantiomers show proton conductivity caused by hydrogen bonding networks. Furthermore, the circular dichroism (CD) spectra of R-1 and S-1 confirmed their enantiomeric nature, and the magnetic circular dichroism (MCD) study indicated that both R-1 and S-1 have strong magneto-optical Faraday effects at room temperature, with a large | gmax(MCD)| value of 0.58 T-1.

Automated summary

A pair of homochiral Cu6Dy3 heterometallic cluster complexes were synthesized using Schiff base ligands derived from 2-hydroxy-1-naphthalenecarboxaldehyde and (1R,2R)/(1S,2S)-2-aminocyclohexanol. These complexes show an interesting topology of triangular corner-sharing cubanes and exhibit zero-field single-molecule magnet behavior. The chiral enantiomers also show proton conductivity and have strong magneto-optical Faraday effects.