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Recent advances in conducting polymer-based magnetic nanosorbents for dyes and heavy metal removal: fabrication, applications, and perspective

Journal

ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH
Volume 30, Issue 29, Pages 73031-73060

Publisher

SPRINGER HEIDELBERG
DOI: 10.1007/s11356-023-27458-4

Keywords

Magnetic nanocomposites; Conducting polymers; Nanosorbents; Organic dyes; Heavy metal ions; Wastewater remediation

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Globally, the treatment and disposal of industrial pollutants, such as heavy metal ions (HMIs) and dyes, pose a significant challenge. The development of efficient and cost-effective technologies for removing these toxins from wastewater is crucial for public health and aquatic ecosystems. Conducting polymer-based magnetic nanocomposites (CP-MNCPs) have shown promise in adsorption-based wastewater treatment, particularly for HMIs and dye removal. The combination of CPs with SiO2, graphene oxide (GO), and multi-walled carbon nanotubes (MWCNTs) has demonstrated enhanced adsorption capacity, suggesting future research should focus on the development of cost-effective hybrid CPs-nanocomposites.
Globally, treating and disposing of industrial pollutants is a techno-economic challenge. Industries' large production of harmful heavy metal ions (HMIs) and dyes and inappropriate disposal worsen water contamination. Much attention is required on the development of efficient and cost-effective technologies and approaches for removing toxic HMIs and dyes from wastewater as they pose a severe threat to public health and aquatic ecosystems. Due to the proven superiority of adsorption over other alternative methods, various nanosorbents have been developed for the efficient removal of HMIs and dyes from wastewater and aqueous solutions. Being a good adsorbent, conducting polymer-based magnetic nanocomposites (CP-MNCPs) has drawn more attention for HMIs and dye removal. Conductive polymers' pH-responsiveness makes CP-MNCP ideal for wastewater treatment. The composite material absorbed dyes and/or HMIs from contaminated water could be removed by changing the pH. Here, we review the production strategies and applications of CP-MNCPs for HMIs and dye removal. The review also sheds light on the adsorption mechanism, adsorption efficiency, kinetic and adsorption models, and regeneration capacity of the various CP-MNCPs. To date, various modifications to conducting polymers (CPs) have been explored to improve the adsorption properties. It is evident from the literature survey that the combination of SiO2, graphene oxide (GO), and multi-walled carbon nanotubes (MWCNTs) with CPs-MNCPs enhances the adsorption capacity of nanocomposites to a large extent, so future research should lean toward the development of cost-effective hybrid CPs-nanocomposites.

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