Selective catalytic reduction of nitric oxide with a novel Mn-Ti-Ce oxide core-shell catalyst having improved low-temperature activity and water tolerance

A novel core-shell-shell Mn-Ti-Ce oxide catalyst (MnOx@TiO2@CeO2) was synthesized by a three-step method and applied for the selective catalytic reduction of NOx with ammonia (NH3-SCR). The catalyst exhibited an excellent low-temperature activity with NOx conversion >80% in a broad temperature range under both dry (120-260 degrees C) and wet (180-255 degrees C) conditions with a weight hourly space velocity (WHSV) of 240,000 mL/ (g center dot h). Nitrogen physisorption and X-ray photoelectron spectroscopy (XPS) results showed that the formation of the inner TiO2 shell significantly increased the specific surface area, surface Mn4+/Mn ratio and chemisorbed oxygen, which could provide more active sites and promote the oxidation of NO to NO2. Ammonia temperatureprogrammed desorption (NH3-TPD) results indicated that the formation of the outer CeO2 shell not only extensively increased the surface acid sites but also enhanced the acid strength, beneficial for the ammonia adsorption and resulting in a good water tolerance.

Automated summary

A novel core-shell-shell Mn-Ti-Ce oxide catalyst (MnOx@TiO2@CeO2) was synthesized and demonstrated excellent low-temperature activity for the selective catalytic reduction of NOx with ammonia (NH3-SCR). The formation of the inner TiO2 shell increased the specific surface area, surface Mn4+/Mn ratio and chemisorbed oxygen, promoting NO oxidation. The outer CeO2 shell enhanced surface acid sites and acid strength, beneficial for ammonia adsorption and water tolerance.