Valorization of lignocellulosic biomass into sustainable materials for adsorption and photocatalytic applications in water and air remediation

An exponential rise in global pollution and industrialization has led to significant economic and environmental problems due to the insufficient application of green technology for the chemical industry and energy production. Nowadays, the scientific and environmental/industrial communities push to apply new sustainable ways and/or materials for energy/environmental applications through the so-called circular (bio)economy. One of today's hottest topics is primarily valorizing available lignocellulosic biomass wastes into valuable materials for energy or environmentally related applications. This review aims to discuss, from both the chemistry and mechanistic points of view, the recent finding reported on the valorization of biomass wastes into valuable carbon materials. The sorption mechanisms using carbon materials prepared from biomass wastes by emphasizing the relationship between the synthesis route or/and surface modification and the retention performance were discussed towards the removal of organic and heavy metal pollutants from water or air (NOx, CO2, VOCs, SO2, and Hg-0). Photocatalytic nanoparticle-coated biomass-based carbon materials have proved to be successful composites for water remediation. The review discusses and simplifies the most raised interfacial, photonic, and physical mechanisms that might take place on the surface of these composites under light irradiation. Finally, the review examines the economic benefits and circular bioeconomy and the challenges of transferring this technology to more comprehensive applications.

Automated summary

An exponential rise in pollution and industrialization has created significant economic and environmental issues due to the lack of green technology in the chemical industry and energy production. There is now a push from the scientific and environmental/industrial communities to utilize sustainable methods and materials for energy and environmental applications in the circular (bio)economy. This review focuses on the valorization of biomass wastes into valuable carbon materials, discussing the chemistry and mechanistic aspects along with the sorption mechanisms for organic and heavy metal pollutant removal.