Influence of Co3O4-based catalysts on N2O catalytic decomposition and NO conversion

This study investigated the effect of different Co3O4-based catalysts on the catalytic decomposition of nitrous oxide (N2O) and on nitric oxide (NO) conversion. The experiments were carried out using various reaction temperatures, alkaline solutions, pH, mixing conditions, aging times, space velocities, impregnation loads, and compounds. The results showed that Co3O4 catalysts prepared by precipitation methods have the highest catalytic activity and N2O conversion, even at low reaction temperatures, while the commercial nano and powder forms of Co3O4 (CS) have the lowest performance. The catalysts become inactive at temperatures below 400 degrees C, and their activity is strongly influenced by the mixing temperature. Samples without stirring during the aging process have higher catalytic activity than those with stirring, even at low reaction temperatures (200-300 degrees C). The catalytic activity of Co3O4 PM1 decreases with low W/F values and low reaction temperatures. Additionally, the catalyst's performance tends to increase with the reduction process. The study suggests that cobalt-oxide-based catalysts are effective in N2O catalytic decomposition and NO conversion. The findings may be useful in the design and optimization of catalytic systems for N2O and NO control. The results obtained provide important insights into the development of highly efficient, low-cost, and sustainable catalysts for environmental protection.

Automated summary

This study explores the impact of different Co3O4-based catalysts on the catalytic decomposition of nitrous oxide (N2O) and the conversion of nitric oxide (NO). The results indicate that Co3O4 catalysts prepared through precipitation methods exhibit the highest activity and N2O conversion, even at low reaction temperatures, while commercial nano and powder forms of Co3O4 (CS) perform the poorest. The catalysts lose effectiveness below 400 degrees C, with their activity being greatly influenced by the mixing temperature. The findings offer valuable insights for designing and optimizing catalytic systems for N2O and NO control.