☆ 4.8 Review

Recent Progress of Promising Cathode Candidates for Sodium-Ion Batteries: Current Issues, Strategy, Challenge, and Prospects

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Low-Cost Zinc Substitution of Iron-Based Prussian Blue Analogs as Long Lifespan Cathode Materials for Fast Charging Sodium-Ion Batteries

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Insights into the improved cycle and rate performance by ex-situ F and in-situ Mg dual doping of layered oxide cathodes for sodium-ion batteries

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Fluffy-Like Cation-Exchanged Prussian Blue Analogues for Sodium- Ion Battery Cathodes

Yaozong Zhou et al.

Summary: In this study, fluffy-like nickel PB (PB-Ni) was prepared by replacing parts of Fe ion sites in PB with Ni ions, resulting in improved cycling stability for sodium-ion batteries. PB-Ni exhibited an initial capacity of 114.2 mA h g(-1) and a stable cycling performance of 800 cycles at 50mA g(-1). In situ X-ray diffraction characterization revealed reversible phase transformation and small volume variation for PB-Ni.

ACS APPLIED MATERIALS & INTERFACES (2022)

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Bimetal Substitution Enabled Energetic Polyanion Cathode for Sodium-Ion Batteries

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Summary: This study proposes a strategy of using cheaper metal elements to replace expensive ones in order to improve the sodium ion conductivity, and demonstrates the excellent performance of the obtained cathode material in terms of electrochemical properties, cycling stability, and low-temperature performance.

NANO LETTERS (2022)

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Achieving reversible Mn2+/Mn4+ double redox couple through anionic substitution in a P2-type layered oxide cathode

Haolv Hu et al.

Summary: In this study, we successfully introduced reversible Mn2+/Mn4+ double redox couple into P2-type Na0.6Mg0.3Mn0.7O2 cathode with suppressed Jahn-Teller (J-T) effect through F anion doping strategy. The introduction of F anions enlarged the interlayer spacing, reduced the band gap, improved charge transfer kinetics, suppressed Mn2+ dissolution, promoted reversible conversion, enhanced oxygen redox reaction, and ultimately enhanced the electrochemical performance.

NANO ENERGY (2022)

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Homogeneous hybridization of NASICON-type cathode for enhanced sodium-ion storage

Ying Geng et al.

Summary: By delicately regulating the reaction components and utilizing a hybridization strategy, a cathode material based on Na3V2(PO4)(3) has been designed to improve the kinetic performance and cycling stability of sodium-ion batteries. This research provides new possibilities for the development of sodium-ion batteries.

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Summary: This study proposes a non-aqueous ball-milling method assisted by an antioxidant and chelating agent to generate hollow Na2-xFe[Fe(CN)(6)](y) nanospheres. These hollow nanospheres exhibit low vacancies and interstitial water content, resulting in high sodium content, initial Coulombic efficiency, cycling stability, and rate performance.

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Progress on Fe-Based Polyanionic Oxide Cathodes Materials toward Grid-Scale Energy Storage for Sodium-Ion Batteries

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Summary: The development of large-scale energy storage systems is crucial for utilizing intermittent renewable energy sources. Fe-based sodium-ion battery cathodes, as substitutes for lithium-ion batteries, offer advantages such as earth-abundance, environmental friendliness, and safety. The Fe-based polyanionic oxide cathodes, with high thermal stability, ultra-long cycle life, and adjustable voltage, show great potential for commercial sodium-ion batteries.

SMALL METHODS (2022)

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Sodium Ion Storage in Na4MnV(PO4)3@C Free-Standing Electrode

Ping Hu et al.

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Article Chemistry, Multidisciplinary

Heterogeneous NASICON-Type Composite as Low-Cost, High-Performance Cathode for Sodium-Ion Batteries

Jin-Zhi Guo et al.

Summary: A double-carbon-layer decorated heterogeneous composite, Na3V2(PO4)(3)-Na3Fe2(PO4)(P2O7) (NVFPP/C/G), is successfully prepared to address the limitations of sodium-ion battery cathodes. The composite exhibits excellent electrochemical performance in both half-cell and full-cell systems.

ADVANCED FUNCTIONAL MATERIALS (2022)

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Article Chemistry, Multidisciplinary

Pilot-Scale Synthesis Sodium Iron Fluorophosphate Cathode with High Tap Density for a Sodium Pouch Cell

Yongjie Cao et al.

Summary: A kilogram-scale route to synthesize Na2FePO4F/carbon/multi-walled carbon nanotubes microspheres with high tap density has been developed for sodium-ion batteries. The cathode material exhibits a high reversible specific capacity and excellent cycling stability, making it a promising candidate for practical application.

SMALL (2022)

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Defect Engineering in Prussian Blue Analogs for High-Performance Sodium-Ion Batteries

Xinyi Liu et al.

Summary: Prussian blue and its analogs are promising materials for sodium-ion batteries, but structural defects generated during synthesis process can affect their electrochemical performance, while proper defect construction can achieve new functions.

ADVANCED ENERGY MATERIALS (2022)

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Article Chemistry, Physical

Prospective Sustainability Screening of Sodium-Ion Battery Cathode Materials

Manuel Baumann et al.

Summary: A comprehensive and flexible cathode active material screening method has been developed for sodium-ion batteries, providing a fast and comprehensive overview of potential sustainability hotspots for supporting cathode material selection; results show that energy density is one of the most important factors determining overall material demand, with most SIB cathodes showing very promising performance.

ADVANCED ENERGY MATERIALS (2022)

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Article Chemistry, Multidisciplinary

Double-Carbon-Layer Coated Na4MnV(PO4)3 Towards High-Performance Sodium-Ion Full Batteries

Hongyang Ma et al.

Summary: By using a double-carbon-layer coating strategy, the electronic conductivity and structural stability of NMVP material are enhanced, improving its sodium storage capacity and cycle stability. The modified NMVP electrode exhibits high capacity and good capacity retention at high rates, demonstrating excellent performance in sodium-ion batteries.

ADVANCED MATERIALS INTERFACES (2022)

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Article Chemistry, Physical

Interlocking biphasic chemistry for high-voltage P2/O3 sodium layered oxide cathode

Lianzheng Yu et al.

Summary: Biphasic hybridization of layered cathode materials is crucial for enhancing the storage performances of sodium-ion batteries (SIBs). In this study, a unique high-voltage-stable biphasic P2/O3 composite layered oxide-Na0.85Ni0.34Mn0.33Ti0.33O2 was successfully synthesized via Ti substitution. The biphasic cathode showed reversible structural evolution and improved structural stability under high-voltage regions, leading to excellent capacity retention and high energy density in full cells. These findings provide new insights into the design of composite structure materials for SIBs.

ENERGY STORAGE MATERIALS (2022)

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Recent Progress in Surface Coatings for Sodium-Ion Battery Electrode Materials

Tyler Or et al.

Summary: Sodium-ion batteries are a promising alternative to lithium-ion batteries, but their cycling stability and rate performance need improvement. Coatings offer a way to enhance electrode materials by reducing side reactions, limiting dissolution, and providing reinforcement. This review provides an overview and comparison of coatings applied to sodium-ion battery electrodes.

ELECTROCHEMICAL ENERGY REVIEWS (2022)

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Article Chemistry, Multidisciplinary

From Solid-Solution MXene to Cr-Substituted Na3V2(PO4)3: Breaking the Symmetry of Sodium Ions for High-Voltage and Ultrahigh-Rate Cathode Performance

Hong Yu et al.

Summary: A facile in-situ reactive transformation strategy was proposed to embed Cr-substituted NVP nanocrystals in a dual-carbon network, resulting in enhanced Na+ accessibility and accelerated Na+ diffusivity in the NVCP cathode. The NVCP cathode exhibited outstanding battery performance with high-rate capability, cycle stability, low-temperature property, and full cell performance.

ACS NANO (2022)

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Article Chemistry, Physical

3D porous spheroidal Na4Mn0.9Ce0.1V(PO4)3@CeO2/C cathode for high-energy Na ion batteries

Kun Wang et al.

Summary: The 3D porous spheroidal Ce3+-doped NMVP@CeO2/C cathode showed improved electronic conductivity and stabilized crystalline structure due to the synergistic effect of Ce3+ doping in the crystal framework and CeO2 surface coating. The optimized NMVP cathode delivered superior discharge performance and long cycle life, with potential for practical utilization in full cells demonstrated through successful assembly.

JOURNAL OF MATERIALS CHEMISTRY A (2022)

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Review Materials Science, Multidisciplinary

Air sensitivity of electrode materials in Li/Na ion batteries: Issues and strategies

Ruiwang Zhang et al.

Summary: With the development of electrode materials and the shifting of battery systems, the air sensitivity of electrode materials has become increasingly important. It is of great significance to understand the air degradation mechanism and explore new methods to enhance the air stability of electrode materials for the development of batteries with better performance. This review summarizes the issues related to air exposure of electrode materials in Li/Na ion batteries, including factors related to air sensitivity, degradation mechanisms, and recent progress in improving air stability.

INFOMAT (2022)

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Hexacyanoferrate-Type Prussian Blue Analogs: Principles and Advances Toward High-Performance Sodium and Potassium Ion Batteries

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Summary: This review discusses the research progress on HCF-type cathode materials, focusing on their structural features, redox mechanisms, synthesis control, and modification strategies for improved performance in NIBs and KIBs. The use of HCFs in these battery systems offers specific capacity and voltage advantages, with ongoing efforts to enhance their material properties and promote future design of PBAs for advanced rechargeable batteries.

ADVANCED ENERGY MATERIALS (2021)

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The Layered Oxides in Lithium and Sodium-Ion Batteries: A Solid-State Chemistry Approach

Claude Delmas et al.

Summary: This paper provides an overview of research on lithium and sodium layered materials as positive electrodes in lithium (sodium)-ion batteries, focusing on the solid-state chemistry's role in discovering new materials and optimizing properties for different applications. Layered structures, especially lithium-based ones, are considered as the best candidates for high energy density batteries for mobile applications. Through high-temperature solid-state chemistry, many substituted phases have been obtained to stabilize the layered structure and increase the specific capacity.

ADVANCED ENERGY MATERIALS (2021)

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Article Nanoscience & Nanotechnology

Manipulating the Phase Compositions of Na3(VO1-xPO4)F1+2x (0 ≤ x ≤ 1) and Their Synergistic Effects with Reduced Graphene Oxide toward High-Rate Sodium-Ion Batteries

Jiarong He et al.

Summary: Sodium-ion batteries have attracted attention due to the abundant and cost-effective sodium resources, with the NVPF1+2x cathode material optimized using a microwave-assisted hydrothermal approach showing promising electrochemical performances.

ACS APPLIED MATERIALS & INTERFACES (2021)

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Article Engineering, Environmental

High-voltage P2-type manganese oxide cathode induced by titanium gradient modification for sodium ion batteries

Quanqing Zhao et al.

Summary: The titanium gradient modification in the P2-Na0.66Mn0.54Ni0.13Co0.13O2 cathode can deliver high reversible discharge capacity, excellent stability, and rate capability, leading to increased energy density in sodium ion batteries.

CHEMICAL ENGINEERING JOURNAL (2021)

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Article Engineering, Environmental

Nanoscale surface modification of P2-type Na0.65[Mn0.70Ni0.16Co0.14]O2 cathode material for high-performance sodium-ion batteries

Qiang Deng et al.

Summary: The study successfully modified NMNCO with NTP through a wet chemical method, which significantly improved the performance and cycling stability of the NMNCO@NTP composite as a cathode material for SIBs.

CHEMICAL ENGINEERING JOURNAL (2021)

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Article Engineering, Environmental

Cu-doped layered P2-type Na0.67Ni0.33-xCuxMn0.67O2 cathode electrode material with enhanced electrochemical performance for sodium-ion batteries

Liu Yang et al.

Summary: Cu-doped layered P2-type Na0.67Ni0.33-xCuxMn0.67O2 materials were prepared and investigated for sodium-ion batteries. The introduction of Cu2+ ions improved the capacity retention, cycling stability, and rate performance by stabilizing the P2-phase structure and facilitating reversible capacity based on Cu2+/Cu3+ redox reaction.

CHEMICAL ENGINEERING JOURNAL (2021)

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Article Engineering, Environmental

Engineering sodium-rich manganese oxide with robust tunnel structure for high-performance sodium-ion battery cathode application

Jian Zhang et al.

Summary: A novel sodium-rich tunnel-type Na0.6MnO2 material was reported in this study, fancily prepared with the guidance of CTAB surfactant, exhibiting outstanding cycling durability and high discharge capacity. The sodium-rich tunnel-structured manganese oxide provides a new perspective for engineering high-performance SIB cathode materials.

CHEMICAL ENGINEERING JOURNAL (2021)

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Article Engineering, Environmental

Artificial cathode electrolyte interphase by functional additives toward long-life sodium-ion batteries

Iqra Moeez et al.

Summary: In this study, functional additives NaF and Na2CO3 were used to form a thick and stable cathode electrolyte interphase (CEI), effectively preventing capacity fading of Na0.67Fe0.5Mn0.5O2 during electrochemical cycles. The artificially induced CEI layer inhibits dissolution of transition metals and deterioration of the solid interphase, resulting in improved cyclability compared to bare Na0.67Fe0.5Mn0.5O2.

CHEMICAL ENGINEERING JOURNAL (2021)

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Review Chemistry, Physical

Recent Advances and Perspectives of Zn-Metal Free Rocking-Chair-Type Zn-Ion Batteries

Yuan Tian et al.

Summary: This review systematically evaluates the emerging rocking-chair-type Zn-ion batteries with Zn host anodes instead of Zn metal anodes. It discusses the fundamental principles, advantages, and challenges of rocking-chair-type Zn-ion batteries, summarizes the design principles and recent advances of cathode, anode, and electrolyte for rocking-chair Zn-ion batteries, and presents perspectives on the future of rocking-chair Zn-ion batteries. The review aims to provide alternative directions for the design of Zn-ion batteries.

ADVANCED ENERGY MATERIALS (2021)

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Article Nanoscience & Nanotechnology

Self-Template Synthesis of NaCrO2 Submicrospheres for Stable Sodium Storage

Shuo Wang et al.

Summary: This study focuses on the design and synthesis of the sodium-ion battery cathode material O3-NaCrO2, successfully producing s-NaCrO2 with high diffusion rate and stable structure. The s-NaCrO2 exhibits outstanding electrochemical performance and cycling stability in both high and low temperature environments, showing feasibility and potential application prospects.

ACS APPLIED MATERIALS & INTERFACES (2021)

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Article Chemistry, Multidisciplinary

Tailoring P2/P3 Biphases of Layered NaxMnO2 by Co Substitution for High-Performance Sodium-Ion Battery

Na Jiang et al.

Summary: The P2/P3-Na0.67Mn0.64Co0.30Al0.06O2 cathode with tunable biphase structures shows excellent rate capability and cycling stability for sodium-ion batteries, attributed to stable crystal structures and fast Na+ diffusion. The study highlights the importance of precisely tailoring phase composition in designing advanced cathode materials.

SMALL (2021)

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Article Chemistry, Physical

Tuning Sodium Occupancy Sites in P2-Layered Cathode Material for Enhancing Electrochemical Performance

Qin-Chao Wang et al.

Summary: The study successfully improved the sodium ion transport and electrochemical performance by adjusting the occupancy ratio of two different sodium sites in P2 layered cathode materials. In situ X-ray absorption spectroscopy revealed charge compensation provided by Mn and Ni redox couples. Sb substitution suppressed phase transition in the high voltage region, ensuring structural stability.

ADVANCED ENERGY MATERIALS (2021)

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Review Chemistry, Physical

Accommodating diverse ions in Prussian blue analogs frameworks for rechargeable batteries: The electrochemical redox reactions

Longtao Ma et al.

Summary: Prussian blue analogs (PBAs) show great potential as electrode materials for various rechargeable batteries, offering highly reversible insertion/removal of ions in both aqueous and non-aqueous electrolytes. However, challenges like limited electrochemical utilization of PBAs framework need to be addressed for further development.

NANO ENERGY (2021)

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Review Chemistry, Physical

Low-Cost Polyanion-Type Sulfate Cathode for Sodium-Ion Battery

Yun Gao et al.

Summary: The urgent need for developing renewable and clean energy storage devices due to environmental degradation and the energy crisis has led to sodium ion batteries (SIBs) being promising candidates. To accelerate the commercialization of SIBs, stable and high-voltage cathode materials, such as polyanionic sulfate materials (PSMs), are considered to be the most promising for increasing the energy density of SIBs.

ADVANCED ENERGY MATERIALS (2021)

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Article Chemistry, Physical

P2/O3 biphasic Fe/Mn-based layered oxide cathode with ultrahigh capacity and great cyclability for sodium ion batteries

Cong Chen et al.

Summary: By introducing high-proportion Li/Ti co-substitution, a unique Fe/Mn-based layered oxide with a P2/O3 biphasic architecture was successfully designed, offering high capacity and long cycling stability compared to other Fe- and Mn-based cathodes.

NANO ENERGY (2021)

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Article Materials Science, Multidisciplinary

Challenges and future perspectives on sodium and potassium ion batteries for grid-scale energy storage

Wenchao Zhang et al.

Summary: This article summarizes the latest developments in sodium and potassium ion batteries, including their challenges and strategies for achieving better electrochemical performance.

MATERIALS TODAY (2021)

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Article Chemistry, Physical

Surface-Modified Na(Ni0.3Fe0.4Mn0.3)O2 Cathodes with Enhanced Cycle Life and Air Stability for Sodium-Ion Batteries

Julia Lamb et al.

Summary: Sodium layered-oxide cathodes are considered as a promising alternative for energy storage, but the O3-type structures face challenges in cycle life and air stability. Phosphate coatings can mitigate these challenges, but the sodium extraction during coating process results in reduced capacity and conductivity, highlighting the unique issues of O3-type sodium layered oxides. Despite these challenges, a 1% (NaPO3)(n) coating shows significant improvement in capacity retention and air stability compared to uncoated samples.

ACS APPLIED ENERGY MATERIALS (2021)

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Article Multidisciplinary Sciences

Rapid mechanochemical synthesis of polyanionic cathode with improved electrochemical performance for Na-ion batteries

Xing Shen et al.

Summary: By employing a solvent-free mechanochemical protocol, sodium vanadium fluorophosphates have been successfully synthesized with improved electrochemical performance, demonstrating promise for industrial application in sodium-ion batteries.

NATURE COMMUNICATIONS (2021)

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Article Nanoscience & Nanotechnology

Stabilizing P2-Type Ni-Mn Oxides as High-Voltage Cathodes by a Doping-Integrated Coating Strategy Based on Zinc for Sodium-Ion Batteries

Fengping Zhang et al.

Summary: By doping with zinc element and applying a coating strategy, the electrochemical reversibility of Na0.66Ni0.33Mn0.67O2 has been effectively improved, resulting in enhanced cycling stability and rate performance.

ACS APPLIED MATERIALS & INTERFACES (2021)

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Article Nanoscience & Nanotechnology

Self-Template Synthesis of Prussian Blue Analogue Hollow Polyhedrons as Superior Sodium Storage Cathodes

Tianbei Huang et al.

Summary: A hollow-structured Prussian blue analogue (CoFePBA) was successfully prepared using a self-template method, and the addition of a thin polydopamine coating significantly improved its energy storage performance in sodium-ion batteries, resulting in a high capacity retention rate.

ACS APPLIED MATERIALS & INTERFACES (2021)

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Article Nanoscience & Nanotechnology

Continuous Conductive Networks Built by Prussian Blue Cubes and Mesoporous Carbon Lead to Enhanced Sodium-Ion Storage Performances

Ziheng Wang et al.

Summary: By modifying Prussian blue and its analogues, a composite material N-PB@CMK with high conductivity and capacitive contribution ratio has been developed, demonstrating excellent battery performance and stability.

ACS APPLIED MATERIALS & INTERFACES (2021)

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Article Electrochemistry

A collaborative strategy with ionic conductive Na2SiO3 coating and Si doping of P2-Na0.67Fe0.5Mn0.5O2 cathode: An effective solution to capacity attenuation

Jianyue Jiao et al.

Summary: This study focuses on a strategy of modifying layered oxide P2-Na0.67Fe0.5Mn0.5O2 with conducting ionic Na2SiO3 nanolayers and Si doping, resulting in excellent electrochemical performance including reduced polarization, improved cycling stability, and enhanced thermal stability.

ELECTROCHIMICA ACTA (2021)

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Article Chemistry, Physical

Multiple Influences of Nickel Concentration Gradient Structure and Yttrium Element Substitution on the Structural and Electrochemical Performances of the NaNi0.25Mn0.25Fe0.5O2 Cathode Material

Kang Wu et al.

Summary: A novel nickel concentration gradient NMF material (NCG-NMF) was designed with Y element doping to improve the cycle stability and rate performance of SIB cathode materials, demonstrating excellent capacity retention and cycling stability.

JOURNAL OF PHYSICAL CHEMISTRY C (2021)

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Review Nanoscience & Nanotechnology

Fundamentals, status and promise of sodium-based batteries

Robert Usiskin et al.

Summary: Sodium batteries have made significant progress in recent years and are considered promising candidates for mitigating supply risks associated with lithium batteries. This review compares the fundamental principles and specific materials of sodium and lithium batteries, and evaluates the performance of recent prototype sodium cells.

NATURE REVIEWS MATERIALS (2021)

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Article Green & Sustainable Science & Technology

Carbon-coated single crystal O3-NaFeO2 nanoflakes prepared via topochemical reaction for sodium-ion batteries

Yuhang Zhuang et al.

Summary: Layered O3-NaFeO2 nanoflakes were successfully synthesized via a solvothermal route without using Na2O2 as sodium source. A thin layer of carbon was coated on the nanoflakes to enhance electrode kinetics and structural stability. A full cell with carbon coated NaFeO2//hard carbon showed good cyclability with 81.9% capacity retention after 100 cycles.

SUSTAINABLE MATERIALS AND TECHNOLOGIES (2021)

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Article Chemistry, Physical

Effects of low doping on the improvement of cathode materials Na3+xV2-xMx(PO4)3 (M = Co2+, Cu2+; x=0.01-0.05) for SIBs

Ruoyu Chen et al.

Summary: Metal ion doping was used to enhance the electrochemical performance of Na (NVP) cathode material for sodium-ion batteries. The study demonstrated that doping with Co or Cu did not alter the NVP structure, and the presence of an amorphous carbon coating improved the electronic conductivity of the composites. Among the samples, Na/C composite showed the highest electrochemical ability with a stable reversible capacity even at high cycling rates.

JOURNAL OF MATERIALS CHEMISTRY A (2021)

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Article Chemistry, Physical

Preparation of intergrown P/O-type biphasic layered oxides as high-performance cathodes for sodium ion batteries

Kai Wang et al.

Summary: This study reports on the synthesis and characterization of novel quaternary P/O intergrown cathode materials and reveals their superior performance in a sodium ion battery. The nature of the P/O interface was studied by transmission electron microscopy, showing a semi-coherent interface grown along the a/b and c axes with local differences in transition metal concentration. EDX and EELS characterization revealed a charge compensation mechanism based on variation of transition element distribution across the phase boundary.

JOURNAL OF MATERIALS CHEMISTRY A (2021)

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Article Chemistry, Multidisciplinary

Defect-free-induced Na+ disordering in electrode materials

Jian Peng et al.

Summary: By using a self-healing method, defect-free PBAs were prepared as high-performance cathode materials for SIBs. The nickel-based PBAs achieved rapid Na+ extraction/insertion and nearly 100% capacity retention over 4000 cycles, ensuring long cycle life and high-rate capability.

ENERGY & ENVIRONMENTAL SCIENCE (2021)

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Review Chemistry, Multidisciplinary

A comprehensive understanding of the anionic redox chemistry in layered oxide cathodes for sodium-ion batteries

Junteng Jin et al.

Summary: The strategy of activating anionic redox in the cathodes of sodium-ion batteries has been shown to significantly improve energy density, leading to new advancements in the field. The latest progress and challenges of anionic redox in layered oxide cathodes have been comprehensively reviewed and discussed, providing valuable insights for future research on high-energy cathode materials.

SCIENCE CHINA-CHEMISTRY (2021)

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Article Nanoscience & Nanotechnology

Manipulating the Phase Compositions of Na-3(VO1-xPO4)F1+2x (0 <= x <= 1) and Their Synergistic Effects with Reduced Graphene Oxide toward High-Rate Sodium-Ion Batteries

Jiarong He et al.

Summary: This study optimized the electrochemical performance of NVPF1+2x using a one-step microwave-assisted hydrothermal method, manipulating phase compositions and introducing the conductive reduced graphene oxide (rGO) framework to significantly improve the cathode material performance.

ACS APPLIED MATERIALS & INTERFACES (2021)

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Article Engineering, Environmental

O3-type NaNi0.5Mn0.5O2 hollow microbars with exposed {010} facets as high performance cathode materials for sodium-ion batteries

Qianjiang Mao et al.

CHEMICAL ENGINEERING JOURNAL (2020)

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Article Chemistry, Physical

Fluorophosphates as Efficient Bifunctional Electrocatalysts for Metal-Air Batteries

Lalit Sharma et al.

ACS CATALYSIS (2020)

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Article Chemistry, Physical

Crystallization-induced ultrafast Na-ion diffusion in nickel hexacyanoferrate for high-performance sodium-ion batteries

Yue Xu et al.

NANO ENERGY (2020)

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Article Nanoscience & Nanotechnology

Core-Shell Layered Oxide Cathode for High-Performance Sodium-Ion Batteries

Cheng Chen et al.

ACS APPLIED MATERIALS & INTERFACES (2020)

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Article Chemistry, Multidisciplinary

Constructing Na-Ion Cathodes via Alkali-Site Substitution

Chenglong Zhao et al.

ADVANCED FUNCTIONAL MATERIALS (2020)

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Review Chemistry, Multidisciplinary

The Cathode Choice for Commercialization of Sodium-Ion Batteries: Layered Transition Metal Oxides versus Prussian Blue Analogs

Qiannan Liu et al.

ADVANCED FUNCTIONAL MATERIALS (2020)

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Article Chemistry, Physical

Enhancing the interfacial stability of P2-type cathodes by polydopamine-derived carbon coating for achieving performance improvement

Jiuyang Xia et al.

CARBON (2020)

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Article Chemistry, Multidisciplinary

Suppressing Cation Migration and Reducing Particle Cracks in a Layered Fe-Based Cathode for Advanced Sodium-Ion Batteries

Jialu Xu et al.

SMALL (2020)

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Article Chemistry, Multidisciplinary

A Heterostructure Coupling of Bioinspired, Adhesive Polydopamine, and Porous Prussian Blue Nanocubics as Cathode for High-Performance Sodium-Ion Battery

Yang Liu et al.

SMALL (2020)

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Article Multidisciplinary Sciences

Reversible structural evolution of sodium-rich rhombohedral Prussian blue for sodium-ion batteries

Wanlin Wang et al.

NATURE COMMUNICATIONS (2020)

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Article Chemistry, Applied

Effect of cation (Li+, Na+, K+, Rb+, Cs+) in aqueous electrolyte on the electrochemical redox of Prussian blue analogue (PBA) cathodes

Satyajit Phadke et al.

JOURNAL OF ENERGY CHEMISTRY (2020)

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Article Chemistry, Physical

High-Voltage Oxygen-Redox-Based Cathode for Rechargeable Sodium-Ion Batteries

Aishuak Konarov et al.

ADVANCED ENERGY MATERIALS (2020)

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Article Chemistry, Multidisciplinary

Stepwise Hollow Prussian Blue Nanoframes/Carbon Nanotubes Composite Film as Ultrahigh Rate Sodium Ion Cathode

Ping Wan et al.

ADVANCED FUNCTIONAL MATERIALS (2020)

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Article Chemistry, Multidisciplinary

Overcoming the Unfavorable Kinetics of Na3V2(PO4)2F3//SnPx Full-Cell Sodium-Ion Batteries for High Specific Energy and Energy Efficiency

Hayong Song et al.

ADVANCED FUNCTIONAL MATERIALS (2020)

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Article Chemistry, Physical

Construction of the Na0.92Li0.40Ni0.73Mn0.24Co0.12O2 sodium-ion cathode with balanced high-power/energy-densities

Changchun Sun et al.

ENERGY STORAGE MATERIALS (2020)

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Article Chemistry, Physical

Oxygen redox activity with small voltage hysteresis in Na0.67Cu0.28Mn0.72O2 for sodium-ion batteries

Wei Zheng et al.

ENERGY STORAGE MATERIALS (2020)

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Article Materials Science, Multidisciplinary

One-step solid-state reaction synthesis of β-NaFeO2 nanopebble as high capacity cathode material for sodium ion batteries

Lignesh Durai et al.

MATERIALS LETTERS (2020)

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Article Chemistry, Physical

Na-Ion Batteries-Approaching Old and New Challenges

Eider Goikolea et al.

ADVANCED ENERGY MATERIALS (2020)

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Article Chemistry, Multidisciplinary

Oriented Formation of a Prussian Blue Nanoflower as a High Performance Cathode for Sodium Ion Batteries

Daxian Zuo et al.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2020)

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Article Chemistry, Multidisciplinary

Dual-Strategy of Cation-Doping and Nanoengineering Enables Fast and Stable Sodium-Ion Storage in a Novel Fe/Mn-Based Layered Oxide Cathode

Qiuyu Shen et al.

ADVANCED SCIENCE (2020)

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Article Engineering, Environmental

Construction nasicon-type NaTi2(PO4)3 nanoshell on the surface of P2-type Na0 .67Co0.2Mn0.8O2 cathode for superior room/low-temperature sodium storage

Yong Li et al.

CHEMICAL ENGINEERING JOURNAL (2020)

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Article Multidisciplinary Sciences

Rational design of layered oxide materials for sodium-ion batteries

Chenglong Zhao et al.

SCIENCE (2020)

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Article Chemistry, Physical

Sodium storage property and mechanism of NaCr1/4Fe1/4Ni1/4Ti1/4O2 cathode at various cut-off voltages

Ming-Hui Cao et al.

ENERGY STORAGE MATERIALS (2020)

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Review Nanoscience & Nanotechnology

Polyanion-type electrode materials for advanced sodium-ion batteries

N. Zhao et al.

MATERIALS TODAY NANO (2020)

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Article Chemistry, Physical

Effect of the interfacial protective layer on the NaFe0.5Ni0.5O2 cathode for rechargeable sodium-ion batteries

Iqra Moeez et al.

JOURNAL OF MATERIALS CHEMISTRY A (2020)

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Review Chemistry, Multidisciplinary

Polyanion-type cathode materials for sodium-ion batteries

Ting Jin et al.

CHEMICAL SOCIETY REVIEWS (2020)

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Article Chemistry, Physical

Influence of Na/Mn arrangements and P2/P′2 phase ratio on the electrochemical performance of NaxMnO2 cathodes for sodium-ion batteries

Andrzej Kulka et al.

JOURNAL OF MATERIALS CHEMISTRY A (2020)

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Article Chemistry, Physical

Understanding the Multiple Effects of TiO2 Coating on NaMn0.33Fe0.33Ni0.33O2 Cathode Material for Na-Ion Batteries

Yang Yu et al.

ACS APPLIED ENERGY MATERIALS (2020)

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Article Chemistry, Multidisciplinary

Recent Progress of Layered Transition Metal Oxide Cathodes for Sodium-Ion Batteries

Qiannan Liu et al.

SMALL (2019)

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Review Chemistry, Physical

High-Abundance and Low-Cost Metal-Based Cathode Materials for Sodium-Ion Batteries: Problems, Progress, and Key Technologies

Mingzhe Chen et al.

ADVANCED ENERGY MATERIALS (2019)

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Article Chemistry, Physical

A Stable Layered Oxide Cathode Material for High-Performance Sodium-Ion Battery

Yao Xiao et al.

ADVANCED ENERGY MATERIALS (2019)

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Article Chemistry, Multidisciplinary

Manganese-Based Na-Rich Materials Boost Anionic Redox in High-Performance Layered Cathodes for Sodium-Ion Batteries

Xiaoyu Zhang et al.

ADVANCED MATERIALS (2019)

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Article Chemistry, Multidisciplinary

Chemical Properties, Structural Properties, and Energy Storage Applications of Prussian Blue Analogues

Wei-Jie Li et al.

SMALL (2019)

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Article Energy & Fuels

Building aqueous K-ion batteries for energy storage

Liwei Jiang et al.

NATURE ENERGY (2019)

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Article Chemistry, Multidisciplinary

Low-Cost Self-Assembled Oxide Separator for Rechargeable Batteries

Nicholas S. Grundish et al.

ADVANCED FUNCTIONAL MATERIALS (2019)

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Article Chemistry, Physical

Structural stability and ionic transport property of NaMPO4 (M = V, Cr, Mn, Fe, Co, Ni) as cathode material for Na-ion batteries

Lin Zhu et al.

JOURNAL OF POWER SOURCES (2019)

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Article Nanoscience & Nanotechnology

Ultralong Layered NaCrO2 Nanowires: A Competitive Wide-Temperature-Operating Cathode for Extraordinary High-Rate Sodium-Ion Batteries

Longwei Liang et al.

ACS APPLIED MATERIALS & INTERFACES (2019)

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Article Chemistry, Physical

Polydopamine-derived N-doped carbon-wrapped Na3V2(PO4)3 cathode with superior rate capability and cycling stability for sodium-ion batteries

Hyeongwoo Kim et al.

NANO RESEARCH (2019)

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Article Nanoscience & Nanotechnology

Insight into Preparation of Fe-Doped Na3V2(PO4)3@C from Aspects of Particle Morphology Design, Crystal Structure Modulation, and Carbon Graphitization Regulation

Xiaohong Liu et al.

ACS APPLIED MATERIALS & INTERFACES (2019)

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Article Chemistry, Multidisciplinary

Prussian blue coupling with zinc oxide as a protective layer: an efficient cathode for high-rate sodium-ion batteries

Yun Qiao et al.

CHEMICAL COMMUNICATIONS (2019)

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Article Chemistry, Physical

CuO-Coated and Cu2+-doped Co-modified P2-type Na2/3[Ni1/3Mn2/3]O2 for sodium-ion batteries

Rongbin Dang et al.

PHYSICAL CHEMISTRY CHEMICAL PHYSICS (2019)

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Article Electrochemistry

Tribute to Michel Armand: from Rocking Chair - Li-ion to Solid-State Lithium Batteries

Alain Mauger et al.

JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2019)

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Review Chemistry, Physical

Review on anionic redox in sodium-ion batteries

Hang Xu et al.

JOURNAL OF MATERIALS CHEMISTRY A (2019)

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Article Chemistry, Physical

An Al-doped high voltage cathode of Na4Co3(PO4)2P2O7 enabling highly stable 4 V full sodium-ion batteries

Xiaohao Liu et al.

JOURNAL OF MATERIALS CHEMISTRY A (2019)

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Article Chemistry, Physical

Hierarchical Hollow Prussian Blue Rods Synthesized via Self-Sacrifice Template as Cathode for High Performance Sodium Ion Battery

Fan Feng et al.

SMALL METHODS (2019)

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Review Chemistry, Physical

Progress in High-Voltage Cathode Materials for Rechargeable Sodium-Ion Batteries

Ya You et al.

ADVANCED ENERGY MATERIALS (2018)

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Review Chemistry, Physical

Layered Oxide Cathodes for Sodium-Ion Batteries: Phase Transition, Air Stability, and Performance

Peng-Fei Wang et al.

ADVANCED ENERGY MATERIALS (2018)

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Article Electrochemistry

On the Effect of Silicon Substitution in Na3V2(PO4)(3) on the Electrochemical Behavior as Cathode for Sodium-Ion Batteries

Mari J. Aragon et al.

CHEMELECTROCHEM (2018)

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Article Chemistry, Multidisciplinary

A General Metal-Organic Framework (MOF)-Derived Selenidation Strategy for In Situ Carbon-Encapsulated Metal Selenides as High-Rate Anodes for Na-Ion Batteries

Xijun Xu et al.

ADVANCED FUNCTIONAL MATERIALS (2018)

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Article Chemistry, Physical

Surface engineering induced core-shell Prussian blue@polyaniline nanocubes as a high-rate and long-life sodium-ion battery cathode

Qi Zhang et al.

JOURNAL OF POWER SOURCES (2018)

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Article Chemistry, Multidisciplinary

Insight into Ca-Substitution Effects on O3-Type NaNi1/3Fe1/3Mn1/3O2 Cathode Materials for Sodium-Ion Batteries Application

Liqi Sun et al.

SMALL (2018)

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Article Chemistry, Multidisciplinary

A Chemical Precipitation Method Preparing Hollow-Core-Shell Heterostructures Based on the Prussian Blue Analogs as Cathode for Sodium-Ion Batteries

Yongxin Huang et al.

SMALL (2018)

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Article Chemistry, Physical

Bioinspired Surface Layer for the Cathode Material of High-Energy-Density Sodium-Ion Batteries

Chang-Heum Jo et al.

ADVANCED ENERGY MATERIALS (2018)

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Article Chemistry, Physical

KVOPO4: A New High Capacity Multielectron Na-Ion Battery Cathode

Jia Ding et al.

ADVANCED ENERGY MATERIALS (2018)

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Review Chemistry, Physical

Sodium and Sodium-Ion Batteries: 50 Years of Research

Claude Delmas

ADVANCED ENERGY MATERIALS (2018)

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Review Chemistry, Physical

Polyanionic Insertion Materials for Sodium-Ion Batteries

Prabeer Barpanda et al.

ADVANCED ENERGY MATERIALS (2018)

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Review Chemistry, Physical

Prussian Blue Cathode Materials for Sodium-Ion Batteries and Other Ion Batteries

Jiangfeng Qian et al.

ADVANCED ENERGY MATERIALS (2018)

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Article Chemistry, Physical

A Dual-Insertion Type Sodium-Ion Full Cell Based on High-Quality Ternary-Metal Prussian Blue Analogs

Jian Peng et al.

ADVANCED ENERGY MATERIALS (2018)

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Review Chemistry, Applied

Progress and prospect for NASICON-type Na3V2(PO4)(3) for electrochemical energy storage

Qiong Zheng et al.

JOURNAL OF ENERGY CHEMISTRY (2018)

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Editorial Material Multidisciplinary Sciences

What is the promising anode material for Na ion batteries?

Yangyang Zhou et al.

SCIENCE BULLETIN (2018)

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Review Energy & Fuels

Fundamental understanding and practical challenges of anionic redox activity in Li-ion batteries

Gaurav Assat et al.

NATURE ENERGY (2018)

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Article Chemistry, Multidisciplinary

Room-Temperature Liquid Na-K Anode Membranes

Leigang Xue et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2018)

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Article Chemistry, Physical

A Novel Graphene Oxide Wrapped Na2Fe2(SO4)3/C Cathode Composite for Long Life and High Energy Density Sodium-Ion Batteries

Mingzhe Chen et al.

ADVANCED ENERGY MATERIALS (2018)

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Review Electrochemistry

Electrode Materials for Sodium-Ion Batteries: Considerations on Crystal Structures and Sodium Storage Mechanisms

Tianyi Wang et al.

ELECTROCHEMICAL ENERGY REVIEWS (2018)

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Article Chemistry, Physical

Scalable Room-Temperature Synthesis of Multi-shelled Na-3(VOPO4)(2)F Microsphere Cathodes

Yuruo Qi et al.

JOULE (2018)

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Article Chemistry, Multidisciplinary

Prussian Blue@MoS2 Layer Composites as Highly Efficient Cathodes for Sodium- and Potassium-Ion Batteries

Marc Morant-Giner et al.

ADVANCED FUNCTIONAL MATERIALS (2018)

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Article Chemistry, Physical

A promising approach for the recovery of high value-added metals from spent lithium-ion batteries

Juntao Hu et al.

JOURNAL OF POWER SOURCES (2017)

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Article Chemistry, Physical

Crystal chemistry of Mg substitution in NaMnPO4 olivine: concentration limit and cation distribution

T. Boyadzhieva et al.

PHYSICAL CHEMISTRY CHEMICAL PHYSICS (2017)

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Article Chemistry, Physical

GO-induced preparation of flake-shaped Na3V2(PO4)3@rGO as high-rate and long-life cathodes for sodium-ion batteries

Feng Li et al.

JOURNAL OF MATERIALS CHEMISTRY A (2017)

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Article Chemistry, Physical

Resolving the degradation pathways of the O3-type layered oxide cathode surface through the nano-scale aluminum oxide coating for high-energy density sodium-ion batteries

Jang-Yeon Hwang et al.

JOURNAL OF MATERIALS CHEMISTRY A (2017)

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Review Chemistry, Physical

Carbon nanofiber-based nanostructures for lithium-ion and sodium-ion batteries

Weihan Li et al.

JOURNAL OF MATERIALS CHEMISTRY A (2017)

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Review Chemistry, Physical

A review on hexacyanoferrate-based materials for energy storage and smart windows: challenges and perspectives

Andrea Paolella et al.

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Hierarchical Ru-doped sodium vanadium fluorophosphates hollow microspheres as a cathode of enhanced superior rate capability and ultralong stability for sodium-ion batteries

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NANO ENERGY (2017)

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Core-shell structured CoP/FeP porous microcubes interconnected by reduced graphene oxide as high performance anodes for sodium ion batteries

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NANO ENERGY (2017)

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Polyanion-Type Electrode Materials for Sodium-Ion Batteries

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ADVANCED SCIENCE (2017)

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Review Chemistry, Multidisciplinary

Challenges and Perspectives for NASICON-Type Electrode Materials for Advanced Sodium-Ion Batteries

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ADVANCED MATERIALS (2017)

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BATTERIES-BASEL (2017)

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A High Capacity, Good Safety and Low Cost Na2FeSiO4-Based Cathode for Rechargeable Sodium-Ion Battery

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ACS APPLIED MATERIALS & INTERFACES (2017)

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A Practical High-Energy Cathode for Sodium-Ion Batteries Based on Uniform P2-Na0.7CoO2 Microspheres

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ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2017)

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Multiangular Rod-Shaped Na0.44MnO2 as Cathode Materials with High Rate and Long Life for Sodium-Ion Batteries

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ACS APPLIED MATERIALS & INTERFACES (2017)

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Double-Nanocarbon Synergistically Modified Na3V2(PO4)3: An Advanced Cathode for High-Rate and Long-Life Sodium-Ion Batteries

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ACS APPLIED MATERIALS & INTERFACES (2016)

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Na3V2(PO4)3/C Nanorods with Improved Electrode-Electrolyte Interface As Cathode Material for Sodium-Ion Batteries

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ACS APPLIED MATERIALS & INTERFACES (2016)

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Subzero-Temperature Cathode for a Sodium-Ion Battery

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ADVANCED MATERIALS (2016)

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Strong Oxygen Participation in the Redox Governing the Structural and Electrochemical Properties of Na-Rich Layered Oxide Na2IrO3

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CHEMISTRY OF MATERIALS (2016)

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Sodium Extraction from NASICON-Structured Na3MnTi(PO4)3 through Mn(III)/Mn(II) and Mn(IV)/Mn(III) Redox Couples

Hongcai Gao et al.

CHEMISTRY OF MATERIALS (2016)

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Jahn-Teller Assisted Na Diffusion for High Performance Na Ion Batteries

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CHEMISTRY OF MATERIALS (2016)

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Uniform Hierarchical Fe3O4@Polypyrrole Nanocages for Superior Lithium Ion Battery Anodes

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ADVANCED ENERGY MATERIALS (2016)

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The Anode Challenge for Lithium-Ion Batteries: A Mechanochemically Synthesized Sn-Fe-C Composite Anode Surpasses Graphitic Carbon

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Review Chemistry, Multidisciplinary

Recent Advances and Prospects of Cathode Materials for Sodium-Ion Batteries

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ADVANCED MATERIALS (2015)

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Energy Storage Materials from Nature through Nanotechnology: A Sustainable Route from Reed Plants to a Silicon Anode for Lithium-Ion Batteries

Jun Liu et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2015)

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New Insights into the Performance Degradation of Fe-Based Layered Oxides in Sodium-Ion Batteries: Instability of Fe3+/Fe4+ Redox in α-NaFeO2

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CHEMISTRY OF MATERIALS (2015)

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NaCrO2 cathode for high-rate sodium-ion batteries

Chan-Yeop Yu et al.

ENERGY & ENVIRONMENTAL SCIENCE (2015)

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Uniform yolk-shell Sn4P3@C nanospheres as high-capacity and cycle-stable anode materials for sodium-ion batteries

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ENERGY & ENVIRONMENTAL SCIENCE (2015)

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Fast discharge process of layered cobalt oxides due to high Na+ diffusion

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SCIENTIFIC REPORTS (2015)

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Multifunctional conducing polymer coated Na1+xMnFe(CN)6 cathode for sodium-ion batteries with superior performance via a facile and one-step chemistry approach

Wei-Jie Li et al.

NANO ENERGY (2015)

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Facile synthesis of P2-type Na0.4Mn0.54Co0.46O2 as a high capacity cathode material for sodium-ion batteries

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RSC ADVANCES (2015)

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Highly crystalline Prussian blue/graphene composites for high-rate performance cathodes in Na-ion batteries

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RSC ADVANCES (2015)

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Research Development on Sodium-Ion Batteries

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CHEMICAL REVIEWS (2014)

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High-voltage NASICON Sodium Ion Batteries: Merits of Fluorine Insertion

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ELECTROCHIMICA ACTA (2014)

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P2-type Na0.67Mn0.65Fe0.2Ni0.15O2 Cathode Material with High-capacity for Sodium-ion Battery

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ELECTROCHIMICA ACTA (2014)

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High-quality Prussian blue crystals as superior cathode materials for room-temperature sodium-ion batteries

Ya You et al.

ENERGY & ENVIRONMENTAL SCIENCE (2014)

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Temperature dependence of anisotropic displacement parameters in O3-type NaMO 2 ( M = Cr and Fe): Comparison with isostructural LiCoO 2

D. Tanabe et al.

PHYSICA STATUS SOLIDI-RAPID RESEARCH LETTERS (2014)

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Manganese hexacyanomanganate open framework as a high-capacity positive electrode material for sodium-ion batteries

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NATURE COMMUNICATIONS (2014)

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Na2FeP2O7 as a Promising Iron-Based Pyrophosphate Cathode for Sodium Rechargeable Batteries: A Combined Experimental and Theoretical Study

Heejin Kim et al.

ADVANCED FUNCTIONAL MATERIALS (2013)

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Magnetic Structures of NaFePO4 Maricite and Triphylite Polymorphs for Sodium-Ion Batteries

Maxim Avdeev et al.

INORGANIC CHEMISTRY (2013)

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First-Principles Study of Alkali and Alkaline Earth Ion Intercalation in Iron Hexacyanoferrate: The Important Role of Ionic Radius

Chen Ling et al.

JOURNAL OF PHYSICAL CHEMISTRY C (2013)

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Structural Response of P2-Type NaxMnO2 against Na+ Intercalation

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JOURNAL OF THE PHYSICAL SOCIETY OF JAPAN (2013)

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Comparison of electrochemical performances of olivine NaFePO4 in sodium-ion batteries and olivine LiFePO4 in lithium-ion batteries

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NANOSCALE (2013)

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The Birth of the Lithium-Ion Battery

Akira Yoshino

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2012)

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Opportunities and challenges for a sustainable energy future

Steven Chu et al.

NATURE (2012)

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Structure and Stability of Sodium Intercalated Phases in Olivine FePO4

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Review on thermal energy storage with phase change materials and applications

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RENEWABLE & SUSTAINABLE ENERGY REVIEWS (2009)

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Thermal oxidation strategy towards porous metal oxide hollow architectures

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ADVANCED MATERIALS (2008)

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Prussian blue: Artists' pigment and chemists' sponge

Mike Ware

JOURNAL OF CHEMICAL EDUCATION (2008)

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Biodiesel from microalgae

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BIOTECHNOLOGY ADVANCES (2007)

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