Journal
DALTON TRANSACTIONS
Volume 52, Issue 27, Pages 9368-9376Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d3dt01209c
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Mixing cations with different chemical properties is a new approach for tuning the optical properties of hybrid organic-inorganic metal halides (HOIMHs). In this study, zero-dimensional (C9N3H15)(C9H13SO)MBr6 (M = Bi/Sb) with two different cations were synthesized, resulting in significant second harmonic generation. The synthesized compounds exhibited direct bandgaps and bright yellow emission due to fluorescence emission.
Mixing cations with different chemical properties to induce the generation of asymmetric structures is a new approach for tuning the optical properties of hybrid organic-inorganic metal halides (HOIMHs). In this study, zero-dimensional (C9N3H15)(C9H13SO)MBr6 (M = Bi/Sb, [C9N3H15](2+) = [(C4N2H10)(C5NH5)](2+) and [C9H14SO](+) = [CH3(C6H4)OS(CH3)(2)](+)) are synthesized. Two different cations cause both compounds to crystallize in the polar space group P2(1)2(1)2(1), thus resulting in significant phase matchable second harmonic generation under a 1064 nm laser excitation. Thus, (C9N3H15)(C9H13SO)BiBr6 and (C9N3H15)(C9H13SO)SbBr6 exhibit intensities that are approximately 1.8 and 1.7 times that of KH2PO4, respectively. The results of density functional theory calculations show that both (C9N3H15)(C9H13SO)BiBr6 and (C9N3H15)(C9H13SO)SbBr6 exhibit direct bandgaps of 2.95 and 2.81 eV, respectively. Additionally, because of the distortion of the inorganic octahedra, (C9N3H15)(C9H13SO)SbBr6 exhibited bright yellow emission at room temperature, which is attributed to ns(2) fluorescence emission. We believe that the symmetry of the HOIMH crystal structure can be broken by introducing spatially differentiated bifunctional organic cations, which consequently enables even-order nonlinear activities.
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