Journal
INORGANIC CHEMISTRY FRONTIERS
Volume 10, Issue 14, Pages 4117-4125Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d3qi00731f
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By utilizing solvent-oriented structural self-assembly and solvent-induced single-crystal to single-crystal transformation strategies, eight structurally distinct Cd-CPs were controllably synthesized with the same linkers for the first time. The significant role of solvents in the self-assembly and transformations in CPs has been demonstrated, and rare reversible CP-based phase transition phenomena at low temperatures were observed, including the first example of a novel turn-on-off CP-based Fe3+ ion sensor.
Linker conformation engineering provides opportunities for the structural diversity of coordination polymers (CPs); however, the approaches for modulating the synthesis solvents to influence linker conformation are very limited, and they are facing unpredictable challenges to date. Herein, through strategies of solvent-oriented structural self-assembly and solvent-induced single-crystal to single-crystal transformation, eight structurally distinct Cd-CPs were controllably synthesized with the same linkers for the first time. The decisive role of solvents in the self-assembly and transformations in CPs has been demonstrated in depth. Besides, rare reversible CP-based phase transition phenomena at low temperatures were observed. One of these represents the first example of an unprecedented turn-on-off CP-based Fe3+ ion sensor.
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