Journal
CHEMICAL COMMUNICATIONS
Volume 59, Issue 53, Pages 8270-8273Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d3cc02136j
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Efficient annulation of in situ formed azaoxyallyl cations using diaziridines has been achieved at room temperature with the aid of a base, leading to the formation of 1,2,4-triazines. The practical advantages of this reaction include its broad substrate scope, scalability, high tolerance towards functional groups, and the absence of transition-metal catalysts.
Efficient annulation of in situ formed azaoxyallyl cations using a base has been accomplished with diaziridines to provide 1,2,4-triazines at room temperature. The substrate scope, scale up, functional group tolerance and transition-metal free reaction conditions are the important practical features.
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