4.7 Article

Electronic structure modulation of Pdn (n=2-5) nanoclusters in the hydrogenation of cinnamaldehyde

Related references

Note: Only part of the references are listed.
Article Biochemical Research Methods

DFT study of interaction of Palladium Pdn (n=1-6) nanoparticles with deep eutectic solvents

Hamid Reza Ghenaatian et al.

Summary: In this study, density functional theory calculations were used to investigate the stability, reactivity, and interactions of Palladium Pd-n nanoparticles with ChCl:U and ChCl:EG based deep eutectic solvents. The DES Pd-n complexes were found to be stabilized by two types of binding, with charge transfer playing an important role in their stability.Overall, these DESs are potentially promising green solvents for nanoparticle synthesis and activity.

JOURNAL OF MOLECULAR GRAPHICS & MODELLING (2022)

Article Chemistry, Physical

Single palladium atoms stabilized by β-FeOOH nanorod with superior performance for selective hydrogenation of cinnamaldehyde

Zhijun Li et al.

Summary: This study presents a synthetic approach to create defect-containing beta-FeOOH doped with isolated palladium atoms that bond covalently to nearby oxygen and iron atoms. The single palladium atom catalyst demonstrates outstanding catalytic efficiency in the selective hydrogenation of cinnamaldehyde. The high catalytic activity and strong metal-support interaction of the catalyst stem from the unique coordination environment of the isolated palladium atoms.

NANO RESEARCH (2022)

Review Chemistry, Multidisciplinary

Biotechnological synthesis of Pd-based nanoparticle catalysts

Christopher Egan-Morriss et al.

Summary: Palladium metal nanoparticles are important catalysts that can be prepared through microbial bioreduction, avoiding the use of toxic chemicals for sustainable utilization; recent studies have shown that using bio-bimetallic nanoparticles can significantly enhance the catalytic properties of palladium.

NANOSCALE ADVANCES (2022)

Article Multidisciplinary Sciences

The promotion effect of π-π interactions in Pd NPs catalysed selective hydrogenation

Miao Guo et al.

Summary: The utilization of weak interactions to improve the catalytic performance is crucial but challenging. This study demonstrates that by using imine-linked covalent organic frameworks, the weak interactions near Pd nanoparticles can be finely tuned. The pi-pi interaction between the organic frameworks and the substrate significantly reduces the activation barrier, thus enhancing the catalytic activity.

NATURE COMMUNICATIONS (2022)

Article Chemistry, Multidisciplinary

Selective Hydrogenolysis of 5-Hydroxymethylfurfural into 2,5-Dimethylfuran under Mild Conditions Using Pd/MOF-808

Kaili Zhang et al.

Summary: This article introduces a Zr-based metal-organic framework (MOF-808) supported Pd catalyst, which can efficiently catalyze the hydrogenolysis of HMF under mild conditions with a yield of 99%, and also shows good reusability.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2022)

Review Chemistry, Physical

Well-Defined Pdn Clusters for Cross-Coupling and Hydrogenation Catalysis: New Opportunities for Catalyst Design

Neda Jeddi et al.

Summary: Recent studies have shown that the privileged reactivity of higher-order metal clusters can be utilized in widely applied catalytic processes. Small Pdn clusters with unique reactivity, selectivity, and catalyst behavior have been discovered, presenting potential in catalyst design and application. This review focuses on the catalytic applications of Pdn clusters and discusses the underlying structure linked to their reactivity. It further proposes a hypothesis regarding the formation of higher-order Pd species through ligated Pdn clusters.

ACS CATALYSIS (2022)

Review Chemistry, Multidisciplinary

Palladium Nanoparticles in Polyols: Synthesis, Catalytic Couplings, and Hydrogenations

Isabelle Favier et al.

CHEMICAL REVIEWS (2020)

Review Chemistry, Multidisciplinary

Selective Hydrogenation over Supported Metal Catalysts: From Nanoparticles to Single Atoms

Leilei Zhang et al.

CHEMICAL REVIEWS (2020)

Review Chemistry, Inorganic & Nuclear

Atomic-precision engineering of metal nanoclusters

Xiangsha Du et al.

DALTON TRANSACTIONS (2020)

Review Chemistry, Physical

Transformation of Atomically Precise Nanoclusters by Ligand-Exchange

Xi Kang et al.

CHEMISTRY OF MATERIALS (2019)

Review Chemistry, Multidisciplinary

Atomically Tailored Gold Nanoclusters for Catalytic Application

Tatsuya Higaki et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

Review Chemistry, Multidisciplinary

Toward Total Synthesis of Thiolate-Protected Metal Nanoclusters

Qiaofeng Yao et al.

ACCOUNTS OF CHEMICAL RESEARCH (2018)

Article Engineering, Environmental

Selective hydrogenation of the C=C bond in cinnamaldehyde over an ultra-small Pd-Ag alloy catalyst

Rongrong Li et al.

CHEMICAL ENGINEERING JOURNAL (2018)

Review Chemistry, Inorganic & Nuclear

Atomically precise copper nanoclusters and their applications

Xiang Liu et al.

COORDINATION CHEMISTRY REVIEWS (2018)

Review Chemistry, Multidisciplinary

Atomic-Level Doping of Metal Clusters

Atanu Ghosh et al.

ACCOUNTS OF CHEMICAL RESEARCH (2018)

Article Chemistry, Physical

Control of interfacial acid-metal catalysis with organic monolayers

Jing Zhang et al.

NATURE CATALYSIS (2018)

Article Chemistry, Multidisciplinary

Doping-Induced Anisotropic Self-Assembly of Silver Icosahedra in [Pt2Ag23Cl7(PPh3)10] Nanoclusters

Megalamane S. Bootharaju et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2017)

Article Multidisciplinary Sciences

Interfacial charge distributions in carbon-supported palladium catalysts

Radhika G. Rao et al.

NATURE COMMUNICATIONS (2017)

Review Chemistry, Multidisciplinary

Atomically Precise Clusters of Noble Metals: Emerging Link between Atoms and Nanoparticles

Indranath Chakraborty et al.

CHEMICAL REVIEWS (2017)

Review Chemistry, Multidisciplinary

Atomically Precise Colloidal Metal Nanoclusters and Nanoparticles: Fundamentals and Opportunities

Rongchao Jin et al.

CHEMICAL REVIEWS (2016)

Review Chemistry, Multidisciplinary

Reactivity of Metal Clusters

Zhixun Luo et al.

CHEMICAL REVIEWS (2016)

Article Chemistry, Physical

Reversible Size Control of Silver Nanoclusters via Ligand-Exchange

Megalamane Siddaramappa Bootharaju et al.

CHEMISTRY OF MATERIALS (2015)

Article Chemistry, Physical

Confinement of Metal Nanoparticles in Carbon Nanotubes

T. Trang Nguyen et al.

CHEMCATCHEM (2013)

Article Chemistry, Multidisciplinary

An Efficient Strategy to Drive Nanoparticles into Carbon Nanotubes and the Remarkable Effect of Confinement on Their Catalytic Performance

Eva Castillejos et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2009)

Article Chemistry, Inorganic & Nuclear

Trinuclear Triangular Copper(II) Clusters - Synthesis, Electrochemical Studies and Catalytic Peroxidative Oxidation of Cycloalkanes

Corrado Di Nicola et al.

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY (2009)