Journal
CHEMICAL COMMUNICATIONS
Volume 59, Issue 58, Pages 9001-9004Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d3cc02644b
Keywords
-
Categories
Ask authors/readers for more resources
This study describes the first example of a binary cocrystal comprised of SnPh3Cl and PPh3, in which the components are organized via short and directional tetrel bonds (TtB) between tin and phosphorus. DFT elucidates, for the first time, the factors influencing the strength of TtBs involving heavy pnictogens. A CSD survey reveals that such TtBs are also present and determinative in single component molecular systems, highlighting their significant potential as tuneable structure-directing elements.
The first example of a binary cocrystal, comprised of SnPh3Cl and PPh3, whose components are organized via short and directional tetrel bonds (TtB) between tin and phosphorus, is described. DFT elucidates, for the first time, the factors influencing the strength of TtBs involving heavy pnictogens. A CSD survey reveals that such TtBs are also present and determinative in single component molecular systems, highlighting their significant potential as tuneable structure-directing elements.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available