Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 21, Issue 21, Pages 4504-4517Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d3ob00407d
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Dibenzo[a,j] acridines and regioisomeric dibenzo[c,h]acridines were synthesized from 2,3,5,6-tetrachloropyridine using site-selective cross-coupling and alkyne-carbonyl metathesis reactions. The two regioisomeric series were obtained by changing the order of Sonogashira and Suzuki-Miyaura reactions. The optical and electronic properties of the products were studied using spectroscopy and DFT calculations.
Dibenzo[a,j]acridines and regioisomeric dibenzo[c,h]acridines were synthesized from a common starting material, 2,3,5,6-tetrachloropyridine, by combination of site-selective cross-coupling reaction followed by ring-closing alkyne-carbonyl metathesis using simple Bronsted acids. The two regioisomeric series were accessed by change of the order of Sonogashira and Suzuki-Miyaura reactions. The optical properties of the products were studied by steady-state absorption spectroscopy and time-resolved emission measurements. The electronic properties of the products were further elucidated by DFT calculations.
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