☆ 4.8 Review

Insights into the solvation chemistry in liquid electrolytes for lithium-based rechargeable batteries

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Catalytic Oxidation of K2S via Atomic Co and Pyridinic N Synergy in Potassium-Sulfur Batteries

Chao Ye et al.

Summary: This study reports the catalytic oxidation of K2S on a sulfur host with Co single atoms immobilized on nitrogen-doped carbon. The potassium-sulfur battery exhibited high capacities under high current densities, providing atomic-scale insights for the rational design of highly efficient sulfur hosts.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

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Article Chemistry, Multidisciplinary

Steric Effect Tuned Ion Solvation Enabling Stable Cycling of High-Voltage Lithium Metal Battery

Yuelang Chen et al.

Summary: The study introduces a molecular design principle that utilizes steric hindrance effect to improve the electrochemical stability of lithium electrolytes through tuning the solvation structures of lithium ions. Experimental and computational evidence show that this design leads to enhanced cyclic performance and stability of lithium metal batteries under high-voltage conditions.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

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Article Chemistry, Multidisciplinary

Bioselective Synthesis of a Porous Carbon Collector for High-Performance Sodium-Metal Anodes

Ping Wang et al.

Summary: In the process of preparing carbon materials using natural wood structures, it was found that cellulose contributes to the formation of graphitic structure during pyrolysis, thus enhancing charge transfer and the stability of electrode reactions.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

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Article Multidisciplinary Sciences

Effects of fluorinated solvents on electrolyte solvation structures and electrode/electrolyte interphases for lithium metal batteries

Xia Cao et al.

Summary: The formulation and structure of electrolytes play a critical role in the performance of high-voltage Li metal batteries, with localized high-concentration electrolytes outperforming carbonate electrolytes in various aspects due to their unique solvation structures.

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA (2021)

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Article Chemistry, Physical

Understanding the Outstanding High-Voltage Performance of NCM523||Graphite Lithium Ion Cells after Elimination of Ethylene Carbonate Solvent from Conventional Electrolyte

Sven Klein et al.

Summary: Increasing the specific energy of lithium ion batteries by raising the cell voltage can lead to rapid capacity fade, which can be prevented by removing ethylene carbonate from the electrolyte. This change in electrolyte composition results in a decrease in transition metal deposits and lithium dendrites, ultimately ensuring a rollover-free performance at high voltage conditions.

ADVANCED ENERGY MATERIALS (2021)

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Review Chemistry, Physical

A Growing Appreciation for the Role of LiF in the Solid Electrolyte Interphase

Jian Tan et al.

Summary: Rechargeable lithium batteries have transformed energy storage technology, but their further commercialization is hindered by short lifetime and safety issues, mainly due to the unstable solid-electrolyte interphase (SEI) and uncontrolled lithium dendrite growth. Research on SEI worldwide has focused on its debated structure and composition, particularly the role of the main component LiF. This review covers the development history of the SEI model, fundamental understanding of SEI, categorization of anode materials generating LiF in SEI, characterization techniques of SEI layers, transport mechanism of Li+ ions within SEI, physical properties of LiF, and analysis of LiF sources, offering insights for future research directions to promote large-scale applications of lithium metal batteries.

ADVANCED ENERGY MATERIALS (2021)

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Article Chemistry, Multidisciplinary

High-Efficacy and Polymeric Solid-Electrolyte Interphase for Closely Packed Li Electrodeposition

Siyuan Li et al.

Summary: This study investigates the impact of the oxidation behavior of LiDFOB salt on the formation of solid-electrolyte interphase and Li reversibility through a new high concentration electrolyte system. It was found that a polyether/coordinated borate containing solid-electrolyte interphase with inner Li2O crystalline can be observed with increasing salt concentration, enabling stable cycling of LiNi0.8Co0.1Mn0.1O2/Li cells under high cutoff voltage conditions.

ADVANCED SCIENCE (2021)

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Article Multidisciplinary Sciences

A Mo5N6 electrocatalyst for efficient Na2S electrodeposition in room-temperature sodium-sulfur batteries

Chao Ye et al.

Summary: The Mo5N6 cathode material enables efficient Na2S electrodeposition, improving cycling performance in room-temperature sodium-sulfur batteries.

NATURE COMMUNICATIONS (2021)

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Article Chemistry, Physical

High-Voltage and High-Safety Practical Lithium Batteries with Ethylene Carbonate-Free Electrolyte

Yu Wu et al.

Summary: The article introduces a novel triple-salt ethylene carbonate (EC) free electrolyte for high-safety and high-energy batteries, demonstrating its superior performance in enhancing safety, electrochemical properties, and high voltage stability.

ADVANCED ENERGY MATERIALS (2021)

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Article Energy & Fuels

Tailoring electrolyte solvation for Li metal batteries cycled at ultra-low temperature

John Holoubek et al.

Summary: This study highlights the importance of the solvation structure of the electrolyte in charge-transfer behavior at ultra-low temperatures for lithium metal batteries. By designing an electrolyte to enable low-temperature operations, stable performance and high efficiency can be achieved for Li-metal batteries.

NATURE ENERGY (2021)

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Article Chemistry, Multidisciplinary

Lithium-Ion Desolvation Induced by Nitrate Additives Reveals New Insights into High Performance Lithium Batteries

Wandi Wahyudi et al.

Summary: This study reveals the key role of additives in promoting cation desolvation, further demonstrating the importance of nitrate anions in improving battery performance.

ADVANCED FUNCTIONAL MATERIALS (2021)

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Article Chemistry, Multidisciplinary

Nitrate Additives Coordinated with Crown Ether Stabilize Lithium Metal Anodes in Carbonate Electrolyte

Sichen Gu et al.

Summary: By adding rubidium nitrate additive coordinated with 18-crown-6 crown ether to the carbonate electrolyte, the stability of lithium metal anodes can be improved, leading to higher Coulombic efficiency and better battery performance.

ADVANCED FUNCTIONAL MATERIALS (2021)

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Article Chemistry, Multidisciplinary

Design Parameters for Ionic Liquid-Molecular Solvent Blend Electrolytes to Enable Stable Li Metal Cycling Within Li-O2 Batteries

Alex R. Neale et al.

Summary: Effective utilization of Li-metal electrodes is crucial for enhancing the specific energy of lithium-oxygen batteries. Through optimizing formulations based on solvent, salt, and ionic liquid, stable Li plating/stripping performances and improved performance in Li-O-2 full cells were achieved. Introducing non-volatile IL had negligible disrupting effects on critical stabilizing interactions between Li+ and DMSO.

ADVANCED FUNCTIONAL MATERIALS (2021)

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Article Chemistry, Multidisciplinary

Dual-Solvent Li-Ion Solvation Enables High-Performance Li-Metal Batteries

Hansen Wang et al.

Summary: Novel electrolyte designs, including fluorinated 1,6-dimethoxyhexane and 1,2-dimethoxyethane as solvent molecules, along with lithium bis(fluorosulfonyl)imide, enable high-performance lithium metal batteries with improved stability and ionic conductivity. The use of a dual-solvent system contributes to the anion-derived solid-electrolyte interphase and enhances the overall battery performance.

ADVANCED MATERIALS (2021)

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Article Chemistry, Multidisciplinary

Advanced Low-Flammable Electrolytes for Stable Operation of High-Voltage Lithium-Ion Batteries

Hao Jia et al.

Summary: By optimizing the electrolyte additives and structure, the study achieved excellent electrochemical performance of TMPa-based electrolytes in lithium-ion batteries, demonstrating outstanding cycling stability and energy storage efficiency.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

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Article Chemistry, Physical

Understanding Li-ion thermodynamic and kinetic behaviors in concentrated electrolyte for the development of aqueous lithium-ion batteries

Jiangtao Hu et al.

Summary: This study investigates the thermodynamic and kinetic behaviors of Li-ion in high concentration aqueous electrolytes using LiFePO4 as the active electrode. The research reveals that the formation of polymeric solution structure at high concentrations leads to an increase in Li-ion activity and activity coefficient. Additionally, the slow Li-ion desolvation process is identified as the main contributor to the slower interface kinetics in high concentration electrolytes.

NANO ENERGY (2021)

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Review Chemistry, Multidisciplinary

Chemical Aspects of Human and Environmental Overload with Fluorine

Jianlin Han et al.

Summary: This comprehensive review focuses on the effects of fluoride ions and organofluorine compounds on human health and the environment, as well as related topics including the reasons for the advancement of fluorine-containing pharmaceuticals and agrochemicals, metabolism of fluorinated drugs, withdrawn fluorinated drugs, natural sources of fluorine compounds in the environment, sources of fluoride intake, and biomarkers of fluoride exposure.

CHEMICAL REVIEWS (2021)

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Article Chemistry, Multidisciplinary

Non-Flammable and Highly Concentrated Carbonate Ester-Free Electrolyte Solutions for 5 V-Class Positive Electrodes in Lithium-Ion Batteries

Takayuki Doi et al.

Summary: A non-flammable and highly concentrated electrolyte solution using TFEP as the main solvent was designed to improve the safety and energy density of lithium-ion batteries significantly. By introducing a fluorinated diluent FMP, the decomposition of LiBF4 and TFEP at high potentials was successfully suppressed, leading to enhanced charge and discharge performance of LiNi0.5Mn1.5O4 electrodes.

CHEMSUSCHEM (2021)

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Article Chemistry, Physical

Bayesian learning for rapid prediction of lithium-ion battery-cycling protocols

Benben Jiang et al.

Summary: A new data-driven methodology is demonstrated for rapid and accurate prediction of cycle life in lithium-ion batteries, enabling exploration of cycling protocol design spaces with significant reduction in testing time. By combining lifetime early prediction with a hierarchical Bayesian model, high protocol-lifetime prediction performance is achieved with minimal testing.

JOULE (2021)

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Article Chemistry, Physical

Ethylene Carbonate-Free Propylene Carbonate-Based Electrolytes with Excellent Electrochemical Compatibility for Li-Ion Batteries through Engineering Electrolyte Solvation Structure

Xingwei Liu et al.

Summary: This study introduces a simple and effective strategy to prepare electrochemically compatible PC-based electrolytes, utilizing a weakly coordinating diethyl carbonate co-solvent to enhance the reduction tolerance of PC solvent. By incorporating a film-forming additive, an electrochemically stable PC-based electrolyte that allows reversible Li+ intercalation on the graphite electrode is obtained.

ADVANCED ENERGY MATERIALS (2021)

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Article Chemistry, Physical

Intrinsically Nonflammable Ionic Liquid-Based Localized Highly Concentrated Electrolytes Enable High-Performance Li-Metal Batteries

Zhicheng Wang et al.

Summary: An intrinsically nonflammable ionic liquid-based localized highly concentrated electrolyte (LHCE) has been designed, which significantly improves the performance of Li-metal batteries (LMBs) by enhancing ionic conductivity and suppressing Li dendrite growth. The LHCE exhibits high Coulombic efficiency and stable cycling performance over thousands of cycles, making it suitable for various LMB systems. This electrolyte shows great potential for practical application in high-performance batteries.

ADVANCED ENERGY MATERIALS (2021)

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Article Chemistry, Physical

Cathode-Electrolyte-Interphase Film Formation on a LiNiO2 Surface in Conventional Aqueous Electrolytes: Simple Method to Improve the Electrochemical Performance of LiNiO2 Electrodes for Use in Aqueous Li-Ion Batteries

Changhee Lee et al.

Summary: The study demonstrates for the first time that a cathode-electrolyte interphase (CEI) film can be created on a LiNiO2 (LNO) electrode in conventional aqueous electrolytes, improving electrochemical performance such as reversible capacities and cyclability. The CEI film, mainly composed of Li2CO3 and LiOH, is formed in a saturated LiNO3 aqueous electrolyte containing LiOH, suppressing side reactions between the surface and aqueous electrolyte, and improving the recovery rate of structural changes of LNO during the charge/discharge process. This suggests that LNO has great potential as a cathode material for high energy density aqueous Li-ion batteries (ALIBs).

ADVANCED ENERGY MATERIALS (2021)

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Review Chemistry, Physical

A decade of advanced rechargeable batteries development guided by in situ transmission electron microscopy

Junpeng Xie et al.

Summary: Advanced rechargeable batteries (ARBs) have attracted attention for their green resource, safe operation, and low cost properties. In situ transmission electron microscopy (TEM) provides high temporal and spatial resolutions for real-time observation, revealing the evolution and mechanisms of electrode materials during charge and discharge processes. This advanced technique can help address the main challenges of ARBs and further promote the design of electrode materials.

NANO ENERGY (2021)

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Article Chemistry, Physical

Lithium Metal Batteries Enabled by Synergetic Additives in Commercial Carbonate Electrolytes

Nan Piao et al.

Summary: By introducing lithium nitrate (LiNO3) and fluoroethylene carbonate (FEC) into commercial 1 M LiPF6/EC-DMC electrolytes, an inorganic-enhanced LiF-Li3N SEI was designed to improve the Li plating/stripping Coulombic efficiency to 99.6% in 100 cycles. This strategy enabled a lithium metal anode cell to achieve an average CE of 99.7% and a capacity retention of 90.8% after 150 cycles, demonstrating high performance in commercial carbonate electrolytes.

ACS ENERGY LETTERS (2021)

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Article Chemistry, Physical

Enabling the Low-Temperature Cycling of NMC∥Graphite Pouch Cells with an Ester-Based Electrolyte

Yoon-Gyo Cho et al.

Summary: Utilizing an ester electrolyte based on methyl propionate, LiNixMnyCozO2 parallel graphite full cells demonstrate successful cycling at high rates at extremely low temperatures. This work provides a new avenue for achieving high-performance LIBs capable of ultralow-temperature charging and discharging operations.

ACS ENERGY LETTERS (2021)

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Article Chemistry, Physical

Dissolution-Precipitation Dynamics in Ester Electrolyte for High-Stability Lithium Metal Batteries

Huicong Yang et al.

Summary: The research shows that using ethylene glycol diacetate in ester electrolyte can prevent the recombination of anions and cations, increasing the solubility of LiNO3 and achieving lithium metal batteries with high Coulombic efficiency and long cycling life. Low permittivity solvents can change the solvation structures of cations and increase the solubility of salts by preventing the recombination of anions and cations.

ACS ENERGY LETTERS (2021)

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Article Chemistry, Physical

Tailoring Electrolyte Solvation Chemistry toward an Inorganic-Rich Solid-Electrolyte Interphase at a Li Metal Anode

Xueying Zheng et al.

Summary: The study formulated a nonflammable and highly fluorinated electrolyte recipe for a highly reversible Li metal anode, resulting in significant improvements in Li deposition morphology, Coulombic efficiency, and Li+ desolvation/transfer kinetics. Stable cyclability was achieved in full cells pairing with commercial cathodes under both room-temperature and subzero conditions, showcasing the universality of the design principle provided in the study.

ACS ENERGY LETTERS (2021)

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Article Energy & Fuels

Ultra-high-voltage Ni-rich layered cathodes in practical Li metal batteries enabled by a sulfonamide-based electrolyte

Weijiang Xue et al.

Summary: The authors have developed a sulfonamide-based electrolyte that allows for stable cycling of LiNi0.8Co0.1Mn0.1O2 in lithium metal batteries at a cutoff voltage of 4.7 V, achieving a specific capacity >230 mA h g(-1) and an average Coulombic efficiency >99.65% over 100 cycles. The 4.7 V lithium-metal battery can retain >88% capacity for 90 cycles even under harsh testing conditions, advancing practical lithium-metal batteries.

NATURE ENERGY (2021)

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Review Chemistry, Physical

Stabilizing metal battery anodes through the design of solid electrolyte interphases

Qing Zhao et al.

Summary: The solid electrolyte interphase (SEI) is a chemically distinct material phase formed by a combination of electrochemical reduction and chemical reactions at both the explicit and implicit interfaces in all electrochemical cells. Understanding the structure, chemistry, and thermodynamics of the materials that accumulate in such interfacial material phases plays a crucial role in achieving high levels of anode reversibility in secondary batteries. Strategies focusing on the rational design of the SEI at metal anodes, including taking advantage of redox chemistry of electrolyte components and creating artificial SEI outside the cell, are highlighted in the study.

JOULE (2021)

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Article Chemistry, Multidisciplinary

Electrolyte Design Enabling a High-Safety and High-Performance Si Anode with a Tailored Electrode-Electrolyte Interphase

Zhang Cao et al.

Summary: This study demonstrates the superior cyclability of silicon anodes in lithium-ion batteries using a nonflammable ether-based electrolyte with dual additives. By forming a high-modulus SEI rich in fluoride and boron species, the Si/Li cells achieve a high initial Coulombic efficiency and low capacity-fading rate. Additionally, full cells pairing the unmodified Si anode with commercial cathodes show extended service life, highlighting the potential for developing high-performance Si-based batteries through Si/electrolyte interphase regulation.

ADVANCED MATERIALS (2021)

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Article Chemistry, Multidisciplinary

Stabilizing the Solid-Electrolyte Interphase with Polyacrylamide for High-Voltage Aqueous Lithium-Ion Batteries

Xu Hou et al.

Summary: The polymeric additive polyacrylamide (PAM) stabilizes the solid-electrolyte interphase in water-in-salt electrolyte (WiSE) systems, leading to enhanced cycling stability.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

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Article Chemistry, Multidisciplinary

Stable Anion-Derived Solid Electrolyte Interphase in Lithium Metal Batteries

Tao Li et al.

Summary: By regulating the electrolyte structure of anions using TPFPB anion acceptors, a stable anion-derived SEI was constructed to improve the stability and cycling performance of lithium metal batteries under practical conditions.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

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Article Chemistry, Multidisciplinary

Localized Water-In-Salt Electrolyte for Aqueous Lithium-Ion Batteries

Pauline Jaumaux et al.

Summary: A localized water-in-salt (LWIS) electrolyte based on low-cost lithium nitrate (LiNO3) salt and 1,5-pentanediol (PD) was developed, which improved electrolyte stability and cycling performance for aqueous Li-ion batteries. By in situ gelling the LWIS electrolyte with tetraethylene glycol diacrylate (TEGDA) monomer, the stability window was expanded to 3.0 V, resulting in excellent cycling performance with high Coulombic efficiency.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

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Article Chemistry, Multidisciplinary

Isomeric Organodithiol Additives for Improving Interfacial Chemistry in Rechargeable Li-S Batteries

Jing Lian et al.

Summary: Benzenedithiols have been successfully used as electrolyte additives to limit the shuttle effect of lithium polysulfides in lithium-sulfur batteries, forming a stable solid-electrolyte interphase to enhance battery performance.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

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Article Multidisciplinary Sciences

Carbon-free high-loading silicon anodes enabled by sulfide solid electrolytes

Darren H. S. Tan et al.

Summary: The research successfully achieved stable operation of silicon anodes by using the interface passivating properties of sulfide solid electrolytes. Analysis showed that this approach eliminates continuous interfacial growth and irreversible lithium losses. The promising performance of microsilicon full cells can be attributed to the ideal interface properties between microsilicon and sulfide electrolytes and the unique chemomechanical behavior of the lithium-silicon alloy.

SCIENCE (2021)

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Article Chemistry, Physical

Electrolytes Polymerization-Induced Cathode-Electrolyte-Interphase for High Voltage Lithium-Ion Batteries

Jixiang Yang et al.

Summary: The research shows that adding aluminum isopropoxide to commercial electrolyte can significantly improve the cycling stability of lithium-ion batteries, providing a promising approach to enhance energy density.

ADVANCED ENERGY MATERIALS (2021)

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Article Chemistry, Physical

Ion-Dipole Chemistry Drives Rapid Evolution of Li Ions Solvation Sheath in Low-Temperature Li Batteries

Zhenxing Wang et al.

Summary: The sluggish evolution of lithium ions' solvation sheath can lead to dendrite formation and capacity loss in lithium batteries, especially at low temperatures. However, by using an ion-dipole strategy to regulate the fluorination degree of solvating agents, it is possible to accelerate the evolution of Li+ solvation sheath and improve battery performance. The DFEC-based electrolyte demonstrates significantly faster ion desolvation rate at low temperatures, allowing for better capacity retention in LiNi0.8Co0.1Mn0.1O2||lithium cells after cycling. This work provides a new technique towards rational design of electrolyte engineering for low-temperature lithium batteries.

ADVANCED ENERGY MATERIALS (2021)

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Article Chemistry, Physical

Lithium Borate Ester Salts for Electrolyte Application in Next-Generation High Voltage Lithium Batteries

Binayak Roy et al.

Summary: A new class of Li salts with improved electrochemical performance, including higher oxidative stability and good stability towards aluminum substrates, has been introduced in this study. Testing with high voltage NMC811 and LMO cathodes showed stable cycling performance, with the LMO|Li cell maintaining a low capacity fade rate even after exposure to atmospheric conditions for 24 hours.

ADVANCED ENERGY MATERIALS (2021)

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Review Chemistry, Applied

In-situ/operando characterization techniques in lithium-ion batteries and beyond

Haoyu Li et al.

Summary: In-situ/operando characterization is a powerful means to monitor battery reactions and study energy-storage mechanisms. This review summarizes the progress of techniques employed in rechargeable batteries, highlighting simultaneous strategies of various in-situ methods.

JOURNAL OF ENERGY CHEMISTRY (2021)

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Article Chemistry, Multidisciplinary

Concentrated Electrolytes Widen the Operating Temperature Range of Lithium-Ion Batteries

Jianhui Wang et al.

Summary: The use of concentrated electrolytes can expand the operating temperature range of Lithium-ion batteries, improving their stability. Research shows that concentrated electrolytes can enable stable charge-discharge cycling in a wide temperature range from -20 to 100 degrees Celsius, reducing challenges at high temperatures.

ADVANCED SCIENCE (2021)

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Article Chemistry, Physical

High-Performance Lithium Metal Batteries with a Wide Operating Temperature Range in Carbonate Electrolyte by Manipulating Interfacial Chemistry

Peitao Xiao et al.

Summary: In this study, a new solvent TPPO was introduced to improve the carbonate electrolyte and achieve stable cycling performance of lithium metal batteries. The interaction between TPPO and Li+ can prevent the formation of lithium dendrites and suppress electrolyte decomposition, enabling high stability over a wide temperature range (-15 to 70 degrees Celsius).

ACS ENERGY LETTERS (2021)

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Article Energy & Fuels

Balancing interfacial reactions to achieve long cycle life in high-energy lithium metal batteries

Chaojiang Niu et al.

Summary: The study investigates the degradation mechanisms of Li || LiNi0.6Mn0.2Co0.2O2 pouch cells and shows that an optimal anode to cathode capacity ratio of 1:1 can balance well the rates of Li consumption, electrolyte depletion, and solid-electrolyte interphase construction to extend the cycle life of the cell. Contrary to conventional wisdom, long cycle life is observed with ultra-thin Li in balanced cells. A prototype 350 Wh kg(-1) pouch cell achieves over 600 stable cycles with 76% capacity retention.

NATURE ENERGY (2021)

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Article Chemistry, Physical

Dual-anion ionic liquid electrolyte enables stable Ni-rich cathodes in lithium-metal batteries

Fanglin Wu et al.

Summary: The use of a dual-anion ionic liquid electrolyte enables high electrochemical performance in lithium-metal batteries, with high initial capacity and outstanding cycling stability.

JOULE (2021)

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Article Chemistry, Multidisciplinary

Stabilizing electrode-electrolyte interfaces to realize high-voltage Li||LiCoO2 batteries by a sulfonamide-based electrolyte

Weijiang Xue et al.

Summary: This study demonstrates the improved cycling stability of high-voltage lithium-metal batteries by using a rationally designed sulfonamide-based electrolyte, which stabilizes the electrode-electrolyte interfaces on both the Li-metal anode and high-voltage LCO cathode. Commercial LCO cathodes show significantly better capacity retention after cycling under high charging voltages of 4.55 V-Li and 4.6 V-Li with the sulfonamide-based electrolyte, outperforming traditional carbonate-based electrolytes. This work provides a promising strategy for designing new electrolytes to achieve high-energy Li||LCO batteries.

ENERGY & ENVIRONMENTAL SCIENCE (2021)

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Review Chemistry, Multidisciplinary

From bulk to interface: electrochemical phenomena and mechanism studies in batteries via electrochemical quartz crystal microbalance

Yuchen Ji et al.

Summary: EQCM technology is a powerful tool for understanding the bulk and interfacial behaviors during battery operation, enabling investigation into phenomena such as ion insertion/deinsertion, solid nucleation, and interphase formation. Recent studies have utilized EQCM to reveal phenomena and mechanisms in various batteries, showing promise for future applications in battery research.

CHEMICAL SOCIETY REVIEWS (2021)

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Review Chemistry, Multidisciplinary

High-voltage liquid electrolytes for Li batteries: progress and perspectives

Xiulin Fan et al.

Summary: The energy density of LIBs has been increased threefold since their introduction, but the capacity of transition metal oxide cathodes is approaching its limit due to stability limitations of electrolytes. To further enhance energy density, new high-capacity and high-voltage cathode materials need to be explored, and graphite anodes may need to be replaced. One of the main challenges for future development is the development of new electrolyte compositions that can accommodate high-voltage cathodes and anodes while ensuring the stability of the batteries.

CHEMICAL SOCIETY REVIEWS (2021)

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Review Chemistry, Physical

Aqueous lithium-ion batteries

Arthur von Wald Cresce et al.

Summary: As lithium-ion batteries revolutionized the industry with high energy density, the safety concerns of organic electrolytes prompted a re-examination of aqueous electrolytes. With the concept of aqueous lithium-ion batteries revived in the mid-2010s using highly concentrated electrolytes, efforts have been made to understand interfacial stability and make the system viable for practical batteries.

CARBON ENERGY (2021)

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Article Chemistry, Multidisciplinary

The underlying mechanism for reduction stability of organic electrolytes in lithium secondary batteries

Xiaohui Shen et al.

Summary: This study reveals the origin of reduction stability of organic carbonate electrolytes through a combination of AIMD simulations, DFT calculations, and electrochemical stability experiments. The increase in salt to solvent molar ratio leads to a V-shaped change in the LUMO energy level of coordinated solvent molecules, affecting the interfacial stability.

CHEMICAL SCIENCE (2021)

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Review Chemistry, Multidisciplinary

Insights into the deposition chemistry of Li ions in nonaqueous electrolyte for stable Li anodes

Zhenxing Wang et al.

Summary: Lithium (Li) is considered the best choice for high energy density energy storage systems, but uncontrollable dendrite formation causes safety concerns and poor coulombic efficiency. This review focuses on the factors influencing dendrite evolution, from formation to growth, in order to understand deposition chemistry better. Special attention is given to the effects of various factors on Li+ movement, desolvation, solid electrolyte interphase formation, and diffusion coefficient, with recommendations for reducing side reactions and volume expansion.

CHEMICAL SOCIETY REVIEWS (2021)

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Article Chemistry, Multidisciplinary

Advanced liquid electrolytes enable practical applications of high-voltage lithium-metal full batteries

Shulan Mao et al.

Summary: In this article, the formation mechanism of the electrode-electrolyte interphase in high-voltage lithium metal batteries is reviewed, surface modification methods are summarized, and the relationship between liquid electrolyte formulation, interphase engineering, and electrochemical performance is analyzed. Industry-level evaluation is carried out and remaining challenges are discussed for advanced electrolytes to ensure practical applications and commercialization of HVLMBs.

CHEMICAL COMMUNICATIONS (2021)

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Article Chemistry, Physical

From-20 °C to 150 °C: a lithium secondary battery with a wide temperature window obtained via manipulated competitive decomposition in electrolyte solution

Tianle Zheng et al.

Summary: The use of adiponitrile (ADN) has been shown to improve the performance of lithium secondary batteries (LSBs) over a wide temperature range, offering higher coulombic efficiency at high temperatures and more stable cycling performance.

JOURNAL OF MATERIALS CHEMISTRY A (2021)

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Article Electrochemistry

In Situ ATR-FTIR Study of the Cathode-Electrolyte Interphase: Electrolyte Solution Structure, Transition Metal Redox, and Surface Layer Evolution

Bertrand J. Tremolet de Villers et al.

Summary: This study investigates the changes at the cathode-electrolyte interface of NMC622 during galvanostatic charging and discharging, focusing on the solvation of lithium ions near the surface and the correlation between cathode metal-oxygen vibrational absorptions and TM redox behaviors. The formation and evolution of a CEI surface layer that contributes to capacity fade in the cell were also detected.

BATTERIES & SUPERCAPS (2021)

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Article Materials Science, Multidisciplinary

Understanding all solid-state lithium batteries through in situ transmission electron microscopy

Yong Cheng et al.

Summary: All solid-state lithium batteries (ASSLBs) are considered to have substantial advantages over conventional liquid electrolyte based lithium ion batteries (LIBs), but the failure mechanisms of ASSLBs are not well understood, requiring particular attention. Recent progress in in situ transmission electron microscopy (TEM) studies of ASSLBs has revealed novel electro-chemo-mechanical coupling phenomena and provided mechanistic insights, demonstrating the general applicability of in situ TEM for elucidating fundamental mechanisms and providing design guidance for the development of high-performance ASSLBs. Challenges and opportunities for in situ TEM studies of ASSLBs are discussed.

MATERIALS TODAY (2021)

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Review Electrochemistry

Review-Localized High-Concentration Electrolytes for Lithium Batteries

Xia Cao et al.

Summary: Conventional LiPF6/carbonate-based electrolytes have been widely used in graphite-based lithium ion batteries for their stability, but are less stable in Li metal and silicon anodes. Localized high-concentration electrolytes have unique advantages, forming stable SEI layers to improve stability.

JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2021)

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Review Chemistry, Multidisciplinary

Electrolytes for Rechargeable Lithium-Air Batteries

Jingning Lai et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

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Review Chemistry, Applied

Recent progress in fluorinated electrolytes for improving the performance of Li-S batteries

Xiwen Wang et al.

JOURNAL OF ENERGY CHEMISTRY (2020)

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Article Chemistry, Physical

Improving Electrochemical Stability and Low-Temperature Performance with Water/Acetonitrile Hybrid Electrolytes

Jiawei Chen et al.

ADVANCED ENERGY MATERIALS (2020)

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Article Chemistry, Physical

Graphite-Lithium Sulfide Battery with a Single-Phase Sparingly Solvating Electrolyte

Taisho Seita et al.

ACS ENERGY LETTERS (2020)

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Article Nanoscience & Nanotechnology

Cycling Performance and Kinetic Mechanism Analysis of a Li Metal Anode in Series-Concentrated Ether Electrolytes

Simin Wang et al.

ACS APPLIED MATERIALS & INTERFACES (2020)

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Article Chemistry, Multidisciplinary

Enabling High-Voltage Lithium Metal Batteries by Manipulating Solvation Structure in Ester Electrolyte

Yulin Jie et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

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Review Chemistry, Multidisciplinary

Lithium-Oxygen Batteries and Related Systems: Potential, Status, and Future

Won-Jin Kwak et al.

CHEMICAL REVIEWS (2020)

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Review Chemistry, Multidisciplinary

Current Challenges and Routes Forward for Nonaqueous Lithium-Air Batteries

Tao Liu et al.

CHEMICAL REVIEWS (2020)

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Article Multidisciplinary Sciences

Closed-loop optimization of fast-charging protocols for batteries with machine learning

Peter M. Attia et al.

NATURE (2020)

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Article Multidisciplinary Sciences

Visualizing H2O molecules reacting at TiO2 active sites with transmission electron microscopy

Wentao Yuan et al.

SCIENCE (2020)

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Article Chemistry, Physical

Countersolvent Electrolytes for Lithium-Metal Batteries

Nan Piao et al.

ADVANCED ENERGY MATERIALS (2020)

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An Anion-Tuned Solid Electrolyte Interphase with Fast Ion Transfer Kinetics for Stable Lithium Anodes

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Fundamentals and Challenges of Lithium Ion Batteries at Temperatures between-40 and 60 °C

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Understanding Transformations in Battery Materials Using in Situ and Operando Experiments: Progress and Outlook

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Advanced Electrolytes for Fast-Charging High-Voltage Lithium-Ion Batteries in Wide-Temperature Range

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Unraveling the Dual Functionality of High-Donor-Number Anion in Lean-Electrolyte Lithium-Sulfur Batteries

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Methylsulfonylmethane-Based Deep Eutectic Solvent as a New Type of Green Electrolyte for a High-Energy-Density Aqueous Lithium-Ion Battery

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Graphite-based lithium ion battery with ultrafast charging and discharging and excellent low temperature performance

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NATURE ENERGY (2019)

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Electrolyte Chemistry Enables Simultaneous Stabilization of Potassium Metal and Alloying Anode for Potassium-Ion Batteries

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Highly Solvating Electrolytes for Lithium-Sulfur Batteries

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A Concentrated Ternary-Salts Electrolyte for High Reversible Li Metal Battery with Slight Excess Li

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Stable Li Metal Anode with Ion-Solvent-Coordinated Nonflammable Electrolyte for Safe Li Metal Batteries

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Regulating Anions in the Solvation Sheath of Lithium Ions for Stable Lithium Metal Batteries

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Extending the low temperature operational limit of Li-ion battery to -80 °C

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Recent Progress of Rechargeable Batteries Using Mild Aqueous Electrolytes

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Critical Parameters for Evaluating Coin Cells and Pouch Cells of Rechargeable Li-Metal Batteries

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Enabling High-Voltage Lithium-Metal Batteries under Practical Conditions

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In situ optical spectroscopy characterization for optimal design of lithium-sulfur batteries

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Accurate Determination of Coulombic Efficiency for Lithium Metal Anodes and Lithium Metal Batteries

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Concentrated mixed cation acetate water-in-salt solutions as green and low-cost high voltage electrolytes for aqueous batteries

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Phase Diagram, Conductivity, and Glass Transition of LiTFSI-H2O Binary Electrolytes

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Factors Limiting Li+ Charge Transfer Kinetics in Li-Ion Batteries

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JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2018)

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Enhanced Electrochemical Performance of High-Energy Lithium-Sulfur Batteries Using an Electrolyte with 1,1,2,2-Tetrafluoro-3-(1,1,2,2-tetrafluoroethoxy)propane

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A carbonate-free, sulfone-based electrolyte for high-voltage Li-ion batteries

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MATERIALS TODAY (2018)

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Non-flammable electrolyte enables Li-metal batteries with aggressive cathode chemistries

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Fluorine-donating electrolytes enable highly reversible 5-V-class Li metal batteries

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PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA (2018)

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Designable ultra-smooth ultra-thin solid-electrolyte interphases of three alkali metal anodes

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High-Energy Aqueous Lithium Batteries

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The development in aqueous lithium-ion batteries

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Enhancing metallic lithium battery performance by tuning the electrolyte solution structure

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Rational design of three-dimensional graphene encapsulated core-shell FeS@carbon nanocomposite as a flexible high-performance anode for sodium-ion batteries

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Manipulating electrolyte and solid electrolyte interphase to enable safe and efficient Li-S batteries

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NANO ENERGY (2018)

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New Insights on Graphite Anode Stability in Rechargeable Batteries: Li Ion Coordination Structures Prevail over Solid Electrolyte Interphases

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Stable cycling of high-voltage lithium metal batteries in ether electrolytes

Shuhong Jiao et al.

NATURE ENERGY (2018)

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Non-flammable electrolytes with high salt-to-solvent ratios for Li-ion and Li-metal batteries

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NATURE ENERGY (2018)

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Highly Fluorinated Interphases Enable High-Voltage Li-Metal Batteries

Xiulin Fan et al.

CHEM (2018)

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Cathodically Stable Li-O-2 Battery Operations Using Water-in-Salt Electrolyte

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CHEM (2018)

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Visualizing Battery Reactions and Processes by Using In Situ and In Operando Microscopies

Yutong Wu et al.

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Localized High-Concentration Sulfone Electrolytes for High-Efficiency Lithium-Metal Batteries

Xiaodi Ren et al.

CHEM (2018)

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Unexpected Effect of Electrode Architecture on High-Performance Lithium-Sulfur Batteries

Peitao Xiao et al.

ACS APPLIED MATERIALS & INTERFACES (2018)

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An Armored Mixed Conductor Interphase on a Dendrite-Free Lithium-Metal Anode

Chong Yan et al.

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The Relationship between the Relative Solvating Power of Electrolytes and Shuttling Effect of Lithium Polysulfides in Lithium-Sulfur Batteries

Chi-Cheung Su et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2018)

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Synthesis and electrochemical properties of partially fluorinated ether solvents for lithium-sulfur battery electrolytes

Zheng Yue et al.

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Planning chemical syntheses with deep neural networks and symbolic AI

Marwin H. S. Segler et al.

NATURE (2018)

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A high-energy-density lithium-oxygen battery based on a reversible four-electron conversion to lithium oxide

C. Xia et al.

SCIENCE (2018)

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A Localized High-Concentration Electrolyte with Optimized Solvents and Lithium Difluoro(oxalate)borate Additive for Stable Lithium Metal Batteries

Lu Yu et al.

ACS ENERGY LETTERS (2018)

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Tuning the electrolyte network structure to invoke quasi-solid state sulfur conversion and suppress lithium dendrite formation in Li-S batteries

Quan Pang et al.

NATURE ENERGY (2018)

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The Radical Pathway Based on a Lithium-Metal-Compatible High-Dielectric Electrolyte for Lithium-Sulfur Batteries

Ge Zhang et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2018)

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Nanometric Water Channels in Water-in-Salt Lithium Ion Battery Electrolyte

Joonhyung Lim et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2018)

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Understanding Thermodynamic and Kinetic Contributions in Expanding the Stability Window of Aqueous Electrolytes

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CHEM (2018)

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Fluorinated solid electrolyte interphase enables highly reversible solid-state Li metal battery

Xiulin Fan et al.

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High-Efficiency Lithium Metal Batteries with Fire-Retardant Electrolytes

Shuru Chen et al.

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High Conductivity Solvates with Unsymmetrical Glymes as New Electrolytes

Devaraj Shanmukaraj et al.

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Low-Polarization Lithium-Oxygen Battery Using [DEME][TFSI] Ionic Liquid Electrolyte

Ulderico Ulissi et al.

CHEMSUSCHEM (2018)

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Hybrid Aqueous/Non-aqueous Electrolyte for Safe and High-Energy Li-Ion Batteries

Fei Wang et al.

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The role of the hydrogen evolution reaction in the solid-electrolyte interphase formation mechanism for Water-in-Salt electrolytes

Nicolas Dubouis et al.

ENERGY & ENVIRONMENTAL SCIENCE (2018)

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Ammonium Additives to Dissolve Lithium Sulfide through Hydrogen Binding for High-Energy Lithium-Sulfur Batteries

Huilin Pan et al.

ACS APPLIED MATERIALS & INTERFACES (2017)

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Spinel LiNi0.5Mn1.5O4 Cathode for High-Energy Aqueous Lithium-Ion Batteries

Fei Wang et al.

ADVANCED ENERGY MATERIALS (2017)

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Role of Li Concentration and the SEI Layer in Enabling High Performance Li Metal Electrodes Using a Phosphonium Bis(fluorosulfonyl)imide Ionic Liquid

Gaetan M. A. Girard et al.

JOURNAL OF PHYSICAL CHEMISTRY C (2017)

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Ramifications of Water-in-Salt Interfacial Structure at Charged Electrodes for Electrolyte Electrochemical Stability

Jenel Vatamanu et al.

JOURNAL OF PHYSICAL CHEMISTRY LETTERS (2017)

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2,4-Dimethoxy-2,4-dimethylpentan-3-one: An Aprotic Solvent Designed for Stability in Li-O2 Cells

Daniel Sharon et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2017)

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How Solid-Electrolyte Interphase Forms in Aqueous Electrolytes

Liumin Suo et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2017)

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Fluorinated Carbonate-Based Electrolyte for High-Voltage Li(Ni0.5Mn0.3Co0.2)O2/Graphite Lithium-Ion Battery

Jinsol Im et al.

JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2017)

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Review-SEI: Past, Present and Future

E. Peled et al.

JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2017)

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Dilution of Highly Concentrated LiBF4/Propylene Carbonate Electrolyte Solution with Fluoroalkyl Ethers for 5-V LiNi0.5Mn1.5O4 Positive Electrodes

Takayuki Doi et al.

JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2017)

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Revealing the reaction mechanisms of Li-O2 batteries using environmental transmission electron microscopy

Langli Luo et al.

NATURE NANOTECHNOLOGY (2017)

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Unique aqueous Li-ion/sulfur chemistry with high energy density and reversibility

Chongyin Yang et al.

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA (2017)

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Atomic structure of sensitive battery materials and Interfaces revealed by cryo-electron microscopy

Yuzhang Li et al.

SCIENCE (2017)

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Liquefied gas electrolytes for electrochemical energy storage devices

Cyrus S. Rustomji et al.

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High Voltage LiNi0.5Mn0.3Co0.2O2/Graphite Cell Cycled at 4.6 V with a FEC/HFDEC-Based Electrolyte

Meinan He et al.

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Stabilization of Li Metal Anode in DMSO-Based Electrolytes via Optimization of Salt-Solvent Coordination for Li-O2 Batteries

Bin Liu et al.

ADVANCED ENERGY MATERIALS (2017)

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Review on High-Loading and High-Energy Lithium-Sulfur Batteries

Hong-Jie Peng et al.

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Non-encapsulation approach for high-performance Li-S batteries through controlled nucleation and growth

Huilin Pan et al.

NATURE ENERGY (2017)

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A rechargeable lithium-oxygen battery with dual mediators stabilizing the carbon cathode

Xiangwen Gao et al.

NATURE ENERGY (2017)

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Li+-Desolvation Dictating Lithium-Ion Battery's Low-Temperature Performances

Qiuyan Li et al.

ACS APPLIED MATERIALS & INTERFACES (2017)

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Fluorinated Ether Based Electrolyte for High-Energy Lithium-Sulfur Batteries: Li+ Solvation Role Behind Reduced Polysulfide Solubility

Sara Drvaric Talian et al.

CHEMISTRY OF MATERIALS (2017)

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More Reliable Lithium-Sulfur Batteries: Status, Solutions and Prospects

Ruopian Fang et al.

ADVANCED MATERIALS (2017)

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Effect of the Hydrofluoroether Cosolvent Structure in Acetonitrile-Based Solvate Electrolytes on the Li+ Solvation Structure and Li-S Battery Performance

Minjeong Shin et al.

ACS APPLIED MATERIALS & INTERFACES (2017)

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Liquid Structure with Nano-Heterogeneity Promotes Cationic Transport in Concentrated Electrolytes

Oleg Borodin et al.

ACS NANO (2017)

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4.0 V Aqueous Li-Ion Batteries

Chongyin Yang et al.

JOULE (2017)

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A High-Performance Li-O2 Battery with a Strongly Solvating Hexamethylphosphoramide Electrolyte and a LiPON-Protected Lithium Anode

Bin Zhou et al.

ADVANCED MATERIALS (2017)

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Toward Safe Lithium Metal Anode in Rechargeable Batteries: A Review

Xin-Bing Cheng et al.

CHEMICAL REVIEWS (2017)

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Enhancing the High-Voltage Cycling Performance of LiNi1/3Co1/3Mn1/3O2/Graphite Batteries Using Alkyl 3,3,3-Trifluoropropanoate as an Electrolyte Additive

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ACS APPLIED MATERIALS & INTERFACES (2017)

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Application of Ionic Liquids to Energy Storage and Conversion Materials and Devices

Masayoshi Watanabe et al.

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Inhibiting Polysulfide Shuttle in Lithium-Sulfur Batteries through Low-Ion-Pairing Salts and a Triflamide Solvent

Abhinandan Shyamsunder et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2017)

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The importance of solvent selection in Li-O2 cells

Daniel Sharon et al.

CHEMICAL COMMUNICATIONS (2017)

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Liquid-Phase Electrochemical Scanning Electron Microscopy for In Situ Investigation of Lithium Dendrite Growth and Dissolution

Genlan Rong et al.

ADVANCED MATERIALS (2017)

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Enhanced Cycling Stability of Rechargeable Li-O2 Batteries Using High-Concentration Electrolytes

Bin Liu et al.

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Li+ Solvation and Ionic Transport in Lithium Solvate Ionic Liquids Diluted by Molecular Solvents

Kazuhide Ueno et al.

JOURNAL OF PHYSICAL CHEMISTRY C (2016)

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Effect of Hydrofluoroether Cosolvent Addition on Li Solvation in Acetonitrile-Based Solvate Electrolytes and Its Influence on S Reduction in a Li-S Battery

Kimberly A. See et al.

ACS APPLIED MATERIALS & INTERFACES (2016)

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Liquid K-Na Alloy Anode Enables Dendrite-Free Potassium Batteries

Leigang Xue et al.

ADVANCED MATERIALS (2016)

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Advanced High-Voltage Aqueous Lithium-Ion Battery Enabled by Water-in-Bisalt Electrolyte

Liumin Suo et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2016)

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Superior rate capability of a sulfur composite cathode in a tris(trimethylsilyl)borate-containing functional electrolyte

Lina Wang et al.

CHEMICAL COMMUNICATIONS (2016)

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Understanding surface reactivity of Si electrodes in Li-ion batteries by in operando scanning electrochemical microscopy

E. Ventosa et al.

CHEMICAL COMMUNICATIONS (2016)

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Stabilizing high voltage LiCoO2 cathode in aqueous electrolyte with interphase-forming additive

Fei Wang et al.

ENERGY & ENVIRONMENTAL SCIENCE (2016)

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Solvent-Dictated Lithium Sulfur Redox Reactions: An Operando UV-vis Spectroscopic Study

Qingli Zou et al.

JOURNAL OF PHYSICAL CHEMISTRY LETTERS (2016)

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A Molten Salt Lithium-Oxygen Battery

Vincent Giordani et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2016)

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Critical Role of Redox Mediator in Suppressing Charging Instabilities of Lithium-Oxygen Batteries

Zhuojian Liang et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2016)

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Promoting solution phase discharge in Li-O2 batteries containing weakly solvating electrolyte solutions

Xiangwen Gao et al.

NATURE MATERIALS (2016)

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A stable room-temperature sodium-sulfur battery

Shuya Wei et al.

NATURE COMMUNICATIONS (2016)

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Superconcentrated electrolytes for a high-voltage lithium-ion battery

Jianhui Wang et al.

NATURE COMMUNICATIONS (2016)

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Restricting the Solubility of Polysulfides in Li-S Batteries Via Electrolyte Salt Selection

Junzheng Chen et al.

ADVANCED ENERGY MATERIALS (2016)

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From Lithium-Oxygen to Lithium-Air Batteries: Challenges and Opportunities

Dongsheng Geng et al.

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Hydrate-melt electrolytes for high-energy-density aqueous batteries

Yuki Yamada et al.

NATURE ENERGY (2016)

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Design principles for electrolytes and interfaces for stable lithium-metal batteries

Mukul D. Tikekar et al.

NATURE ENERGY (2016)

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Promise and reality of post-lithium-ion batteries with high energy densities

Jang Wook Choi et al.

NATURE REVIEWS MATERIALS (2016)

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Li2S5-based ternary-salt electrolyte for robust lithium metal anode

Chen-Zi Zhao et al.

ENERGY STORAGE MATERIALS (2016)

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A new method to prevent degradation of lithium-oxygen batteries: reduction of superoxide by viologen

L. Yang et al.

CHEMICAL COMMUNICATIONS (2015)

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The use of ethyl acetate as a sole solvent in highly concentrated electrolyte for Li-ion batteries

R. Petibon et al.

ELECTROCHIMICA ACTA (2015)

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Soluble TTF catalyst for the oxidation of cathode products in Li-Oxygen battery: A chemical scavenger

Walter R. Torres et al.

ELECTROCHIMICA ACTA (2015)

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Solvent Activity in Electrolyte Solutions Controls Electrochemical Reactions in Li-Ion and Li-Sulfur Batteries

Heejoon Moon et al.

JOURNAL OF PHYSICAL CHEMISTRY C (2015)

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Trade-Offs in Capacity and Rechargeability in Nonaqueous Li-O2 Batteries: Solution-Driven Growth versus Nucleophilic Stability

Abhishek Khetan et al.

JOURNAL OF PHYSICAL CHEMISTRY LETTERS (2015)

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Kinetic investigation of catalytic disproportionation of superoxide ions in the non-aqueous electrolyte used in Li-air batteries

Qiang Wang et al.

JOURNAL OF POWER SOURCES (2015)

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Solvation effect on intercalation behaviour of tetrafluoroborate into graphite electrode

Jichao Gao et al.

JOURNAL OF POWER SOURCES (2015)

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Enhancing electrochemical intermediate solvation through electrolyte anion selection to increase nonaqueous Li-O2 battery capacity

Colin M. Burke et al.

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA (2015)

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Water-in-salt electrolyte enables high-voltage aqueous lithium-ion chemistries

Liumin Suo et al.

SCIENCE (2015)

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Cycling Li-O2 batteries via LiOH formation and decomposition

Tao Liu et al.

SCIENCE (2015)

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High rate and stable cycling of lithium metal anode

Jiangfeng Qian et al.

NATURE COMMUNICATIONS (2015)

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Radical or Not Radical: Revisiting Lithium-Sulfur Electrochemistry in Nonaqueous Electrolytes

Marine Cuisinier et al.

ADVANCED ENERGY MATERIALS (2015)

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On the Way Toward Understanding Solution Chemistry of Lithium Polysulfides for High Energy Li-S Redox Flow Batteries

Huilin Pan et al.

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Understanding the behavior of Li-oxygen cells containing LiI

Won-Jin Kwak et al.

JOURNAL OF MATERIALS CHEMISTRY A (2015)

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Advances in sealed liquid cells for in-situ TEM electrochemial investigation of lithium-ion battery

Fan Wu et al.

NANO ENERGY (2015)

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A Highly Active Low Voltage Redox Mediator for Enhanced Rechargeability of Lithium-Oxygen Batteries

Dipan Kundu et al.

ACS CENTRAL SCIENCE (2015)

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Solvating additives drive solution-mediated electrochemistry and enhance toroid growth in non-aqueous Li-O2 batteries

Nagaphani B. Aetukuri et al.

NATURE CHEMISTRY (2015)

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Towards a Stable Organic Electrolyte for the Lithium Oxygen Battery

Brian D. Adams et al.

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General Observation of Lithium Intercalation into Graphite in Ethylene-Carbonate-Free Superconcentrated Electrolytes

Yuki Yamada et al.

ACS APPLIED MATERIALS & INTERFACES (2014)

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Bis(2,2,2-trifluoroethyl) Ether As an Electrolyte Co-solvent for Mitigating Self-Discharge in Lithium-Sulfur Batteries

Mikhail L. Gordin et al.

ACS APPLIED MATERIALS & INTERFACES (2014)

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Superior Rechargeability and Efficiency of Lithium-Oxygen Batteries: Hierarchical Air Electrode Architecture Combined with a Soluble Catalyst

Hee-Dae Lim et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2014)

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Spatiotemporal Changes of the Solid Electrolyte Interphase in Lithium-Ion Batteries Detected by Scanning Electrochemical Microscopy

Heinz Buelter et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2014)

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Aqueous Rechargeable Li and Na Ion Batteries

Haegyeom Kim et al.

CHEMICAL REVIEWS (2014)

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Electrolytes and Interphases in Li-Ion Batteries and Beyond

Kang Xu

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Unique behaviour of nonsolvents for polysulphides in lithium-sulphur batteries

M. Cuisinier et al.

ENERGY & ENVIRONMENTAL SCIENCE (2014)

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Concentrated electrolytes: decrypting electrolyte properties and reassessing Al corrosion mechanisms

Dennis W. McOwen et al.

ENERGY & ENVIRONMENTAL SCIENCE (2014)

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Lithium-sulfur batteries-the solution is in the electrolyte, but is the electrolyte a solution?

Marzieh Barghamadi et al.

ENERGY & ENVIRONMENTAL SCIENCE (2014)

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Probing the Lithium-Sulfur Redox Reactions: A Rotating-Ring Disk Electrode Study

Yi-Chun Lu et al.

JOURNAL OF PHYSICAL CHEMISTRY C (2014)

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Efficient Li2O2 Formation via Aprotic Oxygen Reduction Reaction Mediated by Quinone Derivatives

Shoichi Matsuda et al.

JOURNAL OF PHYSICAL CHEMISTRY C (2014)

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Unusual Stability of Acetonitrile-Based Superconcentrated Electrolytes for Fast-Charging Lithium-Ion Batteries

Yuki Yamada et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2014)

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A Solution-Phase Bifunctional Catalyst for Lithium-Oxygen Batteries

Dan Sun et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2014)

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TEMPO: A Mobile Catalyst for Rechargeable Li-O2 Batteries

Benjamin J. Bergner et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2014)

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Stability of a Pyrrolidinium-Based Ionic Liquid in Li-O2 Cells

Michele Piana et al.

JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2014)

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The role of LiO2 solubility in O2 reduction in aprotic solvents and its consequences for Li-O2 batteries

Lee Johnson et al.

NATURE CHEMISTRY (2014)

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A New Look at the Stability of Dimethyl Sulfoxide and Acetonitrile in Li-O2 Batteries

Reza Younesi et al.

ECS ELECTROCHEMISTRY LETTERS (2014)

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Increased Cycling Efficiency of Lithium Anodes in Dimethyl Sulfoxide Electrolytes For Use in Li-O2 Batteries

Matthew Roberts et al.

ECS ELECTROCHEMISTRY LETTERS (2014)

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Novel approach for a high-energy-density Li-air battery: tri-dimensional growth of Li2O2 crystals tailored by electrolyte Li+ ion concentrations

Yang Liu et al.

JOURNAL OF MATERIALS CHEMISTRY A (2014)

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Making Li-Air Batteries Rechargeable: Material Challenges

Yuyan Shao et al.

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Ultrasound Assisted Design of Sulfur/Carbon Cathodes with Partially Fluorinated Ether Electrolytes for Highly Efficient Li/S Batteries

Wei Weng et al.

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Sulfur-Infiltrated Micro- and Mesoporous Silicon Carbide-Derived Carbon Cathode for High-Performance Lithium Sulfur Batteries

Jung Tae Lee et al.

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A superconcentrated ether electrolyte for fast-charging Li-ion batteries

Yuki Yamada et al.

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Polysulfide dissolution control: the common ion effect

Eon Sung Shin et al.

CHEMICAL COMMUNICATIONS (2013)

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A redox shuttle to facilitate oxygen reduction in the lithium air battery

Matthew J. Lacey et al.

ELECTROCHEMISTRY COMMUNICATIONS (2013)

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Improved performance of lithium-sulfur battery with fluorinated electrolyte

Nasim Azimi et al.

ELECTROCHEMISTRY COMMUNICATIONS (2013)

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Investigation of Fluorinated Amides for Solid-Electrolyte Interphase Stabilization in Li-O2 Batteries Using Amide-Based Electrolytes

Vyacheslav S. Bryantsev et al.

JOURNAL OF PHYSICAL CHEMISTRY C (2013)

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Solvent Effect of Room Temperature Ionic Liquids on Electrochemical Reactions in Lithium-Sulfur Batteries

Jun-Woo Park et al.

JOURNAL OF PHYSICAL CHEMISTRY C (2013)

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Ionic Liquid Electrolytes for Lithium-Sulfur Batteries

Jun-Woo Park et al.

JOURNAL OF PHYSICAL CHEMISTRY C (2013)

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Anionic Effects on Solvate Ionic Liquid Electrolytes in Rechargeable Lithium-Sulfur Batteries

Kazuhide Ueno et al.

JOURNAL OF PHYSICAL CHEMISTRY C (2013)

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Sulfur Speciation in Li-S Batteries Determined by Operando X-ray Absorption Spectroscopy

Marine Cuisinier et al.

JOURNAL OF PHYSICAL CHEMISTRY LETTERS (2013)

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Suppression of aluminum corrosion by using high concentration LiTFSI electrolyte

Kazuaki Matsumoto et al.

JOURNAL OF POWER SOURCES (2013)

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Liquid electrolyte lithium/sulfur battery: Fundamental chemistry, problems, and solutions

Sheng S. Zhang

JOURNAL OF POWER SOURCES (2013)

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A Rechargeable Li-O2 Battery Using a Lithium Nitrate/N,N-Dimethylacetamide Electrolyte

Wesley Walker et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2013)

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Studies of Li-Air Cells Utilizing Dimethyl Sulfoxide-Based Electrolyte

Matthew J. Trahan et al.

JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2013)

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The Identification of Stable Solvents for Nonaqueous Rechargeable Li-Air Batteries

Vyacheslav S. Bryantsev et al.

JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2013)

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LiTFSI Stability in Water and Its Possible Use in Aqueous Lithium-Ion Batteries: pH Dependency, Electrochemical Window and Temperature Stability

S. F. Lux et al.

JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2013)

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Solvate Ionic Liquid Electrolyte for Li-S Batteries

Kaoru Dokko et al.

JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2013)

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Charging a Li-O2 battery using a redox mediator

Yuhui Chen et al.

NATURE CHEMISTRY (2013)

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A new class of Solvent-in-Salt electrolyte for high-energy rechargeable metallic lithium batteries

Liumin Suo et al.

NATURE COMMUNICATIONS (2013)

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Enhanced Cycling Performance of Li-O2 Batteries by the Optimized Electrolyte Concentration of LiTFSA in Glymes

Fujun Li et al.

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Lithium/Sulfur Cell Discharge Mechanism: An Original Approach for Intermediate Species Identification

Celine Barchasz et al.

ANALYTICAL CHEMISTRY (2012)

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Role of LiNO3 in rechargeable lithium/sulfur battery

Sheng S. Zhang

ELECTROCHIMICA ACTA (2012)

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Using Rotating Ring Disc Electrode Voltammetry to Quantify the Superoxide Radical Stability of Aprotic Li-Air Battery Electrolytes

Juan Herranz et al.

JOURNAL OF PHYSICAL CHEMISTRY C (2012)

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Influence of Lithium Salts on the Discharge Chemistry of Li-Air Cells

Gabriel M. Veith et al.

JOURNAL OF PHYSICAL CHEMISTRY LETTERS (2012)

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Li-O2 Battery with a Dimethylformamide Electrolyte

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JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2012)

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A Reversible and Higher-Rate Li-O2 Battery

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SCIENCE (2012)

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The Lithium-Oxygen Battery with Ether-Based Electrolytes

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ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2011)

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Oxygen Reactions in a Non-Aqueous Li+ Electrolyte

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ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2011)

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Reversibility of electrochemical reactions of sulfur supported on inverse opal carbon in glyme-Li salt molten complex electrolytes

Naoki Tachikawa et al.

CHEMICAL COMMUNICATIONS (2011)

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Article Chemistry, Physical

Increased Stability Toward Oxygen Reduction Products for Lithium-Air Batteries with Oligoether-Functionalized Silane Electrolytes

Zhengcheng Zhang et al.

JOURNAL OF PHYSICAL CHEMISTRY C (2011)

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Article Chemistry, Physical

Solvents' Critical Role in Nonaqueous Lithium-Oxygen Battery Electrochemistry

B. D. McCloskey et al.

JOURNAL OF PHYSICAL CHEMISTRY LETTERS (2011)

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Reaction mechanisms for the limited reversibility of Li-O2 chemistry in organic carbonate electrolytes

Wu Xu et al.

JOURNAL OF POWER SOURCES (2011)

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Article Chemistry, Multidisciplinary

Oxidative-Stability Enhancement and Charge Transport Mechanism in Glyme-Lithium Salt Equimolar Complexes

Kazuki Yoshida et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2011)

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Article Chemistry, Multidisciplinary

Reactions in the Rechargeable Lithium-O2 Battery with Alkyl Carbonate Electrolytes

Stefan A. Freunberger et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2011)

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Synthesis and Electrochemical Performance of a Lithium Titanium Phosphate Anode for Aqueous Lithium-Ion Batteries

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JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2011)

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Ion clustering in aqueous solutions probed with vibrational energy transfer

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PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA (2011)

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Review Multidisciplinary Sciences

Electrical Energy Storage for the Grid: A Battery of Choices

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SCIENCE (2011)

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The improvement of the Li-ion insertion behaviour of Li1.05Cr0.10Mn1.85O4 in an aqueous medium upon addition of vinylene carbonate

Ivana B. Stojkovic et al.

ELECTROCHEMISTRY COMMUNICATIONS (2010)

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The effects of substituting groups in cyclic carbonates for stable SEI formation on graphite anode of lithium batteries

X. J. Wang et al.

ELECTROCHEMISTRY COMMUNICATIONS (2010)

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A macaroni-like Li1.2V3O8 nanomaterial with high capacity for aqueous rechargeable lithium batteries

C. Cheng et al.

ELECTROCHIMICA ACTA (2010)

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Electrochemical Lithium Intercalation into Graphite in Dimethyl Sulfoxide-Based Electrolytes: Effect of Solvation Structure of Lithium Ion

Yuki Yamada et al.

JOURNAL OF PHYSICAL CHEMISTRY C (2010)

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Influence of Nonaqueous Solvents on the Electrochemistry of Oxygen in the Rechargeable Lithium-Air Battery

Cormac O. Laoire et al.

JOURNAL OF PHYSICAL CHEMISTRY C (2010)

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New glyme-cyclic imide lithium salt complexes as thermally stable electrolytes for lithium batteries

Takashi Tamura et al.

JOURNAL OF POWER SOURCES (2010)

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Boron Esters as Tunable Anion Carriers for Non-Aqueous Batteries Electrochemistry

Devaraj Shanmukaraj et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2010)

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Differentiating Contributions to Ion Transfer Barrier from Interphasial Resistance and Li+ Desolvation at Electrolyte/Graphite Interface

Kang Xu et al.

LANGMUIR (2010)

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Raising the cycling stability of aqueous lithium-ion batteries by eliminating oxygen in the electrolyte

Jia-Yan Luo et al.

NATURE CHEMISTRY (2010)

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Electrochemical performance of nanostructured spinel LiMn2O4 in different aqueous electrolytes

Lei Tian et al.

JOURNAL OF POWER SOURCES (2009)

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Article Chemistry, Physical

Liquid electrolyte based on lithium bis-fluorosulfonyl imide salt: Aluminum corrosion studies and lithium ion battery investigations

A. Abouimrane et al.

JOURNAL OF POWER SOURCES (2009)

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On the Surface Chemical Aspects of Very High Energy Density, Rechargeable Li-Sulfur Batteries

Doron Aurbach et al.

JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2009)

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A highly ordered nanostructured carbon-sulphur cathode for lithium-sulphur batteries

Xiulei Ji et al.

NATURE MATERIALS (2009)

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Review Chemistry, Multidisciplinary

Applications of ionic liquids in the chemical industry

Natalia V. Plechkova et al.

CHEMICAL SOCIETY REVIEWS (2008)

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New electrolytes using Li2O or Li2O2 oxides and tris(pentafluorophenyl) borane as boron based anion receptor for lithium batteries

B. Xie et al.

ELECTROCHEMISTRY COMMUNICATIONS (2008)

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Suppression of dendritic lithium formation by using concentrated electrolyte solutions

Soon-Ki Jeong et al.

ELECTROCHEMISTRY COMMUNICATIONS (2008)

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Factors affecting the electrochemical reactivity vs. lithium of carbon-free LiFePO4 thin films

F. Sauvage et al.

JOURNAL OF POWER SOURCES (2008)

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Improved dischargeability and reversibility of sulfur cathode in a novel ionic liquid electrolyte

LX Yuan et al.

ELECTROCHEMISTRY COMMUNICATIONS (2006)

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Rechargeable Li2O2 electrode for lithium batteries

T Ogasawara et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2006)

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Ether-based electrolytes for the lithium/oxygen organic electrolyte battery

J Read

JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2006)

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Lithium-air batteries using hydrophobic room temperature ionic liquid electrolyte

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JOURNAL OF POWER SOURCES (2005)

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Polysulfide shuttle study in the Li/S battery system

YV Mikhaylik et al.

JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2004)

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Electrochemical reduction of oxygen in some hydrophobic room-temperature molten salt systems

Y Katayama et al.

JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2004)

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Solvated Li-ion transfer at interface between graphite and electrolyte

T Abe et al.

JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2004)

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Review Chemistry, Multidisciplinary

Nonaqueous liquid electrolytes for lithium-based rechargeable batteries

K Xu

CHEMICAL REVIEWS (2004)

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Correlation between cointercalation of solvents and electrochemical intercalation of lithium into graphite in propylene carbonate solution

T Abe et al.

JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2003)

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Electrochemical intercalation of lithium ion within graphite from propylene carbonate solutions

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ELECTROCHEMICAL AND SOLID STATE LETTERS (2003)

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The chemistry of organic polysulfanes R-Sn-R (n > 2)

R Steudel

CHEMICAL REVIEWS (2002)

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Characterization of the lithium/oxygen organic electrolyte battery

J Read

JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2002)

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Micromorphological studies of lithium electrodes in alkyl carbonate solutions using in situ atomic force microscopy

YS Cohen et al.

JOURNAL OF PHYSICAL CHEMISTRY B (2000)

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The limits of low-temperature performance of Li-ion cells

CK Huang et al.

JOURNAL OF THE ELECTROCHEMICAL SOCIETY (2000)

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