3.8 Article

Large enhancement of thermal conductivity of aluminum-reduced graphene oxide composites prepared by a single-step method

Journal

OXFORD OPEN MATERIALS SCIENCE
Volume 3, Issue 1, Pages -

Publisher

OXFORD UNIV PRESS
DOI: 10.1093/oxfmat/itac015

Keywords

aluminum; metal matrix composite; thermal conductivity; reduced graphene oxide; Maxwell model; density functional theory

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This study prepared aluminum-reduced graphene oxide (Al-rGO) composites with enhanced thermal conductivity in a simple single-step process. The thermal conductivity of the Al-rGO composite increases with a higher percentage of rGO inside the Al matrix. The composite also shows an increase in microhardness and the electrical resistivity is comparable to that of pristine Al for a narrow weight percentage of rGO.
Metal matrix composites have attracted extensive attention from both the research and industrial perspective. In this study, we prepared aluminum-reduced graphene oxide (Al-rGO) composites with enhanced thermal conductivity in an easy single-step process. Pristine Al shows a thermal conductivity of 175 Wm(-1)K(-1) (standard deviation <5%), which increases to 293 Wm(-1)K(-1) for an Al-rGO composite with 1% rGO. Analysis of theoretical models shows that a higher percentage of rGO inside the Al matrix creates a continuous network resulting in more available phase space through which heat carrier phonons travel with less scattering, and hence thermal conductivity of the composite increases. Furthermore, Al-rGO composites show an & SIM;5% increase in microhardness compared with pristine Al. The electrical resistivity of the composite is comparable to that of pristine Al for a narrow weight percentage of rGO, whereas a 70% enhancement in the thermal conductivity of the composite is observed for the same weight percentage range, suggesting possibilities for exploiting both high electrical and thermal conductivities for various applications.

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