CH/π Interactions for Macroscopic Interfacial Adhesion Design

Adhesion to chemically inert materials without surface modification through noncovalent interactions represents a challenging task in adhesion science. We successfully develop for the first time a strategy utilizing multiple CH/pi interactions that use poly(methacrylate) with an aromatic group (H acceptor) in the ester part and polyolefin materials (H donor). The strength increases with the number of pi electrons and aromatic rings. The trityl methacrylate polymer emerges as the most effective H-acceptor polymer for obtaining strong adhesion to various polyolefin materials. This work will provide not only a promising adhesion strategy that does not require surface activation for polyolefin materials, but also a novel approach using weak noncovalent interactions.