Phase transitions and topological defects in discotic liquid crystal droplets with planar anchoring: a Monte Carlo simulation study

In this work we present the results of Monte Carlo (MC) simulations at the isothermal-isobaric ensemble for a discotic liquid crystal (DLC) droplet whose surface promotes edge-on (planar) anchoring. For a given pressure, we simulate an annealing process that enables observation of phase transitions within the spherical droplet. In particular, we report a first order isotropic-nematic transition as well as a nematic-columnar transition at the center of the droplet. We found the appearance of topological defects consisting of two disclination lines with ends at the surface of the sphere. We also observed that both transitions, isotropic-nematic and nematic-columnar, occur at lower temperatures as compared to the unconfined system.

Automated summary

In this work, Monte Carlo (MC) simulations were performed on a discotic liquid crystal (DLC) droplet with edge-on (planar) anchoring. Phase transitions, including a first order isotropic-nematic transition and a nematic-columnar transition, were observed within the spherical droplet. The appearance of topological defects consisting of two disclination lines and the lower transition temperatures compared to the unconfined system were also observed.