4.6 Article

Sodium ion doped graphitic carbon nitride with high crystallinity for superior photocatalytic hydrogen evolution efficiency

Related references

Note: Only part of the references are listed.
Article Chemistry, Physical

Spatially restricted strategy to construct crystalline carbon nitride nanosheet assists exciton dissociation to enhance photocatalytic hydrogen evolution activity

Shitao Yang et al.

Summary: In this study, highly crystalline carbon nitride sheets were prepared using a integrated strategy involving spatially restricted growth in solid salt media and hydrochloric acid induced exfoliation. The growth of carbon nitride was induced by K+ ions in the confined space of the solid salt, and K+ ions diffused into the carbon nitride bulk phase with feasible paths. Pickling was also used to control the K+ concentration gradient distribution and regulate the charge characteristic of cyanoamino. The carbon nitride dual-functionalized with cyanoamino and K+ (KCCN) exhibited improved photocatalytic performance with significantly higher hydrogen evolution efficiency and quantum efficiency compared to ordinary carbon nitride.

APPLIED SURFACE SCIENCE (2023)

Article Chemistry, Physical

Single-Color and Two-Color Femtosecond Pump-Probe Experiments on Graphitic Carbon Nitrides Revealing Their Charge Carrier Kinetics

Shuang Song et al.

Summary: Graphitic carbon nitride related materials are promising photocatalysts. Understanding their genuine charge carrier kinetics is important for their photocatalytic applications. Two samples with different termination/functionalization groups were synthesized and studied using single-color and two-color femtosecond pump-probe experiments. The results showed that the charge carrier kinetics of CN and NCN should be measured under very low pump fluence, and higher pump fluence would introduce a short picosecond component due to carrier-carrier interactions. The derived absorption cross section of CN and NCN at pump wavelength were also determined. Overall, this study provides insights into the charge carrier kinetics of CN and NCN and their photocatalytic activities.

JOURNAL OF PHYSICAL CHEMISTRY C (2023)

Article Chemistry, Physical

Efficient Exciton Dissociation in Ionically Interacted Methyl Viologen and Polymeric Carbon Nitride for Superior H2O2 Photoproduction

Yubao Zhao et al.

Summary: By anchoring cationic methyl viologen (MV) on polymeric carbon nitride (CN) photocatalyst with an anionic moiety, an ionic link is generated, resulting in an internal local electric field in the organic photocatalyst framework, which greatly enhances exciton dissociation. This study demonstrates an unprecedentedly efficient photocatalyst for the photoproduction of hydrogen peroxide (H2O2), and provides a mechanistic rationale for its remarkable catalytic performance.

ACS CATALYSIS (2023)

Article Chemistry, Multidisciplinary

Unravelling the doping effect of potassium ions on structural modulation and photocatalytic activity of graphitic carbon nitride

Chengyu Peng et al.

Summary: Graphitic carbon nitride (GCN) has been extensively studied as a promising photocatalyst, but its performance is still lacking. Metal ion doping has been proven to enhance the photocatalytic activity of GCN, and in this study, K+-doped GCN samples were prepared at different temperatures. The introduction of K+ improved the crystallinity of GCN at higher temperature, but reduced it at lower temperature. FTIR and SEM-EDS measurements showed that K+ predominantly distributed on the surface of the lower temperature sample, while it was found both on the surface and in the bulk of the higher temperature sample. The higher crystallinity of K+-doped GCN resulted in a higher H-2 evolution rate under visible light irradiation. This work provides insight for optimizing metal ion doped GCN with high photocatalytic activity.

RSC ADVANCES (2023)

Article Chemistry, Physical

Cyano group-enriched crystalline graphitic carbon nitride photocatalyst: Ethyl acetate-induced improved ordered structure and efficient hydrogen-evolution activity

Binbin Zhao et al.

Summary: In this study, the ethyl acetate-mediated method was developed to improve the crystallinity and prepare efficient g-C3N4 photocatalysts. The resultant cyano group-enriched crystalline g-C3N4 photocatalysts (CC-CN) displayed significantly enhanced photocatalytic hydrogen-evolution performance. The improved performance was attributed to the synergy of improved ordered structure and abundant cyano groups, promoting efficient transfer and separation of photoinduced charges as well as excellent interfacial hydrogen-generation reaction.

JOURNAL OF COLLOID AND INTERFACE SCIENCE (2022)

Article Nanoscience & Nanotechnology

Ion-Induced Synthesis of Crystalline Carbon Nitride Ultrathin Nanosheets from Mesoporous Melon for Efficient Photocatalytic Hydrogen Evolution with Synchronous Highly Selective Oxidation of Benzyl Alcohol

Tingting Huo et al.

Summary: In this study, Na+-doped ultrathin crystalline carbon nitride nanosheets (CCNuns) were successfully synthesized and demonstrated high performance in photocatalytic hydrogen evolution and organic oxidation. Additionally, the selectivity of CCNuns for benzaldehyde formation was found to increase gradually with increasing light wavelengths, which is of great significance.

ACS APPLIED MATERIALS & INTERFACES (2022)

Review Materials Science, Multidisciplinary

Recent Advances in g-C3N4-Based Donor-Acceptor Photocatalysts for Photocatalytic Hydrogen Evolution: An Exquisite Molecular Structure Engineering

Qiang Zhang et al.

Summary: This article reviews the research on photocatalytic hydrogen evolution based on graphitic carbon nitride and introduces the design strategies and mechanisms of donor-acceptor type photocatalysts. The article also provides an overview of the major challenges and opportunities in this research field and shows the implications for future studies.

ACS MATERIALS LETTERS (2022)

Article Energy & Fuels

One-Step Realization of Crystallization and Cyano-Group Generation for g-C3N4 Photocatalysts with Improved H2 Production

Huogen Yu et al.

Summary: The ordered crystallization and cyano-group generation in g-C(3)N(4) photocatalyst was achieved through a one-step Na2CO3-assisted synthesis approach, leading to significantly improved hydrogen production activity. The synergistic effect of highly crystalline structure and cyano-groups contributed to the enhanced activity of cyano-group-modified crystalline g-C(3)N(4). This technology provides insights for the preparation of other crystalline photocatalysts.

SOLAR RRL (2021)

Article Chemistry, Multidisciplinary

Photodriven Charge Accumulation and Carrier Dynamics in a Water-Soluble Carbon Nitride Photocatalyst

Chunyu Li et al.

Summary: Light-driven charge accumulation in a novel water-soluble carbon nitride photocatalyst was investigated for selective photocatalytic oxidation of alcohols and reduction of dioxygen. The material showed excellent charge storage ability and long-lived radicals generated under anaerobic conditions were utilized in dark reactions. Effective electron donors were found to play a crucial role in creating long-lived photo-generated carbon nitride radicals.

CHEMSUSCHEM (2021)

Article Chemistry, Multidisciplinary

On-Surface Polymerization of In-Plane Highly Ordered Carbon Nitride Nanosheets toward Photocatalytic Mineralization of Mercaptan Gas

Fangsong Guo et al.

Summary: 2D carbon nitride nanosheets with in-plane highly ordered structure (PCNNs-IHO) are successfully prepared by on-surface polymerization of melamine on NaCl crystal surface at elevated temperatures. The NaCl crystals with relative high surface energy facilitate the adsorption and activation of melamine to undergo condensation reaction, and also function as unique substrates to orientate the assembly of 2D nanosheet structure. NaCl acts as a reactant to provide Na+ doping into carbon nitride matrix, affording PCNNs-IHO with robust structural base sites. PCNNs-IHO exhibits superior photocatalytic performance toward CH3SH mineralization under visible light irradiation.

ADVANCED MATERIALS (2021)

Review Nanoscience & Nanotechnology

Polymer photocatalysts for solar-to-chemical energy conversion

Tanmay Banerjee et al.

Summary: Organic polymeric photocatalysts offer a promising solution for sustainable energy resources with their precise molecular backbone and broad design space. By analyzing the photophysical and physico-chemical concepts, design principles and future research directions in the emerging field of 'soft photocatalysis' can be derived. The review discusses the fundamental concepts governing the photocatalytic performance of organic polymer photocatalysts and explores the challenges and potential future developments in the field.

NATURE REVIEWS MATERIALS (2021)

Article Chemistry, Physical

Rapid polymerization synthesizing high-crystalline g-C3N4 towards boosting solar photocatalytic H2 generation

Longyan Wang et al.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2020)

Article Chemistry, Physical

One-step preparation of novel K+ and cyano-group co-doped crystalline polymeric carbon nitride with highly efficient H2 evolution

Ping Deng et al.

COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS (2020)

Article Chemistry, Multidisciplinary

Shallow trap state-enhanced photocatalytic hydrogen evolution over thermal-decomposed polymeric carbon nitride

Jiawei Xue et al.

CHEMICAL COMMUNICATIONS (2020)

Article Chemistry, Physical

EPR investigations of polymeric and H2O2-modified C3N4-based photocatalysts

Dana Dvoranova et al.

JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY (2019)

Article Chemistry, Multidisciplinary

Electron Accumulation Induces Efficiency Bottleneck for Hydrogen Production in Carbon Nitride Photocatalysts

Wenxing Yang et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2019)

Article Chemistry, Physical

Localized π-conjugated structure and EPR investigation of g-C3N4 photocatalyst

Pengfei Xia et al.

APPLIED SURFACE SCIENCE (2019)

Review Chemistry, Multidisciplinary

Crystalline Carbon Nitride Semiconductors for Photocatalytic Water Splitting

Lihua Lin et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

Article Chemistry, Physical

The role of nitrogen defects in graphitic carbon nitride for visible-light-driven hydrogen evolution

Jiawei Xue et al.

PHYSICAL CHEMISTRY CHEMICAL PHYSICS (2019)

Article Chemistry, Physical

Carbon nitride with electron storage property: Enhanced exciton dissociation for high-efficient photocatalysis

Zhenxing Zeng et al.

APPLIED CATALYSIS B-ENVIRONMENTAL (2018)

Article Chemistry, Physical

Electron Transfer of the Metal/Semiconductor System in Photocatalysis

M. A. Khan et al.

JOURNAL OF PHYSICAL CHEMISTRY C (2018)

Article Chemistry, Physical

Template-Induced High-Crystalline g-C3N4 Nanosheets for Enhanced Photocatalytic H2 Evolution

Weinan Xing et al.

ACS ENERGY LETTERS (2018)

Article Chemistry, Multidisciplinary

Dark Photocatalysis: Storage of Solar Energy in Carbon Nitride for Time-Delayed Hydrogen Generation

Vincent Wing-hei Lau et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2017)

Article Chemistry, Multidisciplinary

Time-Resolved Spectroscopic Investigation of Charge Trapping in Carbon Nitrides Photocatalysts for Hydrogen Generation

Robert Godin et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2017)

Article Chemistry, Multidisciplinary

Ultrafast Spectroscopy Reveals Electron-Transfer Cascade That Improves Hydrogen Evolution with Carbon Nitride Photocatalysts

Kathryn L. Corps et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2017)

Article Chemistry, Multidisciplinary

The Easier the Better Preparation of Efficient Photocatalysts-Metastable Poly(heptazine imide) Salts

Zupeng Chen et al.

ADVANCED MATERIALS (2017)

Article Chemistry, Multidisciplinary

Tri-s-triazine-Based Crystalline Carbon Nitride Nanosheets for an Improved Hydrogen Evolution

Honghui Ou et al.

ADVANCED MATERIALS (2017)

Article Chemistry, Multidisciplinary

A Rapid Microwave-Assisted Thermolysis Route to Highly Crystalline Carbon Nitrides for Efficient Hydrogen Generation

Yufei Guo et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2016)

Article Chemistry, Multidisciplinary

Solar-Driven Reduction of Aqueous Protons Coupled to Selective Alcohol Oxidation with a Carbon Nitride-Molecular Ni Catalyst System

Hatice Kasap et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2016)

Article Chemistry, Physical

Charge carrier kinetics of carbon nitride colloid: a femtosecond transient absorption spectroscopy study

Huiyu Zhang et al.

PHYSICAL CHEMISTRY CHEMICAL PHYSICS (2016)

Article Multidisciplinary Sciences

Rational design of carbon nitride photocatalysts by identification of cyanamide defects as catalytically relevant sites

Vincent Wing-hei Lau et al.

NATURE COMMUNICATIONS (2016)

Article Nanoscience & Nanotechnology

Time-Resolved Study on Xanthene Dye-Sensitized Carbon Nitride Photocatalytic Systems

Huiyu Zhang et al.

ACS APPLIED MATERIALS & INTERFACES (2015)

Review Chemistry, Multidisciplinary

Polymeric Photocatalysts Based on Graphitic Carbon Nitride

Shaowen Cao et al.

ADVANCED MATERIALS (2015)

Article Chemistry, Multidisciplinary

Graphitic Carbon Nitride Polymers toward Sustainable Photoredox Catalysis

Yun Zheng et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2015)

Article Chemistry, Physical

Effect of processing temperature on structure and photocatalytic properties of g-C3N4

I. Papailias et al.

APPLIED SURFACE SCIENCE (2015)

Article Chemistry, Physical

g-C3N4-Based Photocatalysts for Hydrogen Generation

Shaowen Cao et al.

JOURNAL OF PHYSICAL CHEMISTRY LETTERS (2014)

Review Chemistry, Multidisciplinary

Exciton Dynamics in Semiconductor Nanocrystals

Damon A. Wheeler et al.

ADVANCED MATERIALS (2013)

Article Chemistry, Physical

Photophysical Properties of Atto655 Dye in the Presence of Guanosine and Tryptophan in Aqueous Solution

Ruixue Zhu et al.

JOURNAL OF PHYSICAL CHEMISTRY B (2011)

Article Chemistry, Physical

Relaxation Dynamics of Anisotropic Shaped CdS Nanoparticles

Suparna Sadhu et al.

JOURNAL OF PHYSICAL CHEMISTRY C (2011)

Article Chemistry, Physical

New non-oxide photocatalysts designed for overall water splitting under visible light

Kazuhiko Maeda et al.

JOURNAL OF PHYSICAL CHEMISTRY C (2007)