Journal
GREEN CHEMISTRY
Volume -, Issue -, Pages -Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/d3gc01833
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This study focuses on the synthesis of tunable bis-allylated compounds from cellulose-derived levoglucosenone and their use in thiol-ene click chemistry for 3D-printing. The resulting materials exhibit excellent reactivity and are suitable for creating well-defined three-dimensional objects.
3D-printing technologies for polymer formulations are experiencing huge development due to the complex and specific geometries that can be created employing additive manufacturing. However, to ensure sustainable growth, it is essential to replace the currently used fossil-based resins with new bio-sourced alternatives. In this study, tunable bis-allylated compounds were efficiently synthesized from cellulose-derived levoglucosenone via a chemo-enzymatic pathway whose greenness has been assessed by E-factor and Eco-Scale. Subsequently, photocuring was employed as an eco-friendly process to polymerize these compounds with a trifunctional thiol using thiol-ene click chemistry. Real-time techniques such as FT-IR, photo-DSC, and photo-rheology were employed to extensively characterize the UV process. The resulting thermosets were also subjected to a thorough analysis, covering their thermo-mechanical properties and degradation. Owing to the exceptional reactivity of this thiol-ene system, 3-D printed materials were achieved with remarkable precision. Novel monomers were prepared through a chemo-enzymatic route from cellulose-based levoglucosenone and polymerized via thiol-ene click-chemistry. The resulting materials proved suitable for 3D-printing, offering well-defined three-dimensional objects.
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