Journal
RSC ADVANCES
Volume 6, Issue 107, Pages 105331-105337Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6ra22527f
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Funding
- National Natural Science Foundation of China [21305014, 81202912]
- Natural Sciences Foundation of Fujian Province [2014J05013, 2016J01396]
- Specialized Research Fund for the Doctoral Program of Higher Education of China [20133514110001]
- Outstanding Youth Research Training Program of Fujian Agriculture and Forestry University [xjq201409]
- Key Subjects of Ecology, Fujian Province [6112C0600]
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Nitrite, an inorganic anion, is widely applied in various fields. Excessive nitrites are harmful to humans and the environment. Here we report on preparation of a nanocomposite, C3N4 quantum dots on C3N4 nanosheets (CNQD@CNNS). With the use of this nanocomposite, we developed a rapid and sensitive electrochemiluminescent (ECL) sensor based on a CNQD@CNNS-modified glassy carbon electrode (GCE). The CNQD@CNNS-modified GCE exhibited strong ECL response using S2O82- as the coreactant. In the presence of nitrites, ECL intensity obviously decreased. After optimizing the dosage of CNQD@CNNS and concentration of co-reactant, the ECL sensor showed a wide linear range (0.28-40 mu M) and good detection limit (0.12 mu M) and selectivity. Further, the proposed ECL sensor was also used to assay nitrites in extract of sausage with satisfactory results.
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