4.6 Article

One-pot solvothermal synthesis of magnetic SnFe2O4 nanoparticles and their performance in the photocatalytic degradation of chlortetracycline with visible light radiation

Journal

RSC ADVANCES
Volume 6, Issue 80, Pages 76542-76550

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c6ra15312g

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Funding

  1. Basic Science Research Program through the National Research Foundation of Korea - Ministry of Science, ICT and Future Planning [2014R1A1A3049826, 2014R1A2A1A11051245]
  2. Nano-material Technology Development Program through the National Research Foundation of Korea (NRF) - Ministry of Science, ICT and Future Planning [2009-0082580]

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Highly crystalline SnFe2O4 nanoparticles with high saturation magnetization and superior chlortetracycline (CTC) degradation efficiency was developed using a one-pot solvothermal method. The SnFe2O4 nanoparticles about 50 nm were prepared with a simple and cost-effective process performed at 200 degrees C. Superparamagnetism was observed from the SnFe2O4 nanoparticles with a high saturation magnetization of 74.3 emu g(-1). The excellent photocatalytic activity of the SnFe2O4 nanoparticles was demonstrated through the high degradation efficiency of CTC under a visible light/SnFe2O4/9 mM H2O2 process. The effective degradation of CTC with the SnFe2O4 nanoparticles was attributed to the effective absorption of the visible light and the good separation ability of the electron-hole pairs. The synergy effect between SnFe2O4 and H2O2 was analysed, and the optimum initial concentration of H2O2 was determined to be 9 mM to achieve the best photocatalytic result on CTC. The SnFe2O4 nanoparticles also exhibited a fast and easy magnetic retrieval and a stable performance with continuous recycled usage.

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