4.7 Article

Polyvalent Ionic Energetic Salts Based on 4-Amino-3-hydrazino-5-methyl-1,2,4-triazole

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Publisher

MDPI
DOI: 10.3390/ijms241713136

Keywords

energetic salts; triazole; methyl; thermostability; detonation performance

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The synthesis and characterization of the new energetic material 4-amino-3-hydrazino-5-methyl-1,2,4-triazole has been investigated in this study. Various techniques including DSC, IR, elemental analysis, and NMR spectroscopy were employed to fully characterize the material. The detonation properties of the synthesized compounds were evaluated, and compounds 7 and 8 exhibited exceptional detonation properties with high pressures and velocities.
The synthesis of the new energetic material 4-amino-3-hydrazino-5-methyl-1,2,4-triazole, which shows excellent performance and reliable safety, has drawn attention recently. To fully characterize this material, a comprehensive analysis was performed using various techniques, including differential scanning calorimetry (DSC), infrared spectroscopy (IR), elemental analysis, and 1H and 13C NMR spectroscopy. Additionally, three compounds, 3, 5 and 9, were further characterized using single X-ray diffraction. The X-ray data suggested that extensive hydrogen bonds affect molecular structure by means of intermolecular interactions. In order to evaluate the explosive properties of these synthesized compounds, detonation pressures and velocities were calculated using EXPLO5 (V6.01). These calculations were carried out utilizing experimental data, including density and heat of formation. Among the explosives tested, compounds 7 and 8 exhibited zero oxygen balance and demonstrated exceptional detonation properties. Compound 7 achieved the highest recorded detonation pressure, at 34.2 GPa, while compound 8 displayed the highest detonation velocity, at 8887 m s-1.

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