Journal
RSC ADVANCES
Volume 6, Issue 80, Pages 77093-77099Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6ra13512a
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Funding
- National Natural Science Foundation of China [21404042]
- Natural Science Foundation of Guangdong Province [2014A030310166]
- International Postdoctoral Exchange Fellowship Program [[2014]29]
- Fundamental Research Funds for the Central Universities [2016ZM060]
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A series of thioxanthone dicarboxamide derivatives (TX-DCAs) containing hydrogen donors as one-component photoinitiators (PIs) have been prepared. In particular, the photoreactivity of these PIs was remarkably improved due to the covalent binding of the N-phthalimido derivative and type II chromophore thioxanthone. These derivatives exhibit interesting shifted absorption so that they can be utilized as versatile PIs upon exposure to various violet and visible LEDs (365 nm, 385 nm, 395 nm and 405 nm), and can efficiently actuate the free radical photopolymerization of acrylates.
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