4.7 Article

A fluoropolymer bifunctional solid membrane interface for improving the discharge duration in aqueous Al-air batteries

Journal

CHEMICAL COMMUNICATIONS
Volume 59, Issue 74, Pages 11121-11124

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/d3cc02671j

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In this study, a fluoropolymer bifunctional solid membrane interface (SMI) is proposed for aqueous Al-air batteries, which not only inhibits anodic self-corrosion but also reduces the accumulation of undesirable by-products. The battery using this SMI exhibits a remarkable anticorrosion efficiency of 81.31% and an astonishing battery lifetime improvement rate of 184.37% under the condition of 5 min intermittent discharge. The fluoropolymer bifunctional solid membrane interface (PTFE SMI) effectively inhibits anodic self-corrosion and reduces the accumulation of by-products, thereby facilitating the commercialization of aqueous Al-air batteries.
Herein, a fluoropolymer bifunctional solid membrane interface (SMI) for an aqueous Al-air battery is proposed, which inhibits anodic self-corrosion, while concurrently reducing the accumulation of undesirable by-products. A battery using the SMI exhibits a remarkable anticorrosion efficiency of 81.31% and achieves an astonishing battery lifetime improvement rate of 184.37% under the condition of 5 min intermittent discharge. A fluoropolymer bifunctional solid membrane interface (PTFE SMI) effectively inhibits anodic self-corrosion, while simultaneously reducing the accumulation of by-products, thereby facilitating the commercialization of aqueous Al-air batteries.

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