Journal
RSC ADVANCES
Volume 6, Issue 99, Pages 96693-96699Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6ra17524d
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Funding
- National Natural Science Foundation of China [21276211, 21472152, 21542014]
- Basic and Frontier Research Project of Chongqing [cstc2015jcyjBX0106]
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A visible light-induced decarboxylative amination of indoline-2-carboxylic acids and azodicarboxylate esters has been developed, in which the oxidation of alpha-amino acids provides a versatile CO2-extrusion platform to generate alpha-aminoalkyl radicals. The corresponding products were obtained with yields of up to 72% catalyzed by a metal-free photocatalyst under mild conditions.
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