Journal
RSC ADVANCES
Volume 6, Issue 64, Pages 59269-59272Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c6ra11374e
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Funding
- Alberta Children's Hospital Research Institute
- Alberta Children's Hospital Foundation
- Charbonneau Cancer Institute
- University of Calgary
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Penetration of light through biological tissue improves in the near-IR windows beyond 650 nm. In an effort to explore the chemical reactivity accessible using this low-energy radiation, this study reveals catalysts and reactions that are experimentally viable with red light. Thiophene-containing porphyrin compounds are capable of catalytic, photo-reductive dehalogenation on an array of a-halo ketone model substrates with low catalyst loadings (0.1mol%), in the presence of low energy, red light (> 645 nm).
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